05410nam 2200637 a 450 991013385670332120230803033511.03-527-65572-73-527-65570-03-527-65573-5(CKB)3360000000455835(EBL)1211855(OCoLC)851315938(SSID)ssj0000872615(PQKBManifestationID)11474395(PQKBTitleCode)TC0000872615(PQKBWorkID)10831344(PQKB)10782722(MiAaPQ)EBC1211855(Au-PeEL)EBL1211855(CaPaEBR)ebr10718825(CaONFJC)MIL497744(EXLCZ)99336000000045583520130618d2013 uy 0engur|n|---|||||txtccrConjugated polyelectrolytes[electronic resource]fundamentals and applications /edited by Bin Liu and Guillermo C. BazanWeinheim an der Bergstrasse, Germany Wiley-VCH Verlagc20131 online resource (440 p.)Description based upon print version of record.3-527-33143-3 Includes bibliographical references at the end of each chapters and index.Conjugated Polyelectrolytes; Contents; Preface; List of Contributors; 1 Design and Synthesis of Conjugated Polyelectrolytes; 1.1 Introduction; 1.2 Poly(arylene)s; 1.2.1 Polythiophenes; 1.2.1.1 Anionic Polythiophenes; 1.2.1.2 Cationic Polythiophenes; 1.2.1.3 Zwitterionic Polythiophenes; 1.2.2 Poly(p-phenylene)s; 1.2.2.1 Anionic Poly(p-phenylene)s; 1.2.2.2 Cationic Poly(p-phenylene)s; 1.2.3 Poly(fluorene)s; 1.2.3.1 Cationic Poly(fluorene)s; 1.2.3.2 Anionic Poly(fluorene)s; 1.2.3.3 Zwitterionic Poly(fluorene)s; 1.3 Poly(arylene ethynylene)s; 1.3.1 Poly(phenylene ethynylene)s1.3.1.1 Anionic Poly(phenylene ethynylene)s1.3.1.2 Cationic Poly(phenylene ethynylene)s; 1.3.2 Poly(fluorene ethynylene)s; 1.3.2.1 Cationic Poly(fluorene ethynylene)s; 1.3.2.2 Anionic Poly(fluorene ethynylene)s; 1.4 Poly(arylene vinylene)s; 1.4.1 Poly(phenylene vinylene)s; 1.4.1.1 Anionic Poly(phenylene vinylene)s; 1.4.1.2 Cationic Poly(phenylene vinylene)s; 1.4.2 Poly(fluorene vinylene)s; 1.4.2.1 Cationic Poly(fluorene vinylene)s; 1.4.2.2 Anionic Poly(fluorene vinylene)s; 1.5 Conclusion; References; 2 All-Conjugated Rod-Rod Diblock Copolymers Containing Conjugated Polyelectrolyte Blocks2.1 Introduction2.2 All-Conjugated, Cationic Polyfluorene-b-Polythiophene Diblock Copolymers; 2.2.1 Synthesis; 2.2.2 Optical Properties; 2.2.3 Aggregation Behavior of Cationic PF-b-PT Diblock Copolymers; 2.2.4 Atomic Force Microscopy; 2.2.4.1 Confocal Microscopy; 2.2.4.2 Complexation with Anionic Surfactants; 2.2.4.3 Complexation with DNA; 2.2.4.4 Incorporation of PF2/6-b-P3TMAHT into Organic Electronic Devices; 2.3 All-Conjugated Cationic Polyfluorene-b-Polyfluorene Diblock Copolymers; 2.3.1 Synthesis; 2.3.2 Optical Properties; 2.3.3 Atomic Force Microscopy; 2.4 Conclusion; AcknowledgmentsReferences3 Ionically Functionalized Polyacetylenes; 3.1 Introduction; 3.2 Polymers from Ionically Functionalized Cyclooctatetraenes; 3.2.1 Synthesis and General Properties; 3.2.2 Electrochemistry; 3.2.2.1 Electrochemical Doping; 3.2.2.2 The Donnan Potential; 3.2.2.3 Internal Compensation; 3.2.3 Polyelectrolyte-Mediated and Self-Limiting Electrochemistry; 3.2.4 Junctions; 3.2.4.1 In situ Electrochemical Manipulation and the Tunable Diode; 3.2.4.2 Internally Compensated p-n Junctions; 3.2.4.3 Undoped Ionic Junctions; 3.3 Polymers from Ionically Functionalized Acetylenes3.3.1 General Properties and Synthetic Approaches3.3.2 Polymer Chain Structure; 3.3.3 Poly(IA)s with Extended Conjugations; 3.4 Summary; Acknowledgment; References; 4 Aggregation Properties of Conjugated Polyelectrolytes; 4.1 Introduction; 4.2 Aggregation: from Disordered Clusters to Structured Vesicles; 4.3 Experimental Studies on Aggregation; 4.3.1 What Scattering Techniques Tell Us; 4.3.2 Microscopy Studies in Solution and Films; 4.3.3 Spectroscopic and Photophysical Studies; 4.3.4 Aggregation as Seen by Electrical Conductivity and NMR Spectroscopy; 4.3.5 Molecular Dynamics Simulations4.4 Conjugated Polyelectrolyte Aggregation in SolutionThis is the first monograph to specifically focus on fundamentals and applications of polyelectrolytes, a class of molecules that gained substantial interest due to their unique combination of properties. Combining both features of organic semiconductors and polyelectrolytes, they offer a broad field for fundamental research as well as applications to analytical chemistry, optical imaging, and opto-electronic devices. The initial chapters introduce readers to the synthesis, optical and electrical properties of various conjugated polyelectrolytes. This is followed by chapters on the applicaPolyelectrolytesConjugated polymersPolyelectrolytes.Conjugated polymers.541.372Liu Bin845441Bazan Guillermo C962990MiAaPQMiAaPQMiAaPQBOOK9910133856703321Conjugated polyelectrolytes2183560UNINA