05118nam 2201273z- 450 991034667230332120210211(CKB)4920000000094944(oapen)https://directory.doabooks.org/handle/20.500.12854/44062(oapen)doab44062(EXLCZ)99492000000009494420202102d2019 |y 0engurmn|---annantxtrdacontentcrdamediacrrdacarrierCoordination Chemistry of SiliconMDPI - Multidisciplinary Digital Publishing Institute20191 online resource (225 p.)3-03897-638-5 The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.Chemistrybicssc?-chloro-?-hydrooligosilane?-electron systems<i>N</i>-heterocyclic carbene<i>N</i>-heterocyclic carbenes<i>N</i>-heterocyclic carbines<i>N</i>-Heterocyclic tetrylene²⁹Si NMR spectroscopy2-silylpyrrolidinesadsorptionAIMBaird's rulebond activationbonding analysisbridging silylene ligandbromosilylenesclustercomputationcomputational chemistrycondensationcyclic organopolysilanedehydrobrominationdehydrogenative alkoxylationdensity functional theoryDFTdigermacyclobutadienedigermenedisilanylene polymerdisilenedisiloxane tetrolsdistorted coordinationdye-sensitized solar cellexcited state aromaticityfunctionalizationgermanethionegermaniumgermathioacid chloridegermylenehost-guest chemistryhydrido complexhydrogen bondinghydrogen bondsintermetallic bondisocyanideisomerizationligand-exchange reactionmain group coordination chemistrymechanistic insightsmolecular cagemolecular orbital analysisnanoparticleorganosiliconoxidative additionpalladiumphotoreactionPhotostabilityplatinumprimary silanereductantrutheniumsalt-freeSi-Cl activationsilanetriolssiliconsilicon clustersilicon surfacessiliconoidsiloxanessilsesquioxanessilylenesilyliumylidenessmall molecule activationstereochemistrysubvalent compoundssupramolecular chemistrysurface modificationtemplateTiO₂titaniumX-ray crystallographyX-ray diffractionChemistryInoue Shigeyoshiauth1331071BOOK9910346672303321Coordination Chemistry of Silicon3040099UNINA