05207nam 2200625Ia 450 991014428000332120170814190141.01-281-75871-X97866117587143-527-61559-83-527-61558-X(CKB)1000000000376625(EBL)481639(OCoLC)262833456(SSID)ssj0000154289(PQKBManifestationID)11162739(PQKBTitleCode)TC0000154289(PQKBWorkID)10417503(PQKB)10647605(MiAaPQ)EBC481639(EXLCZ)99100000000037662519941020d1995 uy 0engur|n|---|||||txtccrFerrocenes[electronic resource] homogeneous catalysis, organic synthesis, materials science /edited by Antonio Togni and Tamio HayashiWeinheim ;New York VCH Publishersc19951 online resource (562 p.)Description based upon print version of record.3-527-29048-6 Includes bibliographical references and index.Ferrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mössbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via π-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of α-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic α-Thio- and α-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis4.3.1.3 From the Chiral PoolWith applications ranging from asymmetric catalysis to magnetic materials, ferrocene is one of the most versatile building blocks in synthesis. This book captures the multidisciplinary nature of ferrocene research, including topics such as ferrocene-containing polymers, ferrocene-containing thermotropic liquid crystals, chiral ferrocene derivatives, and ferrocene-containing charge-transfer materials.In addition, the reader will find* valuable information for planning syntheses* over 70 tables, making relevant data available at a glance * carefully selected references, proviFerroceneOrganoiron compoundsElectronic books.Ferrocene.Organoiron compounds.547.05621Togni Antonio863256Hayashi Tamio92745MiAaPQMiAaPQMiAaPQBOOK9910144280003321Ferrocenes1926978UNINA