05265nam 2200661 a 450 991013923520332120200520144314.03-527-64828-33-527-64830-51-299-24131-X3-527-64831-3(CKB)2560000000099101(EBL)1135505(OCoLC)830165269(SSID)ssj0000904867(PQKBManifestationID)11506360(PQKBTitleCode)TC0000904867(PQKBWorkID)10924584(PQKB)10848551(MiAaPQ)EBC1135505(Au-PeEL)EBL1135505(CaPaEBR)ebr10667421(CaONFJC)MIL455381(PPN)224590820(EXLCZ)99256000000009910120130312d2013 uy 0engur|n|---|||||txtccrPalladium-catalyzed coupling reactions[electronic resource] practical aspects and future developments /edited by Árpád Molnár2nd ed.Weinheim, Germany Wiley20131 online resource (533 p.)Description based upon print version of record.3-527-33254-5 Includes bibliographical references and index.Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Contents; Foreword; Preface; List of Contributors; 1 Palladium-Catalyzed Cross-Coupling Reactions - A General Introduction; 1.1 Introduction; 1.1.1 Historical Reflection; 1.1.2 Characteristics, Recent Developments, and Progress; 1.1.3 Literature Reviews and Organization of the Chapter; 1.2 Carbon-Carbon Cross-Coupling Reactions Catalyzed by Palladium; 1.2.1 Classification and Overview; 1.2.2 Common Mechanistic Features of Cross-Coupling Reactions and Reactivity of the Substrates1.2.2.1 Choice of the Carbon Electrophile1.2.2.2 Choice of the Carbon Nucleophile - What Makes the Difference?; 1.3 The Catalysts; 1.3.1 The Particular Features of Palladium; 1.3.2 Classes of Palladium Catalysts Applied to Cross-Coupling Reactions; 1.3.2.1 Ligands and Palladium Complexes - Homogeneous Systems; 1.3.2.2 Immobilized or Supported Palladium Complexes and Particles - Heterogeneous Systems; 1.3.2.3 Palladium Colloids and (Nonsupported) Nanoparticles; 1.3.2.4 Activity of Heterogeneous Catalysts; 1.4 Mechanistic Aspects1.4.1 General Mechanism of C C Cross-Coupling and Heck Reactions with Homogeneous Catalyst Precursors1.4.2 Models for Heck and Suzuki Reactions with Supported Pd Precursors; 1.4.3 Recent Results on the Reaction Mechanism and the Nature of the Active Pd Species; 1.4.3.1 Observation of Intermediates in Homogeneous Catalysis by Electrochemical Methods; 1.4.3.2 The Question of Pd Leaching; 1.4.3.3 Selectivity Pattern; 1.4.3.4 In Situ Observation by Spectroscopic Methods; 1.4.3.5 Immobilized Pd Pincer Complexes; 1.4.3.6 Palladium Bulk Materials (Pd Foil, Wire, Sponge) as Catalyst1.5 Future ChallengesAbbreviations; References; 2 High-Turnover Heterogeneous Palladium Catalysts in Coupling Reactions: the Case of Pd Loaded on Dealuminated Y Zeolites; 2.1 Introduction; 2.2 Various Methodologies to Afford High Turnover Numbers Over Supported Pd Catalysts; 2.3 Structure and Characteristics of Ultrastable Y Zeolites; 2.4 Suzuki-Miyaura Reactions Catalyzed by Pd/USY; 2.4.1 Catalytic Performance of Pd/USY; 2.4.2 Pd Leaching from Pd/USY; 2.4.3 Selectivity in the Homocoupling Reactions; 2.4.4 Characterization of the Active Pd Species by X-Ray Absorption Spectroscopy2.4.5 A Suggested Mechanism for the Formation of Active Pd Species in Suzuki-Miyaura Coupling Reactions2.5 Catalytic Performance of Pd/USY in Mizoroki-Heck Reactions; 2.5.1 Effect of H2 Bubbling on the Catalytic Reactions of Pd/USY; 2.5.2 Catalytic Reactions Using Chlorobenzene Derivatives; 2.5.3 Characterization of the Pd Species by X-Ray Absorption Spectroscopy; 2.6 Conclusion and Perspective; Abbreviations; References; 3 Palladium-Catalyzed Coupling Reactions with Magnetically Separable Nanocatalysts; 3.1 Introduction3.2 General Considerations Concerning Magnetic