05291nam 2200661Ia 450 991014596560332120170815110054.01-282-00187-697866120018710-470-40370-50-470-40369-1(CKB)1000000000718582(EBL)416156(OCoLC)476247104(SSID)ssj0000117745(PQKBManifestationID)11141825(PQKBTitleCode)TC0000117745(PQKBWorkID)10050569(PQKB)11370422(MiAaPQ)EBC416156(PPN)242555047(EXLCZ)99100000000071858220090301d2009 uy 0engur|n|---|||||txtccrCarbon materials for catalysis[electronic resource] /edited by Philippe Serp, José Luís FigueiredoHoboken, N.J. John Wiley & Sonsc20091 online resource (603 p.)Description based upon print version of record.0-470-17885-X Includes bibliographical references and index.CARBON MATERIALS FOR CATALYSIS; Contents; Contributors; Preface; 1 Physicochemical Properties of Carbon Materials: A Brief Overview; 1.1. Introduction; 1.2. Formation of Carbons; 1.2.1. Gas Phase; 1.2.2. Liquid Phase; 1.2.3. Solid Phase; 1.3. Structure and Properties of Carbons; 1.3.1. Macrostructure; 1.3.2. Microstructure; 1.3.3. Nanostructure; 1.3.4. Bulk Properties; 1.3.5. Surface Properties; 1.4. Reactions of Carbons; 1.4.1. Gas Phase; 1.4.2. Liquid Phase; 1.4.3. Solid Phase; 1.5. Conclusions; References; 2 Surface Chemistry of Carbon Materials; 2.1. Introduction2.2. Surface Functionalities2.2.1. Oxygen-Containing Functionalities; 2.2.2. Nitrogen-Containing Functionalities; 2.2.3. Hydrogen-Carbon Species; 2.2.4. Sulfur, Phosphorus, and Halogen Functionalities; 2.3. Surface Modifications; 2.3.1. Oxidation; 2.3.2. Introduction of Nitrogen-Containing Species; 2.3.3. Introduction of Sulfur Functionality; 2.3.4. Halogenization; 2.3.5. Impregnation and Dry Mixing; 2.3.6. Heat Treatment; 2.4. Characterization of Surface Chemistry; 2.4.1. Elemental Analysis; 2.4.2. Titration; 2.4.3. pH of Carbons, Point of Zero Charge, and Isoelectric Point2.4.4. Spectroscopic Methods2.4.5. Calorimetric Techniques; 2.4.6. Inverse Gas Chromatography; 2.4.7. Temperature-Programmed Desorption; 2.4.8. Characterization of Surface Functionalities by Electrochemical Techniques; 2.5. Role of Surface Chemistry in the Reactive Adsorption on Activated Carbons; 2.6. Role of Carbon Surface Chemistry in Catalysis; References; 3 Molecular Simulations Applied to Adsorption on and Reaction with Carbon; 3.1. Introduction; 3.2. Molecular Simulation Methods Applied to Carbon Reactions; 3.2.1. Electronic Structure Methods (or Quantum Mechanics Methods)3.2.2. Molecular Dynamics Simulations3.2.3. Monte Carlo Simulations; 3.3. Hydrogen Adsorption on and Reaction with Carbon; 3.3.1. Atomic Hydrogen Adsorption on the Basal Plane of Graphite; 3.3.2. Reactivities of Graphite Edge Sites and Hydrogen Reactions on These Sites; 3.3.3. Hydrogen Storage in Carbon Nanotubes; 3.4. Carbon Reactions with Oxygen-Containing Gases; 3.4.1. Carbon Reactions with Oxygen-Containing Gases and the Unified Mechanism; 3.4.2. Catalyzed Gas-Carbon Reactions; 3.4.3. More Specific Studies on NO(x), H(2), CO(2), and O(2)-Carbon Reactions; 3.5. Metal-Carbon Interactions3.6. ConclusionsReferences; 4 Carbon as Catalyst Support; 4.1. Introduction; 4.2. Properties Affecting Carbon's Role as Catalyst Support; 4.2.1. Surface Area and Porosity; 4.2.2. Surface Chemical Properties; 4.2.3. Inertness; 4.3. Preparation of Carbon-Supported Catalysts; 4.3.1. Impregnation; 4.3.2. Other Methods; 4.4. Applications; 4.4.1. Ammonia Synthesis; 4.4.2. Hydrotreating Reactions; 4.4.3. Hydrogenation Reactions; 4.5. Summary; References; 5 Preparation of Carbon-Supported Metal Catalysts; 5.1. Introduction; 5.2. Impregnation and Adsorption5.2.1. Interaction Between Support and PrecursorThis is the first comprehensive book covering all aspects of the use of carbonaceous materials in heterogeneous catalysis. It covers the preparation and characterization of carbon supports and carbon-supported catalysts; carbon surface chemistry in catalysis; the description of catalytic, photo-catalytic, or electro-catalytic reactions, including the development of new carbon materials such as carbon xerogels, aerogels, or carbon nanotubes; and new carbon-based materials in catalytic or adsorption processes. This is a premier reference for carbon, inorganic, and physical chemists, materials scCarbonCatalysisCarbon.Catalysis.660660.2995660/.299535.17bclFigueiredo José Luís985029Serp Philippe983393MiAaPQMiAaPQMiAaPQBOOK9910145965603321Carbon materials for catalysis2250814UNINA