01088nam2 22002893i 450 SBL052423320231121125826.020030724d1961 ||||0itac50 baitageritz01i xxxe z01n˜1: Il œlinguaggioErnst CassirerFirenzeLa Nuova Italia1961XVI, 356 p.22 cm001SBL02577032001 Filosofia delle forme simbolicheErnst Cassirertraduzione di Eraldo Arnaud1˜Die œSpracheLO10086793CFIV010833540652Cassirer, ErnstCFIV01083307045625ITIT-0120030724IT-RM0289 IT-FR0017 Biblioteca Statale A. BaldiniRM0289 Biblioteca umanistica Giorgio ApreaFR0017 NSBL0524233Biblioteca umanistica Giorgio Aprea 52MAG 5/1177.1 52MAG0000026515 VMN RS A 2017100420171004 04 52Sprache540652UNICAS03882nam 22006615 450 991034950700332120200630165025.03-030-31087-610.1007/978-3-030-31087-5(CKB)4100000009382516(DE-He213)978-3-030-31087-5(MiAaPQ)EBC5909873(PPN)248601032(EXLCZ)99410000000938251620190927d2019 u| 0engurnn|008mamaatxtrdacontentcrdamediacrrdacarrierAngle Resolved Photoemission Spectroscopy of Delafossite Metals /by Veronika Sunko1st ed. 2019.Cham :Springer International Publishing :Imprint: Springer,2019.1 online resource (XVII, 198 p. 122 illus., 104 illus. in color.) Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053Doctoral thesis accepted by the Max Planck Institute for chemical physics of solids, Dresden, Germany.3-030-31086-8 Introduction -- Angle Resolved Photoemission -- Theory and Models -- Bulk States in PtCoO2 and PdCoO2 -- Coupling of Metallic and Mott-insulating states in PdCrO2 -- Rashba-like Spin-Split Surface States -- Conclusions and Outlook -- Appendices.This thesis describes the results of angle resolved photoemission spectroscopy experiments on delafossite oxide metals, and theoretical work explaining these observations. The study was motivated by the extraordinarily high conductivity of the non-magnetic delafossites PdCoO2 and PtCoO2, the measurement of whose electronic structure is reported and discussed. Two unexpected effects were observed in the course of the investigation; each is described and analysed in detail. Firstly, a previously unrecognised type of spectroscopic signal, allowing the non-magnetic probe of photoemission to become sensitive to spin-spin correlations, was observed in the antiferromagnetic PdCrO2. Its origin was identified as the Kondo-like coupling of itinerant and Mott insulating electrons. Furthermore, surface states exhibiting an unusually large Rashba-like spin-splitting were observed on the transition metal terminated surfaces of delafossites. The large inversion symmetry breaking energy scale, a consequence of the unusual structure of the surface layer, is identified as the origin of the effect.Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053Solid state physicsSpectrum analysisMicroscopyMaterials—SurfacesThin filmsSolid State Physicshttps://scigraph.springernature.com/ontologies/product-market-codes/P25013Spectroscopy and Microscopyhttps://scigraph.springernature.com/ontologies/product-market-codes/P31090Surfaces and Interfaces, Thin Filmshttps://scigraph.springernature.com/ontologies/product-market-codes/Z19000Spectroscopy/Spectrometryhttps://scigraph.springernature.com/ontologies/product-market-codes/C11020Solid state physics.Spectrum analysis.Microscopy.Materials—Surfaces.Thin films.Solid State Physics.Spectroscopy and Microscopy.Surfaces and Interfaces, Thin Films.Spectroscopy/Spectrometry.530.41530.41Sunko Veronikaauthttp://id.loc.gov/vocabulary/relators/aut1064762MiAaPQMiAaPQMiAaPQBOOK9910349507003321Angle Resolved Photoemission Spectroscopy of Delafossite Metals2540570UNINA