04923nam 2200685Ia 450 991014428600332120170810191508.01-282-30723-197866123072320-470-18735-20-470-18887-1(CKB)1000000000376591(EBL)469121(OCoLC)746577067(SSID)ssj0000339386(PQKBManifestationID)11256682(PQKBTitleCode)TC0000339386(PQKBWorkID)10323840(PQKB)10146950(MiAaPQ)EBC469121(EXLCZ)99100000000037659119890728d1991 uy 0engur|n|---|||||txtccrIsoxazolesPart one[electronic resource] /Paolo Grünanger, Paola Vita-FinziNew York John Wiley & Sons19911 online resource (904 p.)Chemistry of heterocyclic compounds,0069-3154 ;v. 49Description based upon print version of record.0-471-02233-0 Includes bibliographical references and indexes.ISOXAZOLES; The Chemistry of Heterocyclic Compounds Introduction to the Series; Preface; Contents; CHAPTER 1; 1. Isoxazoles; 1.1 Introduction; 1.2 Physicochemical Properties; 1.2.1 Infrared Spectra; 1.2.2 Ultraviolet Spectra; 1.2.3 Nuclear Magnetic Resonance Spectra; 1.2.3.1 PMR Spectra; 1.2.3.2 I3C-NMR Spectra; 1.2.3.3 I4N- and ""N-NMR Spectra; 1.2.3.4 Other Nuclei NMR Spectra; 1.2.4 Mass Spectra; 1.2.5 Other Spectra; 1.2.5.1 Microwave Spectra; 1.2.5.2 Photoelectron Spectra; 1.2.5.3 Electron Paramagnetic Resonance Spectra; 1.2.5.4 Electron Spin Resonance Spectra1.2.5.5 Nuclear Quadrupole Resonance Spectra1.2.5.6 Other Spectra; 1.2.6 Crystal and Molecular Structure; 1.2.7 Dipole Moments; 1.2.8 Theoretical Calculations; 1.2.8.1 Reactivity, Aromaticity, and Electron Density; 1.2.8.2 Molecular Geometry; 1.2.8.3 Basicity and Dipole Moments; 1.2.8.4 Ionization Potentials; 1.2.8.5 Molecular Core Binding Energy; 1.2.8.6 Spectroscopic Data and Conformational Analysis; 1.2.9 Basicity; 1.2.10 Miscellaneous Data; 1.2.11 Analytical Methods; 1.3 Methods of Preparation; 1.3.1 [CCC + NO] Processes; 1.3.1.1 Oximation of 1, 3-Dicarbonyl (and Related) Compounds1.3.1.2 Oximation of a-Acetylenic Carbonyl (and Related) Compounds1.3.1.3 Oximation of a-Dihalocarbonyl (and Related) Compounds; 1.3.1.4 Oximation of z, 8-Ethylenic Carbonyl (and Related) Compounds 8-Substituted with Electron-Withdrawing Groups; 1.3.1.5 Oximation of a, b-Ethylenic Carbonyl (and Related) Compounds; 1.3.1.6 Other Oximation Reactions; 1.3.1.7 Synthesis from Unsaturated Compounds and Nitric (Nitrous) Acid; 1.3.1.8 Nitrosation of Ketodicarboxylic Esters; 1.3.2 [CNO + CC] Processes; 1.3.2.1 Cycloaddition of Nitrile Oxides (or Their Precursors) to Acetylenic Compounds1.3.2.2 Cycloaddition of Nitrile Oxides (or Their Precursors) to Ethylenic Compounds1.3.2.3 Cycloaddition of Nitrile Oxides (or Their Precursors) with Active Methylene Compounds; 1.3.2.4 Cycloaddition of Nitrile Oxides (or Their Precursors) with Sodium Acetylides or Acetylenic Grignard Reagents; 1.3.2.5 Other [CNO + CC] Processes; 1.3.3 [CNO + 2C] Processes: Syntheses from Nitro Derivatives; 1.3.4 [CCNO + C] Processes; 1.3.4.1 Synthesis from Oxime Dilithium Salts and Carboxylic Acid Derivatives; 1.3.4.2 Reaction of a-Chloroketoximes with Ylides; 1.3.5 [CCCN + O] Process1.3.6 Cyclization Processes1.3.6.1 [OCCCN] Processes; 1.3.6.2 [CCCON] Processes; 1.3.6.3 [CCNOC] Processes; 1.3.6.4 [CCCNO] Processes; 1.3.7 From Heterocyclic Compounds; 1.3.7.1 From Other 1, 2-Oxazole Derivatives; 1.3.7.2 From Other Heterocycles; 1.4 Chemical Properties; 1.4.1 Protonation and Quaternization; 1.4.2 Complexation; 1.4.2.1 Metallic Complexes; 1.4.2.2 Molecular Complexes; 1.4.3 Reduction Reactions; 1.4.3.1 Hydrogenolytic Ring Cleavage; 1.4.3.2 Reductions without Ring Cleavage; 1.4.4 Oxidation Reactions; 1.4.5 Thermolysis and Photolysis; 1.4.6 Reactions with Nucleophiles1.4.6.1 Reactions with Ring CleavageIsoxazoles. Isoxazolines (Dihydroisoxazoles). Isoxazolidines (Tetrahydroisoxazoles). References. Index.Chemistry of heterocyclic compounds ;v. 49.OxazolesChemistryElectronic books.Oxazoles.Chemistry.547.592547/.59/05547/.592Grünanger Paolo347683Vita-Finzi Paola51885Dowling James Edward1966-978679MiAaPQMiAaPQMiAaPQBOOK9910144286003321Isoxazoles2230625UNINA