04757nam 2201165z- 450 991036773620332120231214133159.03-03921-995-2(CKB)4100000010106355(oapen)https://directory.doabooks.org/handle/20.500.12854/56702(EXLCZ)99410000001010635520202102d2019 |y 0engurmn|---annantxtrdacontentcrdamediacrrdacarrierPOSS-Based PolymersMDPI - Multidisciplinary Digital Publishing Institute20191 electronic resource (310 p.)3-03921-994-4 The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.graphene oxidelithium ion batteryliquefiedpolypropylenesilsesquioxanesself-assembly behaviorsnanocompositesOctavinyl-POSSpolyimidethermal propertiespolyhedral oligomeric silsesquioxane-based ionic liquidsaqueous self-assemblybi-functional POSSblendslow refractive materialcellular structuremechanism analysismorphologyflame retardanthydrogelsmercapto-modifieddampingPOSS nanoparticlesphthalonitrile polymersmechanical propertiesflame-retardant mechanismthiol-ene 'click' reactionPOSSpoly(?-caprolactone)siloxane-silsesquioxane resinspolyhedral oligomeric silsesquioxane (POSS)surface propertiesfluoropolymerthiol-ene "click" reactionMonomethacryloxy POSSmonodispersethermogravimetryOLEDsfluorescent sensorsdouble-decker-shaped silsesquioxane (DDSQ)dielectric constantcompositesorganic-inorganic hybridspoly(?-caprolactone) nanocompositePOSS-based copolymerorganic-inorganic crosslinkingoptoelectronicsflame retardancycone calorimeter testslauryl methacrylateocta-ammonium POSSnitroaromatic explosivesphthalonitrile-polyhedral oligomeric silsesquioxane copolymerscyanate esterthermoplastic polyurethanesodium alginategiant surfactantbenzoxazinethermal stabilitytemperature responsivenesspolymerization kineticsmechanical performanceSi@C anoderidgid polyurethane foamsepoxy resingrafting synthesisdirect synthesisfillerbridged silsesquioxanehydrophobic modificationdispersionpolyhedral oligomeric silsesquioxanesanchor effectBlanco Ignazioauth1301172BOOK9910367736203321POSS-Based Polymers3025758UNINA