03775nam 22006375 450 991037393390332120200706054341.03-030-26822-510.1007/978-3-030-26822-0(CKB)4100000009844883(DE-He213)978-3-030-26822-0(MiAaPQ)EBC5977076(PPN)258876271(EXLCZ)99410000000984488320191111d2019 u| 0engurnn#008mamaatxtrdacontentcrdamediacrrdacarrierFundamentals of Spin Exchange Story of a Paradigm Shift /by Kev M. Salikhov1st ed. 2019.Cham :Springer International Publishing :Imprint: Springer,2019.1 online resource (XIII, 265 p. 47 illus.)3-030-26821-7 Introduction -- Theory of spin exchange in dilute solutions -- Paramagnetic relaxation caused by spin-spin dipole-dipole interaction of paramagnetic particles in a liquid -- Modified Bloch equations for dilute solutions of free radicals taking into account exchange and dipole-dipole interactions -- Manifestation of exchange and dipole-dipole interaction in the form of EPR spectra of paramagnetic particles in solutions in linear response case -- Experimental determination of the spin exchange rate from the analysis of the EPR spectrum shape -- Other methods of measuring the spin exchange rate constants -- In Conclusion.This book is a comprehensive summary of 50 years of research from theoretical predictions to experimental confirmation of the manifestation of spin exchange in EPR spectroscopy. The author unfolds the details of comprehensive state of the art of theoretical calculations, which have been proven to become the core of the paradigm shift in spin exchange and set the direction for the future of spin exchange research. The book refers to important experimental data that confirms the theory. It describes the modern protocol for determining the bi-molecular spin exchange rate from the EPR spectra, which will be especially interesting for experimentalists. Given its scope, the book will benefit all researchers engaged in theory and experiments in the area of spin exchange and its manifestations in EPR spectroscopy, where many remarkable applications of the spin probe have been developed. .Spectrum analysisMicroscopyChemistry, Physical and theoreticalCondensed matterBiophysicsBiophysicsSpectroscopy and Microscopyhttps://scigraph.springernature.com/ontologies/product-market-codes/P31090Physical Chemistryhttps://scigraph.springernature.com/ontologies/product-market-codes/C21001Condensed Matter Physicshttps://scigraph.springernature.com/ontologies/product-market-codes/P25005Biological and Medical Physics, Biophysicshttps://scigraph.springernature.com/ontologies/product-market-codes/P27008Spectrum analysis.Microscopy.Chemistry, Physical and theoretical.Condensed matter.Biophysics.Biophysics.Spectroscopy and Microscopy.Physical Chemistry.Condensed Matter Physics.Biological and Medical Physics, Biophysics.621.36Salikhov Kev Mauthttp://id.loc.gov/vocabulary/relators/aut837240MiAaPQMiAaPQMiAaPQBOOK9910373933903321Fundamentals of Spin Exchange2527168UNINA