05407nam 2201405z- 450 991036775380332120231214133506.03-03921-362-8(CKB)4100000010106179(oapen)https://directory.doabooks.org/handle/20.500.12854/60409(EXLCZ)99410000001010617920202102d2019 |y 0engurmn|---annantxtrdacontentcrdamediacrrdacarrierSynthesis and Applications of New Spin Crossover CompoundsMDPI - Multidisciplinary Digital Publishing Institute20191 electronic resource (254 p.)3-03921-361-X The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials—promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscles. This Special Issue is devoted to various aspects of SCO and related research, comprising 18 interesting original papers on valuable and important SCO topics. Significant and fundamental scientific attention has been focused on the SCO phenomena in a wide research range of fields of fundamental chemical and physical and related sciences, containing the interdisciplinary regions of chemical and physical sciences related to the SCO phenomena. Coordination materials with bistable systems between the LS and the HS states are usually triggered by external stimuli, such as temperature, light, pressure, guest molecule inclusion, soft X-ray, and nuclear decay. Since the first Hofmann-like spin crossover (SCO) behavior in {Fe(py)2[Ni(CN)4]}n (py = pyridine) was demonstrated, this crystal chemistry motif has been frequently used to design Fe(II) SCO materials to enable determination of the correlations between structural features and magnetic properties.hexadentate ligandX-ray diffractionstructural disorderlattice energy2-bis(4-pyridyl)ethanethermal hysteresisoptical conductivity spectrumspin-state crossoversolvatesingle crystalspin-crossover transitionspin-crossovercobalt oxideamorphousmetal dithiolene complexesqsal ligandimpurity effect3-triazoleintermolecular interactionsspin crossoverhydrogen bonding12optical microscopysupramolecular coordination polymerparamagnetic ligandmagnetic susceptibilityhigh spin[Fe(III)(3-OMesal2-trien)]+aminoxylcobalt(II) ionmosaicityFe(III) coordination complexesnitroxidesC-H···? interactionsFe(II)dithiooxalato liganddinuclear triple helicatecoordination polymersmagnetizationspiral structuremagnetostructural correlationscharge-transfer phase transitionstructure phase transitionmagnetic propertiesspin polaronsubstitution of 3d transition metal ioniron(II) complexesX-ray absorption spectroscopycoordination complexescrystal engineeringfatigabilitysoft X-ray induced excited spin state trappingspin transitiondipyridyl-N-alkylamine ligandscoordination polymeriron (II)iron mixed-valence complexchiral propeller structurespin cross-over (SCO)EPR spectroscopyCu(II) complexessolvent effectsferromagnetismSQUIDLIESST effectlow spin (LS)57Fe Mössbauer spectroscopydielectric responseiron(II)hetero metal complexatropisomerismswitchSchiff basecounter-anionDFT calculationFe(III) complexFe(II) complexhigh spin (HS)reaction diffusionthermochromismsupramolecular isomerismphase transitionmagnetic transitionmononuclear[Au(dmit)2]?UV-Vis spectroscopyphase transitions?-? interactions[Au(dddt)2]?crystal structurelinear pentadentate ligandion-pair crystalsKitazawa Takafumiauth1331935BOOK9910367753803321Synthesis and Applications of New Spin Crossover Compounds3040671UNINA