05385nam 22006854a 450 991014356790332120170810185100.01-280-28813-297866102881370-470-30216-X0-471-74931-10-471-74930-3(CKB)1000000000355885(EBL)243676(OCoLC)70821410(SSID)ssj0000187499(PQKBManifestationID)11939165(PQKBTitleCode)TC0000187499(PQKBWorkID)10134626(PQKB)10537206(MiAaPQ)EBC243676(PPN)143436740(EXLCZ)99100000000035588520050419d2005 uy 0engur|n|---|||||txtccrKinetics of materials[electronic resource] /Robert W. Balluffi, Samuel M. Allen, W. Craig Carter ; with editorial assistance from Rachel A. KemperHoboken, N.J. J. Wiley & Sons20051 online resource (673 p.)"Wiley-Interscience."0-471-24689-1 Includes bibliographical references and index.CONTENTS; Preface; Acknowledgments; Notation; S ymbols-Roman; Symbols-Greek; 1 Introduction; 1.1 Thermodynamics and Kinetics; 1.1.1 Classical Thermodynamics and Constructions of Kinetic Theories; 1.1.2 Averaging; 1.2 Irreversible Thermodynamics and Kinetics; 1.3 Mathematical Background; 1.3.1 Fields; 1.3.2 Variations; 1.3.3 Continuum Limits and Coarse Graining; 1.3.4 Fluxes; 1.3.5 Accumulation; 1.3.6 Conserved and Nonconserved Quantities; 1.3.7 Matrices, Tensors, and the Eigensystem; Bibliography; Exercises; PART I MOTION OF ATOMS AND MOLECULES BY DIFFUSION2 Irreversible Thermodynamics: Coupled Forces and Fluxes2.1 Entropy and Entropy Production; 2.1.1 Entropy Production; 2.1.2 Conjugate Forces and Fluxes; 2.1.3 Basic Postulate of Irreversible Thermodynamics; 2.2 Linear Irreversible Thermodynamics; 2.2.1 General Coupling between Forces and Fluxes; 2.2.2 Force-Flux Relations when Extensive Quantities are Constrained; 2.2.3 Introduction of the Diffusion Potential; 2.2.4 Onsager's Symmetry Principle; Bibliography; Exercises; 3 Driving Forces and Fluxes for Diffusion; 3.1 Concentration Gradients and Diffusion3.1.1 Self-Diffusion: Diffusion in the Absence of Chemical Effects3.1.2 Self-Diffusion of Component i in a Chemically Homogeneous Binary Solution; 3.1.3 Diffusion of Substitutional Particles in a Chemical Concentration Gradient; 3.1.4 Diffusion of Interstitial Particles in a Chemical Concentration Gradient; 3.1.5 On the Algebraic Signs of Diffusivities; 3.1.6 Summary of Diffusivities; 3.2 Electrical Potential Gradients and Diffusion; 3.2.1 Charged Ions in Ionic Conductors; 3.2.2 Electromigration in Metals; 3.3 Thermal Gradients and Diffusion; 3.4 Capillarity and Diffusion3.4.1 The Flux Equation and Diffusion Equation3.4.2 Boundary Conditions; 3.5 Stress and Diffusion; 3.5.1 Effect of Stress on Mobilities; 3.5.2 Stress as a Driving Force for Diffusion: Formation of Solute-Atom Atmosphere around Dislocations; 3.5.3 Influence of Stress on the Boundary Conditions for Diffusion: Diffusional Creep; 3.5.4 Summary of Diffusion Potentials; Bibliography; Exercises; 4 The Diffusion Equation; 4.1 Fick's Second Law; 4.1.1 Linearization of the Diffusion Equation; 4.1.2 Relation of Fick's Second Law to the Heat Equation4.1.3 Variational Interpretation of the Diffusion Equation4.2 Constant Diffusivity; 4.2.1 Geometrical Interpretation of the Diffusion Equation when Diffusivity is Constant; 4.2.2 Scaling of the Diffusion Equation; 4.2.3 Superposition; 4.3 Diffusivity as a Function of Concentration; 4.4 Diffusivity as a Function of Time; 4.5 Diffusivity as a Function of Direction; Bibliography; Exercises; 5 Solutions to the Diffusion Equation; 5.1 Steady-State Solutions; 5.1.1 One Dimension; 5.1.2 Cylindrical Shell; 5.1.3 Spherical Shell; 5.1.4 Variable Diffusivity; 5.2 Non-Steady-State Diffusion5.2.1 Instantaneous Localized Sources in Infinite MediaA classroom-tested textbook providing a fundamental understanding of basic kinetic processes in materialsThis textbook, reflecting the hands-on teaching experience of its three authors, evolved from Massachusetts Institute of Technology's first-year graduate curriculum in the Department of Materials Science and Engineering. It discusses key topics collectively representing the basic kinetic processes that cause changes in the size, shape, composition, and atomistic structure of materials. Readers gain a deeper understanding of these kinetic processes and of the properties and applicatiMaterialsMechanical propertiesMaterials scienceMaterialsMechanical properties.Materials science.541.394620.1/1292620.11292Balluffi R. W855558Allen Samuel M855559Carter W. Craig855560Kemper Rachel A855561MiAaPQMiAaPQMiAaPQBOOK9910143567903321Kinetics of materials1910002UNINA