03506nam 22006015 450 991029859060332120200702175822.0981-10-8327-410.1007/978-981-10-8327-3(CKB)4100000004244301(MiAaPQ)EBC5398099(DE-He213)978-981-10-8327-3(PPN)227399293(EXLCZ)99410000000424430120180516d2018 u| 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierFire Retardancy Behavior of Polymer/Clay Nanocomposites /by Indraneel Suhas Zope1st ed. 2018.Singapore :Springer Singapore :Imprint: Springer,2018.1 online resource (190 pages)Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053981-10-8326-6 Introduction -- Literature Review -- Experimental Methodology -- Decomposition Behavior of Metal-ion Exchanged Clay -- Thermo-oxidative Decomposition Behavior of Polyamide 6 Nanocomposites with Metal-ion Exchanged Clays -- Thermo-oxidative Decomposition Behavior of Polyamide 6 Nanocomposites with Structurally Different Clays -- Controlling the Interfacial Interactions Between Clay and Host Polyamide 6 Matrix -- Clay Catalysis and Fire Retardancy of Polymer/Clay Nanocomposites: A Complete Overview.This thesis investigates the early ignition behavior of polymer/clay nanocomposites, which are perceived as potential eco-friendly flame retardant systems. It examines the correlation between clay structural chemistry and high-temperature transformations with clay-assisted decomposition of organic macromolecules. In particular, it investigates the unique effects of metal ions like Mg2+, Al3+ and Fe3+ that are inherent in clays (smectite) on the combustion and thermo-oxidative decomposition of polyamide 6. The results indicate that metal ions present on/in montmorillonite platelets have preferential reactivity towards peroxy/alkoxy groups during polyamide 6 thermal decomposition.  Lastly, a simple solution in the form of a physical coating on clay surface is proposed, based on the role of polymer–clay interfacial interaction.Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053CeramicsGlassComposites (Materials)Composite materialsEngineering—MaterialsPolymers  Ceramics, Glass, Composites, Natural Materialshttps://scigraph.springernature.com/ontologies/product-market-codes/Z18000Materials Engineeringhttps://scigraph.springernature.com/ontologies/product-market-codes/T28000Polymer Scienceshttps://scigraph.springernature.com/ontologies/product-market-codes/C22008Ceramics.Glass.Composites (Materials).Composite materials.Engineering—Materials.Polymers  .Ceramics, Glass, Composites, Natural Materials.Materials Engineering.Polymer Sciences.628.9223Zope Indraneel Suhasauthttp://id.loc.gov/vocabulary/relators/aut1062859BOOK9910298590603321Fire Retardancy Behavior of Polymer2528770UNINA