02630nam 2200553 450 991014432870332120221001094005.01-280-52013-297866105201383-527-60426-X3-527-60498-7(CKB)1000000000376386(EBL)481968(OCoLC)68626736(SSID)ssj0000245756(PQKBManifestationID)11208511(PQKBTitleCode)TC0000245756(PQKBWorkID)10176990(PQKB)11289334(MiAaPQ)EBC481968(MiAaPQ)EBC6892659(Au-PeEL)EBL6892659(EXLCZ)99100000000037638620221001d2005 uy 0engur|n|---|||||txtccrSide reactions in organic synthesis a guide to successful synthesis design /Florencio Zaragoza DörwaldWeinheim :WILEY-VCH Verlag,2005.1 online resource (392 p.)Description based upon print version of record.3-527-31021-5 Includes bibliographical references and index.Organic synthesis : general remarks. -- Stereoelectronic effects and reactivity. -- The stability of organic compounds. -- Aliphatic nucleophilic substitutions : problematic electrophiles. -- The alkylation of carbanions. -- The alkylation of heteroatoms. -- The acylation of heteroatoms. -- Palladium-catalyzed C-C bond formation. -- Cyclizations. -- Monofunctionalization of symmetric difunctional substrates.Most syntheses in the chemical research laboratory fail and usually require several attempts before proceeding satisfactorily. Failed syntheses are not only discouraging and frustrating, but also cost a lot of time and money. Many failures may, however, be avoided by understanding the structure-reactivity relationship of organic compounds.This textbook highlights the competing processes and limitations of the most important reactions used in organic synthesis. By allowing chemists to quickly recognize potential problems this book will help to improve their efficiency and success-rate. A muOrganic compoundsSynthesisElectronic books.Organic compoundsSynthesis.547.2Dörwald Florencio Zaragoza875082MiAaPQMiAaPQMiAaPQBOOK9910144328703321Side reactions in organic synthesis2074339UNINA