02741nam 2200577 a 450 991043782150332120200520144314.01-283-91033-03-642-33173-410.1007/978-3-642-33173-2(CKB)2670000000279498(EBL)1082659(OCoLC)820861755(SSID)ssj0000798965(PQKBManifestationID)11462947(PQKBTitleCode)TC0000798965(PQKBWorkID)10755547(PQKB)10593882(DE-He213)978-3-642-33173-2(MiAaPQ)EBC1082659(PPN)168323745(EXLCZ)99267000000027949820120820d2013 uy 0engur|n|---|||||txtccrNovel selenium-mediated rearrangements and cyclisations /Sohail Anjum Shahzad1st ed. 2013.New York Springer20131 online resource (207 p.)Springer theses : recognizing outstanding Ph.D. research,2190-5053Description based upon print version of record.3-642-42874-6 3-642-33172-6 Includes bibliographical references.General Introduction on Selenium.- The Synthesis of Novel Dihydronaphthalenes and Benzofluorenes -- The Synthesis of Naphthalenes and Biaryls -- Synthesis of Isocoumarins and Dihydroisocoumarins.- Experimental Section.In his thesis, Sohail Shahzad carefully investigates carbon nucleophiles in selenocyclisations, as well as reaction protocols for performing such reactions catalytically. After a comprehensive introduction to the element selenium, the author goes on to report the synthesis of several substrates for carbocyclisation reactions and the use of selenium reagents for the preparation of dihydronaphthalenes. Further chapters detail electrophilic selenium-mediated reactions, and novel strategies using selenium catalysts together with stoichiometric amounts of hypervalent iodine reagents as oxidants to convert stilbene carbosylic acids into the corresponding isocoumarins. This thesis outlines some excellent new synthetic routes which will be useful tools for synthetic organic chemistry in the future.Springer theses.Organic compoundsSynthesisOrganic compoundsSynthesis.547.05724Shahzad Sohail Anjum1063515MiAaPQMiAaPQMiAaPQBOOK9910437821503321Novel Selenium-Mediated Rearrangements and Cyclisations2532850UNINA