05268nam 2200673 450 991014410970332120170816111721.01-281-94705-997866119470573-527-62285-33-527-62286-1(CKB)1000000000552623(EBL)482371(OCoLC)283799094(SSID)ssj0000202432(PQKBManifestationID)11166376(PQKBTitleCode)TC0000202432(PQKBWorkID)10255068(PQKB)11252723(MiAaPQ)EBC482371(PPN)18240630X(EXLCZ)99100000000055262320160819h20082008 uy 0engur|n|---|||||txtccrMicroreactors in organic synthesis and catalysis /edited by Thomas WirthWeinheim, [Germany] :Wiley-VCH Verlag GmbH & Co. KGaA,2008.©20081 online resource (299 p.)Description based upon print version of record.3-527-31869-0 Includes bibliographical references at the end of each chapters and index.Microreactors in Organic Synthesis and Catalysis; Contents; Preface; List of Contributors; 1 Fabrication of Microreactors Made from Metals and Ceramics; 1.1 Manufacturing Techniques for Metals; 1.1.1 Etching; 1.1.2 Machining; 1.1.3 Generative Method: Selective Laser Melting (SLM); 1.1.4 Metal-Forming Techniques; 1.1.5 Assembling and Bonding of Metal Microstructures; 1.2 Ceramic Devices; 1.2.1 Joining and Sealing; References; 2 Fabrication and Assembling of Microreactors Made from Glass and Silicon; 2.1 How Microreactors are Constructed; 2.2 Glass as Material; 2.3 Silicon as Material2.4 The Structuring of Glass and Silicon2.5 Structuring by Means of Masked Etching in Microsystems Technology; 2.6 Etching Technologies; 2.6.1 Anisotropic (Crystallographic) Wet Chemical Etching of Silicon (KOH); 2.6.2 Isotropic Wet Chemical Etching of Silicon; 2.6.3 Anisotropic Dry Etching of Silicon; 2.6.4 Isotropic Wet Chemical Etching of Silicon Glass; 2.6.5 Photostructuring of Special Glass; 2.7 Chip Removing Processing; 2.7.1 Drilling, Diamond Lapping, Ultrasonic Lapping; 2.7.2 Micropowder Blasting; 2.7.3 Summary; 2.8 Bonding Methods; 2.8.1 Anodic Bonding of Glass and Silicon2.8.2 Silicon Direct Bonding (Silicon Fusion Bonding)2.8.3 Glass Fusion Bonding; 2.9 Establishing Fluid Contact; 2.10 Other Materials; References; 3 Properties and Use of Microreactors; 3.1 Introduction; 3.2 Physical Characteristics of Microreactors; 3.2.1 Geometries; 3.2.2 Constructional Materials and Their Properties; 3.3 Fluid Flow and Delivery Regimes; 3.3.1 Fluid Flow; 3.3.2 Fluid Delivery; 3.3.3 Mixing Mechanisms; 3.4 Multifunctional Integration; 3.5 Uses of Microreactors; 3.5.1 Overview; 3.5.2 Unstable Intermediates Fast and Exothermic Reactions; 3.5.3 Precision Particle Manufacture3.5.4 Wider Industrial Context3.5.4.1 Sustainability Agenda; 3.5.4.2 Point-of-Demand Synthesis; References; 4 Organic Chemistry in Microreactors; 4.1 Homogeneous Reactions; 4.1.1 Acid-Promoted Reactions; 4.1.2 Base-Promoted Reactions; 4.1.3 Condensation Reactions; 4.1.4 Metal-Catalyzed Reactions; 4.1.5 Photochemical Reactions; 4.1.6 Electrochemical Reactions; 4.1.7 Miscellaneous; 4.1.7.1 Swern Oxidation; 4.1.7.2 Grignard Exchange Reaction; 4.1.7.3 Lithium-Halogen Exchange Reaction; 4.1.7.4 Phenyl Boronic Acid Synthesis; References; 4.2 Heterogeneous Reactions; 4.2.1 Introduction4.2.2 Concepts in Flow Mode Synthesis4.2.3 Methods of Conducting Flow Chemistry; 4.2.3.1 On-Bead Synthesis; 4.2.3.2 Solution-Phase Synthesis; 4.2.3.3 Library Synthesis in Flow; 4.2.3.4 Heterocycle Synthesis; 4.2.4 Introduction to Monoliths; 4.2.5 Transition Metal Chemistry Under Flow Conditions; 4.2.5.1 Reduction; 4.2.5.2 Oxidation; 4.2.5.3 Cross-Coupling Reactions; 4.2.5.4 Olefin Metathesis; 4.2.6 Enantioselective Reactions; 4.2.6.1 Hydrolytic Kinetic Resolution; 4.2.6.2 Organometallic Additions; 4.2.6.3 Enantioselective Diels-Alder Reactions; 4.2.6.4 Ene Reactions; 4.2.6.5 Cyclopropanation4.2.6.6 Asymmetric Conjugate AdditionThis one-stop reference is the first book on this emerging and rapid developing field with a focus on synthesis and catalysis. As such, it covers all aspects from academia and industry in a clearly structured way. Leading experts provide the background information as an initial aid for newcomers to the field, while chapters on different reaction types and industrial applications make this an equally vital resource for specialists.MicroreactorsOrganic compoundsSynthesisCatalysisMicroreactors.Organic compoundsSynthesis.Catalysis.547.2660.283235.52bclWirth Thomas1964-MiAaPQMiAaPQMiAaPQBOOK9910144109703321Microreactors in organic synthesis and catalysis2226369UNINA01590nas 2200337 n 450 99000905908040332120240229084440.0000905908FED01000905908(Aleph)000905908FED01000905908CNRP 0001344220161109a19639999km-y0itaa50------baengauu--------Soviet hydrology: Selected papers1963-Washington[s.n.]Soviet hydrology: Selected papers556American Geophysical UnionITACNP20090723http://acnp.cib.unibo.it/cgi-ser/start/it/cnr/dc-p1.tcl?catno=6193&person=false&language=ITALIANO&libr=&libr_th=unina1Biblioteche che possiedono il periodicoSE990009059080403321Biblioteca. Dipartimento di Ingegneria Idraulica, Geotecnica e Ambientale. Sede di via Claudio (Idraulica e Ambientale). Università degli studi di Napoli Federico II1963-1980;DINIDDINIDSoviet hydrology: Selected papers786590UNINA866-01NA120 Biblioteca. Dipartimento di Ingegneria Idraulica, Geotecnica e Ambientale. Sede di via Claudio (Idraulica e Ambientale). Università degli studi di Napoli Federico IIv. Claudio,21, Napoli (NA)(081) 7683431; fax 5938936itacnp.cib.unibo.itACNP Italian Union Catalogue of Serialshttp://acnp.cib.unibo.it/cgi-ser/start/it/cnr/df-p.tcl?catno=6193&language=ITALIANO&libr=&person=&B=1&libr_th=unina&proposto=NO