03130nam 22006255 450 991041004670332120250609110121.03-658-30020-510.1007/978-3-658-30020-3(CKB)4100000011208542(MiAaPQ)EBC6157454(DE-He213)978-3-658-30020-3(PPN)243760299(MiAaPQ)EBC6157405(EXLCZ)99410000001120854220200403d2020 u| 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierChemoselective Nucleophilic α-Amination of Amides /by Miran Lemmerer1st ed. 2020.Wiesbaden :Springer Fachmedien Wiesbaden :Imprint: Springer Spektrum,2020.1 online resource (68 pages)BestMasters,2625-36153-658-30019-1 Traditional Umpolung Reactions in Organic Chemistry -- Insight into Electrophilic Amide Activation -- Results and Discussion of a New α-Amination Method via Umpolung of Amides -- α-Arylation of Carbonlys via a Smiles Rearrangement.α-Amino carbonyl compounds are omnipresent in all living organisms, making their selective synthesis highly sought after. However, the synthesis of α-amino amides, a subclass of α-amino carbonyls, in the presence of other carbonyls is usually challenging, due to the required harsh conditions. Miran Lemmerer expands a novel chemoselective approach for the synthesis of these intriguing molecules together with Univ.-Prof. Dr. Nuno Maulide’s team. Contents Traditional Umpolung Reactions in Organic Chemistry Insight into Electrophilic Amide Activation Results and Discussion of a New α-Amination Method via Umpolung of Amides α-Arylation of Carbonlys via a Smiles Rearrangement Target Groups Scientists and students in the field of organic chemistry, especially in methodology development The Author Miran Lemmerer is currently pursuing his PhD studies under supervision of Prof. Dr. Nuno Maulide at the Department of Organic Chemistry, University of Vienna, Austria. .BestMasters,2625-3615Asymmetric synthesisChemical structureOrganic compoundsSynthesisChemistryAsymmetric SynthesisStructure And BondingSynthetic Chemistry MethodologyReactive PrecursorAsymmetric synthesis.Chemical structure.Organic compoundsSynthesis.Chemistry.Asymmetric Synthesis.Structure And Bonding.Synthetic Chemistry Methodology.Reactive Precursor.547.042Lemmerer Miranauthttp://id.loc.gov/vocabulary/relators/aut1062229MiAaPQMiAaPQMiAaPQBOOK9910410046703321Chemoselective Nucleophilic α-Amination of Amides2523575UNINA