05122nam 2200649Ia 450 991014432760332120201210094149.01-282-30554-997866123055420-470-13258-20-470-13293-0(CKB)1000000000376289(EBL)469419(OCoLC)746577015(SSID)ssj0000299768(PQKBManifestationID)11248731(PQKBTitleCode)TC0000299768(PQKBWorkID)10243645(PQKB)11755605(MiAaPQ)EBC469419(PPN)243188765(EXLCZ)99100000000037628920750907d1990 uy 0engur|n|---|||||txtccrInorganic synthesesVolume 27[electronic resource] /editor-in-chief, Alvin P. GinsbergNew York McGraw Hill19901 online resource (463 p.)Inorganic syntheses ;27Description based upon print version of record.0-471-50976-0 Includes bibliographical references and and index.INORGANIC SYNTHESES; CONTENTS; Chapter One TRANSITION METAL POLYHYDRIDE COMPLEXES; 1. Molecular Hydrogen Complexes of Mo and W; A. Tricarbonyl(dihydrogen)bis(tricyclohexylphosphine)-molybdenum; B. Tricarbonyl(q6-cycloheptatriene)tungsten; C. Tricarbonyl(dihydrogen)bis-(tricyclohexy1phosphine)tungsten; D. Tricarbonyl(dihydrogen)bis-(triisopropylphosphine)tungsten; 2. Molybdenum and Tungsten Phosphine Polyhydrides; A. Tetrahydridotetrakis(methyldiphenylphosphine)- molybdenum(IV); B. Tetrahydridotetrakis(methyldiphenylphosphine)- tungsten(IV)C. Hexahydridotris(dimethylphenylphosphine)tungsten(VI)D. Hexahydridotris(tricyclohexylphosphine)molybdenum(VI); 3. Haptahydridobis(triphenylphosphine)rhenium(VII) and Octahydridotetrakis(triphenylphosphine)dirhenium(IV); A. Heptahydridobis(triphenylphosphine)rhenium(VII); B. Octahydridotetrakis(triphenylphosphine)dirhenium(IV); C. Octahydridotetrakis(triphenylphosphine)dirhenium(IV); 4. Tetrahydrido(n5-pentamethylcyclopentadienyI)iridium5. Tris[1,3-bis(diphenylphosphino)propane]- heptahydridotriiridium(2 + ) Bis(tetrafluoroborate) and Bis[ t,3-bis(diphenylphosphino)propane]-pentahydridodiiridium( 1 + ) TetrafluotoborateA. (q-I, 5-cyclooctadiene)[1, 3-Bis(diphenylphosphino)- propane]iridium Tetrafluoroborate; B. [Ir3(dppp)3H7[BF4]2 and [Ir2(dppp)2H5][BF4]; 6. Heterobimetallic Hydride Complexes; A. mer-Trichlorotris(dimethylphenylphosphine)osmium(III); B. Bis[1, 1(q5)-Cyclopentadienyl]-tris(dimethylphenylphosphine-2kP)-tri-u-hydrido1 -hydridoosmiumzirconiumC. [2(q4)-l, 5-Cyclooctadienel-tris(dimethylphenylphosphine- 1 kP)-tri-u-hydridoosmiumrhodium7. u-Hydrido-tetrakis(tertiary phosphine)diplatinum Cations; A. u-Hydrido-dihydridotetrakis(triethylphosphine)-diplatinum(I1) Tetraphenylborate( 1 -); B. Di-u-hydrido-hydridotetrakis(triethylphosphine)-diplatinum(I1) Tetraphenylborate(1 - ); C. Di-u-hydrido-hydridotetrakis(triphenylphosphine)-diplatinum(I1) Tetraphenylborate( 1 -); Chapter Two TRANSITION METAL CHALCOGENIDE COMPLEXES; 8. Tetraphenylphosphonium Salts of [Mo2(S)n(S2)6-n]2 - Thioanions and DerivativesA. Bis(tetraphenylphosphonium) Tetrathiomolybdate(VI), (Ph4P)2[MoS4]B. (Ph4P)2[(Mo2S10)0.72(Mo2S12)0.28]1/2HC0N(CH3)2; C. Bis(tetraphenylphosphonium) Di-u-thio-tetrathiodimolybdate(V), (Ph4P)2[MO2S6]; D. Bis(tetraphenylphosphonium) (q2-Disulfido)- di-u-thio-trithiodimolybdate(IV, VI),; E. Bis(tetraphenylphosphonium) Bis(q2-disulfido)-di-u-thio-dit hiodimoly bdate(V), (Ph4P)2 [ Mo2S8]; 9. Molybdenum-Sulfur Clusters; A. Diammonium Tris(u-disulfido)tris(disulfido)-u3-thio-rtianguto-trimolybdate(IV) Hydrate; B. Diammonium Bis(u-disulfido)tetrakis(disulfido)-dimolybdate(V) DihydrateC. Diammonium Tris(p-disulfido)tris(disulfido)-u3-thio- triangulo-trimolybdate(IV) Hydrate and Diammonium Bis(u-disulfido)-tetrakis(disulfido)dimolybdate(V) DihydrateThe volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.Inorganic SynthesesInorganic compoundsSynthesisChemistry, InorganicInorganic compoundsSynthesis.Chemistry, Inorganic.541.3541/.39Ginsberg Alvin P961463MiAaPQMiAaPQMiAaPQBOOK9910144327603321Inorganic syntheses2179704UNINA