05566nam 2200709 a 450 991014126640332120230801222442.01-280-58949-397866136193271-118-30948-01-118-30951-01-118-30947-2(CKB)2670000000175359(EBL)827160(OCoLC)787842608(SSID)ssj0000668006(PQKBManifestationID)11391355(PQKBTitleCode)TC0000668006(PQKBWorkID)10685743(PQKB)10693764(MiAaPQ)EBC827160(Au-PeEL)EBL827160(CaPaEBR)ebr10558103(CaONFJC)MIL361932(EXLCZ)99267000000017535920120524d2012 uy 0engur|n|---|||||txtccrKinetics and thermodynamics of multistep nucleation and self-assembly in nanoscale materials[electronic resource] /edited by Gregoire Nicolis and Dominique MaesHoboken, N.J. John Wiley & Sons20121 online resource (353 p.)Advances in chemical physics ;v. 151Description based upon print version of record.1-118-16783-X Includes bibliographical references and indexes.Kinetics and Thermodynamics of Multistep Nucleation and Self-Assembly in Nanoscale Materials: Advances in Chemical Physics Volume 151; CONTRIBUTORS; PREFACE; PREFACE TO THE SERIES; CONTENTS; KINETICS AND THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS IN MULTISTABLE SYSTEMS; I. INTRODUCTION; II. FORMULATION; A. Stationary Distribution; B. Exit from an Attraction Basin; III. CLOSED SYSTEMS AND DETAILED BALANCE; IV. GENERIC POTENTIALS AND THEIR UNFOLDINGS; A. Transitions from 1 to 3 Occur Necessarily Through State 2; B. Transitions from 1 to 3 Need Not Occur Through State 2V. KINETICS OF TRANSITIONS BETWEEN STATES: MAPPING INTO A DISCRETE MARKOV PROCESSA. Three Simultaneously Stable States (Seven-Steady-State Region); B. Two Simultaneously Stable States (Five-Steady-State Region); C. Two Simultaneously Stable States (Three-Steady-State Region); VI. IRREVERSIBLE THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS; VII. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; DYNAMICAL RARE EVENT SIMULATION TECHNIQUES FOR EQUILIBRIUM AND NONEQUILIBRIUM SYSTEMS; I. INTRODUCTION; II. REACTIVE FLUX METHOD; III. TRANSITION PATH SAMPLING; IV. TRANSITION INTERFACE SAMPLINGV. PARTIAL PATH SAMPLINGVI. FORWARD FLUX SAMPLING; VII. REPLICA EXCHANGE TIS; VIII. NUMERICAL EXAMPLE; IX. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; CONFOCAL DEPOLARIZED DYNAMIC LIGHT SCATTERING; I. INTRODUCTION; II. FUNDAMENTALS OF DEPOLARIZED SCATTERING: THE STATE OF THE ART; III. THE TRADITIONAL APPROACH; IV. THE NOVEL APPROACH; V. THE OPTICAL LAYOUT; VI. DATA REDUCTION SCHEME; VII. RESULTS; VIII. CONCLUSIONS; ACKNOWLEDGMENT; REFERENCES; THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL FOR NUCLEATION OF CRYSTALS IN SOLUTION; I. INTRODUCTION; II. THE CLASSICAL NUCLEATION THEORYA. The Crystallization Driving ForceB. The Thermodynamic Theory of J.W. Gibbs; C. The Rate of Crystal Nucleation; III. THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL; A. Experimental Data on the Rate of Nucleation of Crystals; B. The Nucleus Size and Solution-to-Crystal Spinodal; C. The Classical Theory Overestimates the Crystal Nucleation Rate by 10 Orders of Magnitude; D. The Two-Step Mechanism of Nucleation of Crystal in Solution; E. Dense Liquid Clusters; F. The Rate Law for the Two-Step Mechanism of Crystal NucleationG. The Rate-determining Step in the Two-Step Nucleation MechanismH. The Role of Heterogeneous Nucleation Substrates; I. The Broad Applicability of the Two-Step Nucleation Mechanism; IV. SUMMARY AND CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; EXPERIMENTAL STUDIES OF TWO-STEP NUCLEATION DURING TWO-DIMENSIONAL CRYSTALLIZATION OF COLLOIDAL PARTICLES WITH SHORT-RANGE ATTRACTION; I. INTRODUCTION; II. EXPERIMENTAL METHODS: SAMPLE PREPARATION AND IMAGING; III. ANALYSIS OF IMAGES: PARTICLE COORDINATES, AREA FRACTION, CLUSTER SIZES, AND CRYSTALLINE ORDER; IV. RESULTSA. Single-Step and Two-Step Nucleation of Crystallites The Advances in Chemical Physics series-the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class deAdvances in chemical physics ;v. 151.NucleationDynamicsThermodynamicsNucleation.Dynamics.Thermodynamics.541Nicolis Gregoire16618Maes Dominique866817MiAaPQMiAaPQMiAaPQBOOK9910141266403321Kinetics and thermodynamics of multistep nucleation and self-assembly in nanoscale materials1934971UNINA