04561nam 2200613 450 991014626810332120180612234033.01-282-78442-097866127844223-527-62178-43-527-62179-2(CKB)1000000000441546(EBL)482346(OCoLC)609855595(SSID)ssj0000354797(PQKBManifestationID)11249101(PQKBTitleCode)TC0000354797(PQKBWorkID)10313405(PQKB)11185212(MiAaPQ)EBC482346(PPN)150635621(EXLCZ)99100000000044154620160819h20082008 uy 0engur|n|---|||||txtccrSupramolecular catalysis /edited by Piet W. N. M. van LeeuwenWeinheim, [Germany] :Wiley-VCH Verlag GmbH & Co. KGaA,2008.©20081 online resource (321 p.)Description based upon print version of record.3-527-32191-8 Includes bibliographical references at the end of each chapters and index.Supramolecular Catalysis; Contents; List of Authors; 1 Introduction to Supramolecular Catalysis; 1.1 Introduction; 1.2 Design Approaches to Supramolecular Catalysis; 1.2.1 Molecular Receptors that Place a Binding Site Close to a Catalytic Center; 1.2.2 Molecular Receptors that Promote the Reaction of two Simultaneously Complexed Reactants; 1.2.3 Preparation of the Catalyst Backbone via Supramolecular Interactions; 1.3 Artificial Biomacromolecules for Asymmetric Catalysis; 1.4 Summary and Outlook; References2 Supramolecular Construction of Chelating Bidentate Ligand Libraries through Hydrogen Bonding: Concept and Applications in Homogeneous Metal Complex Catalysis2.1 Introduction; 2.2 Emulation of Chelation through Self-Assembly of Monodentate Ligands; 2.3 Tautomeric Self-Complementary Interligand Hydrogen Bonding; 2.3.1 Hydroformylation; 2.3.2 Room Temperature/Ambient Pressure Hydroformylation; 2.3.3 Asymmetric Hydrogenation; 2.4 A-T Base Pair Analogous Complementary Hydrogen Bonding for the Construction of Heterodimeric Self-Assembling Ligands; 2.4.1 Aminopyridine/Isoquinolone Platform3.3.2 X-Ray and other Techniques for Structural Characterization in the Solid State3.3.3 Structural Characterization in Solution by NMR; 3.3.4 Anion Exchange in the Solid State; 3.4 Preparation of Coordination Polymers with 2,3-Pyrazolylquinoxalines or 2,3-Pyrazolylpyrazines and Cu(I) or Ag(I); 3.4.1 Preparation and Characterization of Dinuclear Building Blocks and Coordination Polymers; 3.4.2 X-Ray and other Techniques for Structural Characterization; 3.5 Preparation of Supramolecular Structures with 2,4-Diamino-6-R-1,3,5-triazines and Ag(I); 3.5.1 Synthesis3.5.2 X-Ray Structure Determination3.5.3 Structural Characterization in Solution by NMR; 3.6 Conclusions; References; 4 Chiral Metallocycles for Asymmetric Catalysis; 4.1 Introduction; 4.2 Thermodynamically-Controlled Metallocycles; 4.3 Kinetically-Controlled Metallocycles; 4.4 General Synthetic Strategies for Chiral Metallocycles; 4.5 Self- and Directed-Assembly of Chiral Pt-Alkynyl Metallocycles; 4.6 Chiral Pt-Alkynyl Metallocycles for Asymmetric Catalysis; 4.7 Concluding Remarks; References; 5 Catalysis of Acyl Transfer Processes by Crown-Ether Supported Alkaline-Earth Metal Ions5.1 IntroductionIn the past few years, supramolecular chemistry has led to new approaches in homogeneous catalysis. While host-guest chemistry had already found applications in catalysis as a result of the pioneering work carried out by Professor Ronald Breslow and Nobel prizewinner Professor Jean-Marie Lehn that began some 40 years ago, the construction of catalysts by supramolecular forces has only recently become a powerful tool. This development paves the way for large numbers of new potential catalysts that can be varied in an expedient way by changing the constituting building blocks.Written by someCatalysisSupramolecular chemistryCatalysis.Supramolecular chemistry.541.395Leeuwen P. W. N. M. van(Piet W. N. M.),MiAaPQMiAaPQMiAaPQBOOK9910146268103321Supramolecular Catalysis2819151UNINA