03099nam 22007333a 450 991034667390332120250203235428.09783039210718303921071810.3390/books978-3-03921-071-8(CKB)4920000000094928(oapen)https://directory.doabooks.org/handle/20.500.12854/43680(ScCtBLL)c63cd37f-66b3-4094-86e7-b06794b7a08d(OCoLC)1126168920(EXLCZ)99492000000009492820250203i20192019 uu engurmn|---annantxtrdacontentcrdamediacrrdacarrierCompounds with Polar Metallic BondingConstantin HochBasel, Switzerland :MDPI,2019.1 electronic resource (154 p.)9783039210701 303921070X The Special Edition 'Compounds with Polar Metallic Bonding' is a collection of eight original research reports presenting a broad variety of chemical systems, analytical methods, preparative pathways and theoretical descriptions of bonding situations, with the common aim of understanding the complex interplay of conduction electrons in intermetallic compounds that possess different types of dipoles. Coulombic dipoles introduced by electronegativity differences, electric or magnetic dipoles, polarity induced by symmetry reduction-all the possible facets of the term 'polarity'-can be observed in polar intermetallic phases and have their own and, in most cases, unique consequences on the physical and chemical behaviour. Elucidation of the structure-property relationships in compounds with polar metallic bonding is a modern and growing scientific field which combines solid state physics, preparative chemistry, metallurgy, modern analytic methods, crystallography, theoretical calculations of the electronic state and many more disciplines.bonding analysescoloring problemX-ray diffractionmagnetismband structuregroup-subgroupalkaline-earthZintlnitridometalatestructure optimizationselectronic structurepolar intermetallicspolar intermetallicintermetallic compoundsXPSZintl compoundsstannidestotal energyCOHP methodsymmetry reductionchemical bondplumbidesternary Laves phasespowder diffractionintermetallicsmagnetic propertiesCa14AlSb11thermoelectriccrystal structureliquid ammoniaHoch Constantin1287655ScCtBLLScCtBLLBOOK9910346673903321Compounds with Polar Metallic Bonding3020263UNINA