05045nam 2201237z- 450 991034667230332120231214133529.0(CKB)4920000000094944(oapen)https://directory.doabooks.org/handle/20.500.12854/44062(EXLCZ)99492000000009494420202102d2019 |y 0engurmn|---annantxtrdacontentcrdamediacrrdacarrierCoordination Chemistry of SiliconMDPI - Multidisciplinary Digital Publishing Institute20191 electronic resource (225 p.)3-03897-638-5 The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.clustermolecular orbital analysisbond activationX-ray diffractionsilsesquioxanesdigermacyclobutadieneintermetallic bondgermaniumcomputational chemistry?-electron systemsisocyanideX-ray crystallographycyclic organopolysilanedisilenerutheniumplatinumDFTPhotostabilitysilicon surfacesstereochemistrypalladiumdistorted coordination²⁹Si NMR spectroscopyorganosilicondisilanylene polymerSi–Cl activationadsorptionAIMsiliconoidnanoparticledisiloxane tetrolsgermylenehydrogen bondingTiO₂dehydrogenative alkoxylationsiloxanes2-silylpyrrolidinesbonding analysis?-chloro-?-hydrooligosilanehydrido complexoxidative additionphotoreactiontemplatesurface modificationtitaniumbromosilyleneshost-guest chemistryhydrogen bondssalt-free<i>N</i>-heterocyclic carbinessilicon clustercondensationsilyliumylidenesBaird’s rule<i>N</i>-heterocyclic carbenesreductantmain group coordination chemistrymolecular cagesubvalent compoundsisomerizationsilanetriolsgermathioacid chloridedehydrobromination<i>N</i>-heterocyclic carbenemechanistic insightsligand-exchange reactionbridging silylene liganddye-sensitized solar cellsilylenecomputationfunctionalizationsilicondigermene<i>N</i>-Heterocyclic tetrylenedensity functional theoryprimary silanesmall molecule activationexcited state aromaticitygermanethionesupramolecular chemistryInoue Shigeyoshiauth1331071BOOK9910346672303321Coordination Chemistry of Silicon3040099UNINA