05349nam 2200625 450 991078741890332120230807213715.03-527-69404-83-527-69402-1(CKB)3710000000359140(EBL)1969035(SSID)ssj0001469118(PQKBManifestationID)11872371(PQKBTitleCode)TC0001469118(PQKBWorkID)11528510(PQKB)11705989(MiAaPQ)EBC1969035(EXLCZ)99371000000035914020151105h20152015 uy 0engur|n|---|||||txtccrHandbook of metathesisVolume 2Applications in organic synthesis /editors, Prof. Robert H. Grubbs, Prof. Daniel J. O'Leary2nd ed.Weinheim an der Bergstrasse, Germany :Wiley-VCH,2015.©20151 online resource (772 p.)Description based upon print version of record.3-527-33949-3 Includes bibliographical references at the end of each chapters and index.Cover; Contents; Preface; List of Contributors; List of Abbreviations; Chapter 1 General Ring-Closing Metathesis; 1.1 Introduction; 1.2 Carbocycles (Introduction); 1.2.1 Small-Sized Carbocycles; 1.2.2 Medium-Sized Carbocycles; 1.2.3 Spiro Carbocycles; 1.3 Synthesis of Bridged Bicycloalkenes; 1.4 Synthesis of Heterocycles Containing Si, P, S, or B; 1.4.1 Si-Heterocycles; 1.4.2 P-Heterocycles; 1.4.3 S-Heterocycles; 1.4.4 B-Heterocycles; 1.5 Synthesis of O-Heterocycles; 1.5.1 Small and Medium-Size Cyclic Ethers; 1.5.2 Polycyclic Ethers; 1.6 Synthesis of N-Heterocycles; 1.6.1 N-Heterocycles1.6.2 Small and Medium-Sized Lactams1.7 Synthesis of Cyclic Conjugated Dienes; 1.8 Alkyne Metathesis; 1.9 Enyne Metathesis; 1.9.1 General Enyne Metathesis; 1.9.2 Dienyne Metathesis; 1.10 Tandem Processes; 1.10.1 Tandem ROM/RCM; 1.10.2 Other Tandem RCMs; 1.11 Synthesis of Macrocycles; 1.11.1 Macrocycles; 1.11.2 Macrolactones; 1.11.3 Macrolactams; 1.12 RCM and Isomerization via Ru-H; 1.13 Relay RCM (RRCM); 1.14 Z-Selective RCM; 1.14.1 Substrate-Controlled Z-Selective RCM; 1.14.2 Catalyst-Controlled Z-Selective RCM; 1.15 Enantioselective RCM; 1.16 Conclusion; Acknowledgments; ReferencesChapter 2 Cross-Metathesis2.1 Early Examples Using Well-Defined Molybdenum and Ruthenium Catalysts; 2.2 The General Model for Selectivity in CM Reactions; 2.3 Definition of Cross-Metathesis Reaction Categories and Chapter Organization; 2.4 Hydrocarbons; 2.4.1 Alkane Extensions; 2.4.2 Unsaturated Hydrocarbons, Including Styrene; 2.4.3 Ethylene Cross-Metathesis; 2.5 Boron; 2.6 Nitrogen; 2.6.1 Amines; 2.6.2 Amines as CM Partners in Heterocycle Syntheses; 2.6.3 Acrylonitrile and Other Nitrile-Based CM Applications; 2.6.4 Other Nitrogenous Substrates; 2.7 Oxygen2.7.1 Primary Allylic Alcohols and Derivatives2.7.2 Secondary Allylic Alcohols and Derivatives; 2.7.3 Tertiary Allylic Alcohols and Derivatives; 2.7.4 Homoallylic Alcohols and Derivatives; 2.7.5 Vinyl Ethers; 2.7.6 Acrolein, Crotonaldehyde, and Methacrolein; 2.7.7 Methyl Vinyl Ketone and Related Systems; 2.7.8 Acrylic Acid; 2.7.9 Acrylic Acid Derivatives, Including Esters, Thioesters, and Amides; 2.8 Halides; 2.9 Phosphorus; 2.10 Sulfur; 2.11 Fragment Coupling Reactions; 2.11.1 Acetogenins; 2.11.2 Cross-Metathesis Selectivity; 2.11.3 Tuning Metathesis Selectivity2.11.4 CM as an Alternative Coupling Strategy2.11.5 CM-Based Analog Synthesis; 2.11.6 Polyene Metathesis; 2.11.7 Cross-Metathesis Reaction Optimization: Pinnaic Acid; 2.12 Conclusions; References; Chapter 3 Vignette: Extending the Application of Metathesis in Chemical Biology - The Development of Site-Selective Peptide and Protein Modifications; 3.1 Introduction; 3.2 Cross-Metathesis Methodology Studies in Aqueous Media; 3.2.1 Allyl Sulfides are Reactive Substrates in Olefin Metathesis; 3.2.2 Sulfur-Relayed Cross-Metathesis3.2.3 Application of Aqueous Metathesis of Allyl Sulfides in Synthesis The second edition of the ""go-to"" reference in this field is completely updated and features more than 80% new content, with emphasis on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in such high quality. Edited by the Nobel laureate R. H. Grubbs and D. J. O ́Leary, this volume 2 of the 3-volume work focusses on applications in organic synthesis. With a list of contributors that reads like a ""Who's-Who"" of metathesis, this is an indispensable one-stop reference for chemists in academia and industry.Metathesis (Chemistry)Handbooks, manuals, etcAlkenesHandbooks, manuals, etcOrganic compoundsSynthesisHandbooks, manuals, etcMetathesis (Chemistry)AlkenesOrganic compoundsSynthesis660.299Grubbs Robert H.O'Leary Daniel J.MiAaPQMiAaPQMiAaPQBOOK9910787418903321Handbook of metathesis2870132UNINA01352nam2 22003013i 450 VAN0024465220240806101402.63978-11-387-3530-920220412d2019 |0itac50 baengUS|||| |||||ˆ2: ‰Bioengineering and biophysical aspects of elettromagnetic fieldsedited by Ben Greenebaum, Frank Barnes4. edBoca RatonCRC2019XI, 524 p.ill.24 cm001VAN002446552001 Biological effects of elettromagnetics series210 Boca RatonCRC001VAN002446512001 Handbook of biological effect of electromagnetic fieldedited by Ben Greenebaum, Frank Barnes.- Boca RatonCRC210 volumiill. ; 24 cmUSBoca RatonVANL000070BarnesFrankVANV199813GreenebaumBenVANV199812CRC <editore>VANV108066650ITSOL20240906RICABIBLIOTECA DEL DIPARTIMENTO DI INGEGNERIAIT-CE0100VAN05VAN00244652BIBLIOTECA DEL DIPARTIMENTO DI INGEGNERIA05PREST K 008 05UBI1184 20220412 BuonoBioengineering and biophysical aspects of elettromagnetic fields2821209UNICAMPANIA