02412oam 2200469 450 991029865890332120190911103512.01-4614-8268-210.1007/978-1-4614-8268-0(OCoLC)875638485(MiFhGG)GVRL6VJV(EXLCZ)99371000000008333020131112d2014 uy 0engurun|---uuuuatxtccrElectrostatic and stereoelectronic effects in carbohydrate chemistry /Momcilo Miljkovic1st ed. 2014.New York :Springer,2014.1 online resource (xii, 304 pages) illustrationsGale eBooksDescription based upon print version of record.1-4614-8267-4 Includes bibliographical references at the end of each chapter and indexes.Intramolecular Electrostatic Interacations -- Anomeric Effects -- Acid Catalyzed Hydrolysis of Glycosides -- Conformation and Chemistry of Oxocarbenium Ion -- Glycosylation -- Stereoelectronic Effects in Nucleosides and Nucleotides -- Free Radical Cyclizations -- Sulfones, Olefins, Nitrones, Glycosidic Bond, and Norrish-Young Photocyclization.The book deals with polar effects in carbohydrates and how these effects control the stereochemistry of carbohydrate reactions. This is important for understanding the mechanisms of certain carbohydrate reactions, including enzymatic reactions such as glycosidases, a very important group of enzymes in living matter. It is also very useful for synthetic carbohydrate chemists who would like to synthesize stereoselectively certain classes of carbohydrates. This book will be a very important source of information for practicing synthetic carbohydrate chemists. The book will also be helpful for organic chemists, or for those studying glycobiology.CarbohydratesElectrostaticsCarbohydrates.Electrostatics.54547547.78Miljkovic Momciloauthttp://id.loc.gov/vocabulary/relators/aut1063349MiFhGGMiFhGGBOOK9910298658903321Electrostatic and Stereoelectronic Effects in Carbohydrate Chemistry2531903UNINA