Particles as Catalyst SupportsThis handbook and ready reference brings together all significant issues of practical importance for interested readers in one single volume. While covering homogeneous and heterogeneous catalysis, the text is unique in focusing on such important aspects as using different reaction media, microwave techniques or catalyst recycling. It also provides a comprehensive treatment of modern-day coupling reactions and emphasizes those topics that show potential for future development, such as continuous flow systems, water as a reaction medium, and catalyst immobilization, among others. With iCouplingsCatalysisCouplings.Catalysis.541.395Molnár Árpád448017MiAaPQMiAaPQMiAaPQBOOK9910139235203321Palladium-catalyzed coupling reactions2155219UNINA03245nas 2200925-- 450 991013045220332120220624213020.0(CKB)110978978189158(CONSER)---74648164-(EXLCZ)9911097897818915820750204b19722008 -f- aengtxtrdacontentcrdamediacrrdacarrierEconomic and social progress in Latin AmericaWashington, D.CInter-American Development Bank1 online resourceSubtitle varies.Print version: Economic and social progress in Latin America. (DLC) 74648164 (OCoLC)1796358 0095-2850 Economic and social progressEconomic and social progress reportECONOMIC AND SOCIAL PROGRESS IN LATIN AMERICA REPORTECONOMIC & SOCIAL PROGRESS IN LATIN AMERICAEcon. soc. prog. Lat. Am.AnnuaireseclasDonnées statistiqueseclasDéveloppement économique et socialeclaseconomic conditionseurovocensocial situationeurovocenLatin Americaeurovocencondition économiqueeurovocfrsituation socialeeurovocfrAmérique latineeurovocfrEconomic historyfast(OCoLC)fst00901974Social conditionsfast(OCoLC)fst01919811Sociaal-economische ontwikkelinggttArbeidsmarktgttAgricultural developmentLatin AmericaltcshSocial conditionsLatin AmericaltcshEntwicklungstwWirtschaftslagestwWirtschaftspolitikstwLateinamerikastwLatin AmericaEconomic conditions1945-PeriodicalsLatin AmericaSocial conditions1945-1982PeriodicalsLatin AmericaSocial conditions1982-PeriodicalsAmérique latineeclasLatin AmericafastPeriodicals.fastPeriodicals.lcgftSocial conditionsSouth AmericaCentral AmericaAnnuaires.Données statistiques.Développement économique et social.economic conditions.social situation.Latin America.condition économique.situation sociale.Amérique latine.Economic history.Social conditions.Sociaal-economische ontwikkeling.Arbeidsmarkt.Agricultural developmentSocial conditionsEntwicklung.Wirtschaftslage.Wirtschaftspolitik.Lateinamerika.330.980038David Rockefeller Center for Latin American Studies.JOURNAL9910130452203321exl_impl conversionEconomic and social progress in Latin America2575062UNINA01662nas 2200541-a 450 991014718570332120260218112213.01670-8156(DE-599)ZDB2199136-4(CKB)1000000000307030(CONSER)--2005255370(DE-599)2199136-4(EXLCZ)99100000000030703020051014a20059999 --- -engtxtrdacontentcrdamediacrrdacarrierFinancial stability /Central Bank of IcelandReykjavik, Iceland Central Bank of Iceland2005-1 online resourceTitle from cover.Print version: Financial stability (Reykjavik, Iceland) 1670-584X (DLC) 2005255370 (OCoLC)62082393 FinanceIcelandPeriodicalsFinancePeriodicalsEconomic historyfast(OCoLC)fst00901974Financefast(OCoLC)fst00924349FinanzmarktstwFinanzsektorstwIslandstwIcelandEconomic conditions1945-StatisticsPeriodicalsIcelandfastPeriodicals.fastStatistics.fastPeriodicals.lcgftFinanceFinanceEconomic history.Finance.Finanzmarkt.Finanzsektor.Island.Seðlabanki Íslands.JOURNAL9910147185703321exl_impl conversionFinancial stability2026386UNINA