04117nam 22007455 450 991029864860332120200702035120.03-319-09225-110.1007/978-3-319-09225-6(CKB)3710000000219418(EBL)1802869(SSID)ssj0001338423(PQKBManifestationID)11780360(PQKBTitleCode)TC0001338423(PQKBWorkID)11337771(PQKB)11748709(MiAaPQ)EBC1802869(DE-He213)978-3-319-09225-6(PPN)180624261(EXLCZ)99371000000021941820140811d2014 u| 0engur|n|---|||||txtccrSilicon Containing Copolymers /by Sahar Amiri, Mohammad Ali Semsarzadeh, Sanam Amiri1st ed. 2014.Cham :Springer International Publishing :Imprint: Springer,2014.1 online resource (60 p.)SpringerBriefs in Molecular Science,2191-5407Description based upon print version of record.1-322-13786-2 3-319-09224-3 Includes bibliographical references at the end of each chapters.Introduction -- Polyrotaxane based on inclusion complexes of OH-PDMS-OH and Br-PDMS-Br with γ-cyclodextrin without utilizing sonic energy -- Synthesis and Characterization of PDMS based triblock and pentablock Copolymers -- Cobalt mediated radical polymerization of 4-bromo-2,6-dimethyl phenol and its copolymerization with poly(dimethyl siloxane) in the presence of Co(acac)2: DMF catalyst -- Novel Thermoreversible Block Copolymers: Silicone Macroinitiator in Atom Transfer Radical Polymerization.Silicones have unique properties including thermal oxidative stability, low temperature flow, high compressibility, low surface tension, hydrophobicity and electric properties. These special properties have encouraged the exploration of alternative synthetic routes of well defined controlled microstructures of silicone copolymers, the subject of this Springer Brief. The authors explore the synthesis and characterization of notable block copolymers. Recent advances in controlled radical polymerization techniques leading to the facile synthesis of well-defined silicon based thermo reversible block copolymers are described along with atom transfer radical polymerization (ATRP), a technique utilized to develop well-defined functional thermo reversible block copolymers. The brief also focuses on Polyrotaxanes and their great potential as stimulus-responsive materials which produce poly (dimethyl siloxane) (PDMS) based thermo reversible block copolymers.SpringerBriefs in Molecular Science,2191-5407PolymersOrganometallic chemistryCatalysisNanotechnologyPolymer Scienceshttps://scigraph.springernature.com/ontologies/product-market-codes/C22008Organometallic Chemistryhttps://scigraph.springernature.com/ontologies/product-market-codes/C19020Catalysishttps://scigraph.springernature.com/ontologies/product-market-codes/C29000Nanotechnologyhttps://scigraph.springernature.com/ontologies/product-market-codes/Z14000Polymers.Organometallic chemistry.Catalysis.Nanotechnology.Polymer Sciences.Organometallic Chemistry.Catalysis.Nanotechnology.541.394Amiri Saharauthttp://id.loc.gov/vocabulary/relators/aut929018Semsarzadeh Mohammad Aliauthttp://id.loc.gov/vocabulary/relators/autAmiri Sanamauthttp://id.loc.gov/vocabulary/relators/autMiAaPQMiAaPQMiAaPQBOOK9910298648603321Silicon Containing Copolymers2521570UNINA