05285nam 2200637Ia 450 991014076050332120170809152620.01-282-78382-397866127838213-527-62978-53-527-62979-3(CKB)2670000000047175(EBL)584983(OCoLC)644165891(SSID)ssj0000415712(PQKBManifestationID)11929416(PQKBTitleCode)TC0000415712(PQKBWorkID)10411186(PQKB)10985685(MiAaPQ)EBC584983(EXLCZ)99267000000004717520091218d2010 uy 0engur|n|---|||||txtccrDesign and synthesis of conjugated polymers[electronic resource] /edited by Mario Leclerc, Jean-Francois MorinWeinheim Wiley-VCHc20101 online resource (381 p.)Description based upon print version of record.3-527-32474-7 Includes bibliographical references and index.Design and Synthesis of Conjugated Polymers; Contents; Preface; List of Contributors; 1 Synthesis and Functionality of Substituted Polyacetylenes; 1.1 Introduction; 1.2 Polymer Syntheses; 1.2.1 Catalysts; 1.2.2 Polymerization Behaviors; 1.2.3 Polymer Reactions; 1.3 Functional Properties; 1.3.1 Electrical Conductivity and Photoconductivity; 1.3.2 Liquid Crystallinity; 1.3.3 Luminescence; 1.3.4 Fluorescence Sensing; 1.3.5 Patterning and Imaging; 1.3.6 Chromism; 1.3.7 Optical Activity; 1.3.8 Supramolecular Assembly; 1.3.9 Optical Nonlinearity; 1.3.10 Biological Compatibility1.4 Conclusions and ProspectsAcknowledgments; References; 2 Suzuki Polycondensation: A Powerful Tool for Polyarylene Synthesis; 2.1 Introduction; 2.2 General Remarks; 2.3 How to Do an SPC and Aspects of Characterization; 2.3.1 Monomer Purity, Stoichiometry, and Solvents; 2.3.2 Brief Note on Optimization; 2.3.3 Reduced Catalyst Amount and Product Purification; 2.3.4 Molar Mass Determination; 2.4 Methodological Developments; 2.4.1 Boronic Acid/Boronate Monomers; 2.4.2 Boron-Based Ate Complexes; 2.4.3 Halo and Related Monomers; 2.4.4 Catalysts; 2.4.5 Chain Growth SPC2.4.6 Microwave and Technical Scale Microreactor Applications2.5 Selected Classes of Polyarylenes and Related Polymers; 2.5.1 Poly(para-phenylene)s; 2.5.2 Polyfluorenes; 2.5.3 Poly(para-meta-phenylene)s; 2.5.4 Shielded Polyarylenes; 2.5.5 Miscellaneous; 2.6 Conclusions and Outlook; Acknowledgments; References; 3 Advanced Functional Regioregular Polythiophenes; 3.1 Introduction; 3.2 Unsubstituted Polythiophene; 3.3 Poly(3-alkylthiophene)s; 3.4 Head-to-Tail Regioregular Poly(3-alkylthiophene)s (rrP3ATs); 3.4.1 Design and Synthesis of rrP3ATs; 3.4.1.1 McCullough Method; 3.4.1.2 Rieke Method3.4.1.3 GRIM Method3.4.1.4 Other Methods; 3.4.2 Mechanism of the Nickel-Catalyzed Polymerization; 3.4.3 End Group Functionalization; 3.4.3.1 Postpolymerization End Group Functionalization; 3.4.3.2 In situ End Group Functionalization; 3.4.4 Fundamental Properties of rrP3ATs; 3.4.4.1 UV-vis Absorption; 3.4.4.2 Microstructure and Morphology in Thin Films; 3.4.4.3 Electrical Conductivity; 3.4.5 rrP3ATs in Electronic Devices; 3.4.5.1 rrP3ATs in PLEDs; 3.4.5.2 rrP3ATs in OFETs; 3.4.5.3 rrP3ATs in OPVs; 3.5 Regiosymmetric Poly(alkylthiophene)s3.5.1 Head-to-Head-, Tail-to-Tail-Coupled Poly(alkylthiophene)s3.5.2 Regiosymmetric Alkylthiophene-Thiophene Copolymers; 3.6 Regiosymmetric Polythiophenes with (Hetero)aromatic Rings; 3.7 Polythiophene Block Copolymers; 3.7.1 All-Conjugated rrP3AT-Based Block Copolymers; 3.7.2 Conjugated-Nonconjugated rrP3AT-Based Block Copolymers; 3.8 Conclusion; References; 4 Poly(phenylenevinylenes); 4.1 Introduction; 4.2 Poly(p-phenylenevinylene)s via Polymerization Methods; 4.2.1 Gilch Approach; 4.2.2 The Wessling Method; 4.3 Poly(p-phenylenevinylene)s via Polycondensation4.3.1 Wittig and Horner-Wadsworth-Emmons ReactionThis first systematic compilation of synthesis methods for different classes of polymers describes well-tested and reproducible procedures, thus saving time, money and chemicals.Each chapter presents the latest method for a specific class of conjugated polymers with a particular emphasis on the design aspects for organo-electronic applications. In this concise and practically oriented manner, readers are introduced to the strategies of influencing and controlling the polymer properties with respect to their use in the desired device.This style of presentation quickly helps researchers PolymersElectric propertiesPolymersLaboratory manualsElectronic books.PolymersElectric properties.Polymers620.19620.19204297Leclerc Mario1961-855334Morin Jean-Franc ʹois1978-855335MiAaPQMiAaPQMiAaPQBOOK9910140760503321Design and synthesis of conjugated polymers1909541UNINA01865nam0 22004213i 450 PUV018753920231121125610.0IT711411 20040630d1969 ||||0itac50 baitaengit|||| |||c|z01i xxxe z01n˜Il œpensiero economico modernoRichard T. GillBolognaIl mulino[1969]159 p.22 cm˜La œnuova scienza. Fondamenti di economiaEdizione italiana a cura di Romano ProdiTraduzione di Giuliana de Vergottini.001RAV01787592001 ˜La œnuova scienza. Fondamenti di economiaEvolution of modern economics.NAP0491520RAVV02585424903EconomiaSec. 19.-20.FIRRMLC118145I330.1ECONOMIA. Sistemi e teorie20Gill, Richard ThomasRAVV025854070126113Prodi, RomanoCFIV092546340De Vergottini, GiulianaSBLV188502730ITIT-0120040630IT-RM0290 IT-RM0542 IT-RM0730 IT-FR0017 BIBLIOTECA ANGELICARM0290 BIBLIOTECA DEL MINISTERO DEGLI AFFARI ESTERIRM0542 Biblioteca Storica Nazionale Dell'AgricolturaRM0730 Biblioteca umanistica Giorgio ApreaFR0017 PUV0187539Biblioteca umanistica Giorgio Aprea 52DES 330 Gil.Pen. 52BUN0000374035 VMB RS A 2013050220130502 52MAG 12/2312 52MAG0000054025 VMN RS A 2013062020130620 06 09 21 52Evolution of modern economics24903UNICAS