05900nam 22008533u 450 991013895660332120210111224907.00-470-82487-50-470-82486-7(CKB)2550000001219945(EBL)818626(OCoLC)632157493(SSID)ssj0000597346(PQKBManifestationID)11410509(PQKBTitleCode)TC0000597346(PQKBWorkID)10578452(PQKB)11049715(MiAaPQ)EBC818626(PPN)250379007(EXLCZ)99255000000121994520150223d2011|||| u|| |engur|n|---|||||txtccrRare Earth Coordination Chemistry[electronic resource] Fundamentals and ApplicationsHoboken Wiley20111 online resource (601 p.)Description based upon print version of record.0-470-82485-9 Rare Earth Coordination Chemistry; Contents; Author Biographies; Foreword; Preface; 1 Introduction; 1.1 Electronic Configuration of Lanthanide Atoms in the Ground State; 1.2 Lanthanide Contraction; 1.3 Specificity of the Photophysical Properties of Rare Earth Compounds; 1.3.1 Spectral Terms; 1.3.2 Selection Rules for Atomic Spectra; 1.3.3 Lifetime; 1.3.4 Absorption Spectra; 1.3.5 The Emission Spectra of Rare Earth Compounds; 1.4 Specificities of Rare Earth Coordination Chemistry; 1.4.1 Valence State of Rare Earth Elements; 1.4.2 Chemical Bonding of Rare Earth Elements1.4.3 Coordination Numbers of Rare Earth Complexes1.4.4 Tetrad Effect of Lanthanide Elements - Changing Gradation Rules in Lanthanide Coordination Chemistry; 1.5 Coordination Chemistry of Inorganic Compounds; 1.5.1 Rare Earth Hydroxides; 1.5.2 Rare Earth Halide and Perchlorate Compounds; 1.5.3 Rare Earth Cyanide and Thiocyanate Compounds; 1.5.4 Rare Earth Carbonate Compounds; 1.5.5 Rare Earth Oxalate Compounds; 1.5.6 Rare Earth Nitrate Compounds; 1.5.7 Rare Earth Phosphate Compounds; 1.5.8 Rare Earth Sulfate Compounds; 1.5.9 Rare Earth Borate Compounds; 1.6 Outlook; AcknowledgmentsReferences2 β-Diketonate Lanthanide Complexes; 2.1 Introduction; 2.2 Types of β-Diketones Used for Lanthanide Complexes; 2.2.1 Mono(β-Diketone) Ligands; 2.2.2 Bis(β-Diketones) Ligands; 2.2.3 Dendritic β-Diketones Ligands; 2.3 β-Diketonate Lanthanide Complexes; 2.3.1 Mononuclear Lanthanide Complexes with β-Diketones; 2.3.2 Polynuclear β-Diketonate Lanthanide Complexes; 2.4 Summary and Outlook; Acknowledgments; References; 3 Rare Earth Complexes with Carboxylic Acids, Polyaminopolycarboxylic Acids, and Amino Acids; 3.1 Introduction; 3.2 Rare Earth Complexes with Carboxylic Acids3.2.1 Preparation of Rare Earth Complexes with Carboxylic Acids3.2.2 Structural Chemistry of Rare Earth Complexes with Carboxylic Acids; 3.2.3 Solution Chemistry of Rare Earth Complexes with Carboxylic Acids; 3.3 Rare Earth Complexes with Polyaminopolycarboxylic Acids; 3.3.1 Preparation of Rare Earth Complexes with Polyaminopolycarboxylic Acids; 3.3.2 Structural Chemistry of Rare Earth Complexes with Polyaminopolycarboxylic Acids; 3.3.3 Solution Chemistry of Rare Earth Complexes with Polyaminopolycarboxylic Acids; 3.4 Rare Earth Complexes with Amino Acids3.4.1 Preparation of Rare Earth Complexes with Amino Acids3.4.2 Structural Chemistry of Rare Earth Complexes with Amino Acids; 3.4.3 Solution Chemistry of Rare Earth Complexes with Amino Acids; 3.5 Summary and Outlook; References; 4 N-Based Rare Earth Complexes; 4.1 Introduction; 4.2 Rare Earth Complexes with Amide Type Ligands; 4.2.1 Rare Earth Complexes with Aliphatic Amide Type Ligands; 4.2.2 Rare Earth Complexes with Silyl Amide Type Ligands; 4.3 Rare Earth Complexes with N-Heterocyclic Type Ligands; 4.3.1 Rare Earth Complexes with Pyridine Type Ligands4.3.2 Rare Earth Complexes with Imidazole Type LigandsEdited by a highly regarded scientist and with contributions fromsixteen international research groups, spanning Asia and NorthAmerica, Rare Earth Coordination Chemistry: Fundamentals andApplications provides the first one-stop reference resource forimportant accomplishments in the area of rare earth.Consisting of two parts, Fundamentals and Applications, readers arearmed with the systematic basic aspects of rare earth coordinationchemistry and presented with the latest developments in theapplications of rare earths.The systematic introduction of basic knowledge, applicationtechnology and the Coordination compoundsRare earth metal compoundsRare earthsRare earthsRare earth metal compoundsCoordination compoundsLaw - U.SHILCCChemistryHILCCPhysical Sciences & MathematicsHILCCLaw, Politics & GovernmentHILCCInorganic ChemistryHILCCLaw - U.S. - GeneralHILCCCoordination compounds.Rare earth metal compounds.Rare earths.Rare earthsRare earth metal compoundsCoordination compoundsLaw - U.S.ChemistryPhysical Sciences & MathematicsLaw, Politics & GovernmentInorganic ChemistryLaw - U.S. - General546546.41546/.41Huang Chun-Hui975568Huang Chun-HuiAU-PeELAU-PeELAU-PeELBOOK9910138956603321Rare Earth Coordination Chemistry2221395UNINA