04278nam 2200589 450 991013152940332120211025112838.01-119-17856-81-119-17854-11-119-17855-X(CKB)3710000000498555(EBL)4444935(MiAaPQ)EBC4444935(Au-PeEL)EBL4444935(CaPaEBR)ebr11251270(CaONFJC)MIL847004(OCoLC)945764293(EXLCZ)99371000000049855520160916d2015 uy| 0engur|n|---|||||rdacontentrdamediardacarrierChemical equilibria /Michel SoustelleHoboken, NJ :Wiley,2015.1 online resource (179 p.)Chemical engineering series : chemical thermodynamics set ;volume 4Description based upon print version of record.1-84821-867-2 Includes bibliographical references and index.Table of Contents; Title; Copyright; Preface; Notations and Symbols; 1: Physico-Chemical Transformations and Equilibria; 1.1. Characteristic parameters of physico-chemical transformations; 1.2. Entropy production during the course of a transformation in a closed system; 1.3. Affinity of a transformation; 1.4. De Donder's inequality - direction of the transformations and equilibrium conditions; 1.5. Heats of transformation; 1.6. Set of points representing the equilibrium states of a transformation; 1.7. Closed systems accommodating multiple reactions1.8. Direction of evolution and equilibrium conditions in an open system1.9. Azeotropic transformations; 2: Properties of States of Physico-Chemical Equilibrium; 2.1. Laws of displacement of an equilibrium; 2.2. Properties of all the equilibria in a system; 2.3. Phase laws; 2.4. Indifferent states; 2.5. Thermodynamically-equivalent systems; 2.6. Stability of equilibria; 3: Molecular Chemical Equilibria; 3.1. Law of mass action - equilibrium constants; 3.2. Graphical representations of equilibria - pole diagrams; 3.3. Representation of the evolution of an equilibrium with the temperature3.4. Binary diagrams for chemical equilibrium3.5. Ternary diagrams of chemical equilibria; 3.6. Quaternary diagrams of chemical equilibria; 4: Determination of the Values Associated with Reactions - Equilibrium Calculations; 4.1. Reminders of a few thermodynamic relations; 4.2. Enthalpies of reaction - thermochemistry; 4.3. Reaction entropies; 4.4. Specific heat capacities; 4.5. Experimental determination of the equilibrium constants; 4.6. Calculation of the equilibrium constants on the basis of other thermodynamic data4.7. Determination of the equilibrium constants on the basis of spectral data and statistical thermodynamics4.8. Thermodynamic tables and databanks; 4.9. Estimation of thermodynamic data; 4.10. Thermodynamic calculations for complex systems; APPENDICES; Appendix 1: Recap on the Reference States of Solutions; A1.1. Concentration and molar fraction; A1.2. Chemical potentials and activity coefficients; A1.3. Characterization of the imperfection of a real solution by the excess Gibbs energy; Appendix 2: Recap of statistical thermodynamics; A2.1. The three branches of statisticsA2.2. Partition functions of a molecule objectA2.3. Canonical partition function; A2.4. Canonical partition functions and thermodynamic functions; A2.5. Equilibrium constants and molecular partition functions; Bibliography; Index; End User License AgreementChemical engineering series (ISTE Ltd.)ThermodynamicsMathematical modelsChemical equilibriumMathematical modelsPhase transformations (Statistical physics)ThermodynamicsMathematical models.Chemical equilibriumMathematical models.Phase transformations (Statistical physics)541.392Soustelle Michel854349MiAaPQMiAaPQMiAaPQBOOK9910131529403321Chemical equilibria2278635UNINA