05678nam 2200733 450 991013215650332120170821202941.01-118-67074-41-118-67075-21-118-67073-6(CKB)3710000000250140(EBL)1798776(OCoLC)892240559(SSID)ssj0001347520(PQKBManifestationID)12603796(PQKBTitleCode)TC0001347520(PQKBWorkID)11351158(PQKB)11360673(PQKBManifestationID)16039689(PQKB)23165098(MiAaPQ)EBC1798776(DLC) 2014018459(MiAaPQ)EBC7076142(Au-PeEL)EBL7076142(PPN)220082944(EXLCZ)99371000000025014020141022h20152015 uy 0engur|n|---|||||txtccrFundamentals and applications of organic electrochemistry synthesis, materials, devices /Toshio Fuchigami, Mahito Atobe, Shinsuke InagiChichester, England :Wiley,2015.©20151 online resource (241 p.)Description based upon print version of record.1-322-19612-5 1-118-65317-3 Includes bibliographical references at the end of each chapters and index.Fundamentals and Applications of Organic Electrochemistry: Synthesis, Materials, Devices; Contents; About the Authors; Preface; Introduction; 1. Fundamental Principles of Organic Electrochemistry: Fundamental Aspects of Electrochemistry Dealing with Organic Molecules; 1.1 FORMATION OF ELECTRICAL DOUBLE LAYER; 1.2 ELECTRODE POTENTIALS (REDOX POTENTIALS); 1.3 ACTIVATION ENERGY AND OVERPOTENTIAL; 1.4 CURRENTS CONTROLLED BY ELECTRON TRANSFER AND MASS TRANSPORT; References; 2. Method for Study of Organic Electrochemistry: Electrochemical Measurements of Organic Molecules; 2.1 WORKING ELECTRODES2.2 REFERENCE ELECTRODES2.3 AUXILIARY ELECTRODES; 2.4 SOLVENTS AND SUPPORTING ELECTROLYTES; 2.5 CELLS AND POWER SOURCES; 2.6 STEADY-STATE AND NON-STEADY-STATES POLARIZATION CURVES; 2.7 POTENTIALS IN ELECTROCHEMICAL MEASUREMENTS; 2.8 UTILIZATION OF VOLTAMMETRY FOR THE STUDY OF ORGANIC ELECTROSYNTHESIS; 2.8.1 Voltammetric Analysis for Selective Electrosynthesis; 2.8.2 Clarification of the Reaction Mechanism; 2.8.3 Voltammetry for Selection of Mediator; 2.8.4 Voltammetry for Selection of Electrode Material; References; 3. Methods for Organic Electrosynthesis; 3.1 SELECTION OF ELECTROLYTIC CELLS3.2 CONSTANT CURRENT ELECTROLYSIS AND CONSTANT POTENTIAL ELECTROLYSIS3.3 DIRECT ELECTROLYSIS AND INDIRECT ELECTROLYSIS; 3.4 ELECTRODE MATERIALS AND REFERENCE ELECTRODES; 3.5 ELECTROLYTIC SOLVENTS AND SUPPORTING ELECTROLYTES; 3.6 STIRRING; 3.7 TRACKING OF REACTANT AND PRODUCT; 3.8 WORK-UP, ISOLATION AND DETERMINATION OF PRODUCTS; 3.9 CURRENT EFFICIENCY AND EFFECT OF THE POWER UNIT; References; 4. Organic Electrode Reactions; 4.1 GENERAL CHARACTERISTICS OF ELECTRODE REACTIONS; 4.2 MECHANISM OF ORGANIC ELECTRODE REACTIONS; 4.3 CHARACTERISTICS OF ORGANIC ELECTROLYTIC REACTIONS; 4.3.1 Umpolung4.3.2 Selectivity4.3.2.1 Chemoselectivity; 4.3.2.2 Reaction Pathway Selectivity; 4.3.2.3 Regioselectivity; 4.3.2.4 Stereoselectivity; 4.3.2.5 Selectivity Depending on Electrode Materials; 4.4 MOLECULAR ORBITALS AND ELECTRONS RELATED TO ELECTRON TRANSFER; 4.5 ELECTROAUXILIARIES; 4.5.1 Electroauxiliaries Based on Molecular Orbital Interactions; 4.5.2 Electroauxiliaries Based on Readily Electron-Transferable Functional Groups; 4.5.3 Electroauxiliaries Based on Intermolecular Coordination Effects; 4.5.4 Electroauxiliaries Based on Intramolecular Coordination Effects4.6 REACTION PATTERN OF ORGANIC ELECTRODE REACTIONS4.6.1 Transformation Type of Functional Group; 4.6.2 Addition Type; 4.6.3 Insertion Type; 4.6.4 Substitution Type; 4.6.5 Substitutive Exchange Type; 4.6.6 Elimination Type; 4.6.7 Dimerization Type; 4.6.8 Crossed Dimerization; 4.6.9 Cyclization Type; 4.6.10 Polymorphism Formation Type; 4.6.11 Polymerization Type; 4.6.12 Cleavage Type; 4.6.13 Metalation Type; 4.6.14 Asymmetric Synthesis Type; 4.7 ELECTROCHEMICALLY GENERATED REACTIVE SPECIES; 4.7.1 Carbon Species; 4.7.1.1 Anodically Generated Carbon Species4.7.1.2 Cathodically Generated Carbon SpeciesThis textbook is an accessible overview of the broad field of organic electrochemistry, covering the fundamentals and applications of contemporary organic electrochemistry. The book begins with an introduction to the fundamental aspects of electrode electron transfer and methods for the electrochemical measurement of organic molecules. It then goes on to discuss organic electrosynthesis of molecules and macromolecules, including detailed experimental information for the electrochemical synthesis of organic compounds and conducting polymers. Later chapters highlight new methodology for organicOrganic electrochemistryElectrochemistryChemistry, OrganicOrganic electrochemistry.Electrochemistry.Chemistry, Organic.547/.137Fuchigami Toshio895600Atobe Mahito1969-Inagi ShinsukeMiAaPQMiAaPQMiAaPQBOOK9910132156503321Fundamentals and applications of organic electrochemistry2000721UNINA