05744nam 2200745 a 450 991014623700332120170809173107.01-280-52055-897866105205583-527-60546-03-527-60248-8(CKB)1000000000019376(EBL)481643(OCoLC)68940779(SSID)ssj0000104992(PQKBManifestationID)11128570(PQKBTitleCode)TC0000104992(PQKBWorkID)10086091(PQKB)10106765(MiAaPQ)EBC481643(EXLCZ)99100000000001937620040521d2004 uy 0engur|n|---|||||txtccrAqueous-phase organometallic catalysis[electronic resource] concepts and applications /edited by Boy Cornils and Wolfgang A. Herrmann2nd, completely rev. and enl. ed.Weinheim Wiley-VCHc20041 online resource (782 p.)Green chemistryDescription based upon print version of record.3-527-30712-5 Includes bibliographical references and index.Aqueous-Phase Organometallic Catalysis; Preface to the Second Edition; Preface to the First Edition; Contents; Contributors; 1 Introduction; 1 Introduction; 2 Basic Aqueous Chemistry; 2.1 Organic Chemistry in Water; 2.1.1 Introduction; 2.1.2 Origin of the Reactivity in Water; 2.1.3 Pericyclic Reactions; 2.1.3.1 Diels - Alder Reactions; 2.1.3.2 Hetero Diels - Alder Reactions; 2.1.3.3 Other Cycloadditions; 2.1.3.4 Claisen Rearrangements; 2.1.4 Carbonyl Additions; 2.1.4.1 Aldol-type Reactions; 2.1.4.2 Michael-type Reactions; 2.1.4.3 Allylation Reactions; 2.1.5 Oxido-reductions2.1.5.1 Oxidations2.1.5.2 Reductions; 2.1.6 Radical Reactions; 2.1.7 Outlook; 2.2 Organometallic Chemistry in Water; 2.2.1 Introduction; 2.2.2 Water as a Solvent and Ligand; 2.2.3 Organometallic Reactions of Water; 2.2.4 Catalytic Reactions with Water; 2.2.4.1 Water-gas Shift Reaction; 2.2.4.2 Wacker- Hoechst Acetaldehyde Process; 2.2.4.3 Olefin Hydration; 2.2.4.4 Hydrodimerization; 2.2.5 Water-soluble Metal Complexes; 2.2.6 Perspectives; 2.3 Characterization of Organometallic Compounds in Water; 2.3.1 Introduction; 2.3.2 General Survey2.3.3 Effect of High Hydrostatic Pressure on Aqueous Organometallic Systems2.3.4 Aqueous Organometallics with Pressurized Gases; 2.3.5 Concluding Remarks; 3 Catalysts for an Aqueous Catalysis; 3.1 Variation of Central Atoms; 3.1.1 Transition Metals; 3.1.1.1 Introduction; 3.1.1.2 Water-soluble Catalysts by Virtue of Water-soluble Ligands; 3.1.1.3 Water-soluble Catalysts through Water Coordination; 3.1.2 Lanthanides in Aqueous-phase Catalysis; 3.1.2.1 Introduction; 3.1.2.2 Aldol Reactions; 3.1.2.3 Mannich-type Reactions; 3.1.2.4 Diels - Alder Reactions; 3.1.2.5 Micellar Systems3.1.2.6 Asymmetric Catalysis in Aqueous Media3.1.2.7 Conclusions; 3.2 Variation of Ligands; 3.2.1 Monophosphines; 3.2.1.1 General Features, Scope, and Limitations; 3.2.1.2 Anionic Phosphines; 3.2.1.3 Cationic Phosphines; 3.2.1.4 Nonionic Water-soluble Phosphines; 3.2.2 Diphosphines and Other Phosphines; 3.2.2.1 General; 3.2.2.2 Diphosphines - Introduction of Sulfonate Groups by Direct Sulfonation; 3.2.2.3 Introduction of Sulfonate Groups During Synthesis; 3.2.2.4 Diphosphines with Quaternized Aminoalkyl or Aminoaryl Groups; 3.2.2.5 Diphosphines with Hydroxyalkyl or Polyether Substituents3.2.2.6 Carboxylated Diphosphines3.2.2.7 Amphiphilic Diphosphines; 3.2.2.8 Other Phosphines; 3.2.3 Ligands or Complexes Containing Ancillary Functionalities; 3.2.3.1 Complexes Containing at Least Two Classical Functionalities; 3.2.3.2 Cationic Complexes; 3.2.3.3 Immobilization on Silica Supports; 3.2.3.4 Macromolecular Ligands or Supports; 3.2.3.5 Ligands not Containing Phosphorus; 3.2.3.6 Additional Perspectives; 3.2.4 Tenside Ligands; 3.2.4.1 Introduction; 3.2.4.2 Tenside Phosphines and Amines; 3.2.4.3 Hydroformylation Reactions Catalyzed by Transition Metal Surfactant - Phosphine Complexes3.2.4.4 Hydrogenation Reactions Catalyzed by Transition Metal Surfactant - Phosphine ComplexesNow in its second completely revised and expanded edition. Written by the renowned editors B. Cornils and W. A. Herrmann, this book presents every important aspect of aqueous-phase organometallic catalysis, a method which saves time, waste and money. The large-scale application of this ""green"" technology in chemical industry clearly underlines its practical use outside of academia.New chapters (for example ""Organic Chemistry in Water""), 20% more content and fully updated contributions from by a plethora of international authors make this book a ""must-have"" for everyone working in thiGreen chemistry (Weinheim, Germany)CatalysisMetal catalystsWater-soluble organometallic compoundsCatalystsRecyclingHeterogeneous catalysisElectronic books.Catalysis.Metal catalysts.Water-soluble organometallic compounds.CatalystsRecycling.Heterogeneous catalysis.660.2995660/.2995Cornils Boy498393Herrmann W. A(Wolfgang A.)873820MiAaPQMiAaPQMiAaPQBOOK9910146237003321Aqueous-phase organometallic catalysis1950684UNINA