03983nam 22007335 450 991015330340332120200705114537.03-319-46624-010.1007/978-3-319-46624-8(CKB)3710000000961031(DE-He213)978-3-319-46624-8(MiAaPQ)EBC4747031(PPN)19713856X(EXLCZ)99371000000096103120161122d2017 u| 0engurnn#008mamaatxtrdacontentcrdamediacrrdacarrierEnergy-Level Control at Hybrid Inorganic/Organic Semiconductor Interfaces /by Raphael Schlesinger1st ed. 2017.Cham :Springer International Publishing :Imprint: Springer,2017.1 online resource (XVIII, 211 p. 88 illus., 52 illus. in color.)Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053"Doctoral Thesis accepted by the Humboldt University of Berlin, Germany."3-319-46623-2 Includes bibliographical references at the end of each chapters.Introduction -- Fundamentals -- Theory of Experimental Methods -- Methodology and Experimental Setups -- Results and Discussion -- Conclusion. .This work investigates the energy-level alignment of hybrid inorganic/organic systems (HIOS) comprising ZnO as the major inorganic semiconductor. In addition to offering essential insights, the thesis demonstrates HIOS energy-level alignment tuning within an unprecedented energy range. (Sub)monolayers of organic molecular donors and acceptors are introduced as an interlayer to modify HIOS interface-energy levels. By studying numerous HIOS with varying properties, the author derives generally valid systematic insights into the fundamental processes at work. In addition to molecular pinning levels, he identifies adsorption-induced band bending and gap-state density of states as playing a crucial role in the interlayer-modified energy-level alignment, thus laying the foundation for rationally controlling HIOS interface electronic properties. The thesis also presents quantitative descriptions of many aspects of the processes, opening the door for innovative HIOS interfaces and for future applications of ZnO in electronic devices. .Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053Surfaces (Physics)Interfaces (Physical sciences)Thin filmsOptical materialsElectronic materialsSpectroscopyMicroscopySemiconductorsSurface and Interface Science, Thin Filmshttps://scigraph.springernature.com/ontologies/product-market-codes/P25160Optical and Electronic Materialshttps://scigraph.springernature.com/ontologies/product-market-codes/Z12000Spectroscopy and Microscopyhttps://scigraph.springernature.com/ontologies/product-market-codes/P31090Semiconductorshttps://scigraph.springernature.com/ontologies/product-market-codes/P25150Surfaces (Physics).Interfaces (Physical sciences).Thin films.Optical materials.Electronic materials.Spectroscopy.Microscopy.Semiconductors.Surface and Interface Science, Thin Films.Optical and Electronic Materials.Spectroscopy and Microscopy.Semiconductors.537.622Schlesinger Raphaelauthttp://id.loc.gov/vocabulary/relators/aut819659MiAaPQMiAaPQMiAaPQBOOK9910153303403321Energy-Level Control at Hybrid Inorganic1826565UNINA