05472nam 2200661Ia 450 991014432010332120170810192827.01-282-30845-997866123084510-470-14528-50-470-14549-8(CKB)1000000000376308(EBL)468910(OCoLC)814412967(SSID)ssj0000299754(PQKBManifestationID)11224335(PQKBTitleCode)TC0000299754(PQKBWorkID)10243069(PQKB)11242972(MiAaPQ)EBC468910(EXLCZ)99100000000037630819910826d1991 uy 0engur|n|---|||||txtccrThe formation of bonds to Group-I, -II, and -IIIB elements[electronic resource] /founding editor J.J. Zuckerman; editor, A.P. HagenNew York VCH Publishersc19911 online resource (602 p.)Inorganic reactions and methods ;v. 13Description based upon print version of record.0-471-18664-3 Includes bibliographical references and indexes.Inorganic Reactions and Methods; Contents; How to use this book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 13; Formation of the Bonds to Group-IIIB (B, Al, Ga, In, TI) Elements; Introduction; Formation of the Group-IIIB- Group-IIIB Element (B, Al, Ga, In, TI) Bond; Introduction; from Group-IllB Halides; by Comproportionation with the Group-IllB Element or Its Univalent State; by Reduction with Metals; by Disproportionation of Dinuclear Compounds; by Metal Atom and Related Reactions; in Combination with Group-VIB Elementsfrom Group-IIIB-Group-IVB Bondsfrom Gallium in Halogen Acid Media; Formation of Group-IIIB-Group IA or Group-IIA Bonds; Formation of Group Ill-B-Group-IB or Group-IIB Bonds; Formation of Group-IIIB-Transition- or -inner Transition-Metal Bonds; Introduction; Formation from Group-IIIB Halides; by Reaction with Neutral Metal Bases; by Reaction with Anionic Metal Bases; by Oxidative-Addition Reactions; Formation from Other Group-IIIB Compounds; by Reaction with Neutral Metal Bases; by Reaction with Anionic Metal Bases; by Oxidative Addition Reactions.; by Reaction with Metal HalidesThe Formation of the Group Ill-Group 0 Element BondFormation of Borides; Introduction; Existence and Crystal Chemistry of Borides; Borides with Isolated Boron Atoms; Metal Frame Structures -Topological Packed Structures.; Substitutional Metal Borides.; Metal Boride Structures (Isolated Boron Atoms).; Borides with Boron Chains; Structure Types with Chain Fragments' (B2, B3, B4 Groups).; Ternary Borides with Boron-Boron Chain Formation.; Borides with Two-Dimensional Boron Networks; Borides with Three-Dimensional Boron Networks; ThB4-Type Tetraborides.; CaB6-Type Hexaborides.UB12-Type Dodecaborides.YB66-Type Borides.; Other Types.; Summary.; Solid Solution of Transition and Inner Transition Metals in Boron; The Solubility in the Various Modifications of Boron.; Solid Solutions in B-Rhombohedral Boron.; Crystallographic Data on Solid Solutions of B-Rhombohedral Boron.; Preparation of Borides; by Direct Combination of the Elements; by Reduction of a Metal Compound and Boron Halide with Hydrogen; by Fused-Salt Electrolysis; by Reduction of a Metal Oxide or Other Metal Compound Using Carbon, Boron or Boron Carbideby Reduction of Boron Oxide or Boron Halides with Metalsby Low-Temperature Precipitation of Borides from Solution; by Other Methods; Crystal Growth of Borides; by Gas-Phase Methods; by Chemical Vapor Deposition (CVD).; Crystal Growth of Borides by Chemical Vapor Transport.; Liquid-Phase Method; Crystal Pulling.; Floating-Zone Technique.; Flame-Fusion Technique.; Flux Methods; Sintering Methods; Sintering of Pure Borides; Comminution of Powders.; Compacting or Molding of Powders.; Sintering: Miscellaneous.; Sintering: Characteristics.; Sintering of Boride-Metal Composites.Hot Pressing of Pure BoridesHow to use this book. Preface to the Series. Editorial Consultants to the Series. Contributors to Volume 13. 6. Formation of the Bonds to Group-IIIB (B, AI, Ga, In, TI) Elements. 6.1. Introduction. 6.2. Formation of the Group-IIIB-Group-IIIB Element (B, AI, Ga, In, TI) Bond. 6.2.1. Introduction. 6.2.2. from Group-IIIB Halides. 6.2.2.1. by Comproportionation with the Group-IIIB Element or Its Univalent State. 6.2.2.2. by Reduction with Metals. 6.2.2.3. by Disproportionation of Dinuclear Compounds. 6.2.2.4. by Metal Atom and Related Reactions. 6.2.3. in Combination with Group-VIB Elements. 6.2.4Inorganic Reactions and MethodsChemical kineticsEffect of temperature onInorganic compoundsSynthesisElectronic books.Chemical kineticsEffect of temperature on.Inorganic compoundsSynthesis.541.3/9541.39Hagen A. P857124Zuckerman J. J(Jerold J.),1936-1987.857123MiAaPQMiAaPQMiAaPQBOOK9910144320103321The formation of bonds to Group-I, -II, and -IIIB elements2179702UNINA