05114nam 2200625 a 450 991014603010332120170815110150.03-527-62041-91-283-83495-23-527-62077-X3-527-61993-3(CKB)1000000000417221(EBL)819499(OCoLC)815648594(SSID)ssj0000354581(PQKBManifestationID)11267483(PQKBTitleCode)TC0000354581(PQKBWorkID)10314678(PQKB)11401904(MiAaPQ)EBC819499(EXLCZ)99100000000041722119931102d1994 uy 0engur|n|---|||||txtccrOrganosilicon chemistry[electronic resource] from molecules to materials /edited by Norbert Auner, Johann WeisWeinheim ;New York VCHc19941 online resource (374 p.)Description based upon print version of record.3-527-29061-3 Includes bibliographical references and indexes.Organosilicon Chemistry From Molecules to Materials; Contents; Tetravalent Organosilicon Compounds: Chemistry and Structure; Introduction; Structures of Small Silicon Containing Compounds - Why and How?; Sterically Overcrowded Organosilicon Compounds and their Properties; Synthesis of Functionally Substituted Oligosilanes Based on Silyltriflate Derivatives; Electroreductive Formation of Di- and Polysilanes; Linear Tetrasilanes with Internal Substituents: Oligosilanes with Optical Activity; A New Way to Si-Ge and Si-Sn Bonds: Hexachlorodisilane Cleavage of Organometal Phosphanes29Si29Si-Coupling Constants of Bromo- and Iododisilanes and -trisilanes XnSi2H6-n and XnSi3H8-n (X = Br, I)Calculation of the 29 Si NMR Chemical Shifts in Molecules with SIN, SiCl, and SiSi Bonds; Reactivity of Very Electron-Rich Organosilyl Amines; Lithiated Aminofluorosilanes as Precursors for Monomeric and Dimeric Iminosilanes; Fluorofunctional Silylamines and -Hydrazines Precursors for (Si-N) Ring Systems; New Approaches to (Fluoromethyl)silanes; Homo- and heterocyclic Si-O-Systems . Rings and CagesSilaheterocycles from Intramolecular Reactions of Silicon-functionalized Diazoacetic EstersSynthesis and Reaction Behavior of Organoalkoxysilylphenols; N-Silylation: New Possibilities for Long-known Amines; On the Acid-catalyzed Reaction of Siloxanes with Alcohols; On the Reactivity of Chlorosiloxanes; Chlorosilanols - more stable than you think - shown with 29Si NMR; Diorganosilyl-bis(O-alkylphosphonates); Subvalent and Unsaturated Organosilicon Compounds: Formation and Reactivity; Introduction; Basic Principles of the Theory of Bonding in Silicon CompoundsExpectations from an Unusual Compound: The Chemistry of DecamethylsilicoceneCp*2Si(CO) and CP*2Si(N2): Complexes of Decamethylsilicocene; Silicon and Phosphinomethanides: A Novel Entry to Hypervalent and Low Valent Organosilicon Chemistry; Neopentylsilenes: Laboratory Curiosities or Useful Building Blocks for the Synthesis of Silaheterocycles ?; Synthesis and Thermolysis Reactions of Si-functionalized 2-Silaazetidines; Reactions of Silaethenes in the Gas Phase and in Solution; The Reaction of Vinylsilanes with Lithium Metal; Small Silicon Ring Compounds: Formation and ReactionsMatrix Photolysis of Simple AzidosilanesLow-coordinated Si-Compounds: Gas Phase Reactions with Heterosubstituted Silylenes; Unusual Coordination in Phosphorus-Silicon Compounds; Unsaturated Silicon Compounds: Matrix IR Investigations and Quantum Chemical Calculations; Hypervalent Organosilicon Compounds: Formation, Structure and Chemistry; Introduction; Reactivity of Penta- and Hexacoordinated Silicon Species; Compounds with High Coordination Numbers at Silicon: Models for the Investigation of the Nucleophilic Substitution Reaction at Silicon CentersOrganosilicon Metal Compounds: Coordination Chemistry and CatalysisDo you need to know what's new in organosilicon chemistry? This book provides in-depth coverage of the latest developments in this interdisciplinary and fast-evolving field:- selectivity and reactivity of organosilicon compounds - new synthetic applications- structure and bonding- applications in materials and polymer scienceWritten by leading experts, this book is a well-referenced and critical overview of modern silicon chemistry.'I recommend this book to the student and the practitioner in this new, very different, and very exciting field'. Eugene G. Organosilicon compoundsElectronic books.Organosilicon compounds.547547.08547/.08Auner Norbert906518Weis Johann963192MiAaPQMiAaPQMiAaPQBOOK9910146030103321Organosilicon chemistry2183916UNINA