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Record Nr. |
UNISA996202135403316 |
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Autore |
Nógrádi M |
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Titolo |
Stereoselective synthesis [[electronic resource] ] : a practical approach / / Mihály Nógrádi ; foreword by A.I. Meyers |
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Pubbl/distr/stampa |
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Weinheim ; ; New York, : VCH, 1995 |
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ISBN |
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1-281-75874-4 |
9786611758745 |
3-527-61569-5 |
3-527-61568-7 |
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Edizione |
[2nd, thoroughly rev. and updated ed.] |
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Descrizione fisica |
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1 online resource (390 p.) |
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Disciplina |
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Soggetti |
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Stereochemistry |
Stereoisomers |
Organic compounds - Synthesis |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references (p. [315]-358) and index. |
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Nota di contenuto |
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Stereoselective Synthesis; Contents; List of Symbols and Abbreviations; Introduction; 1 General Concepts of Stereoselective Synthesis; 1.1 Principles of Differentiating Molecules; 1.2 Characterization of Stereoisomers. Conformation and Configuration; 1.3 Intramolecular Symmetry. Topicity and Prochirality; 1.4 Selectivity in Chemistry; 1.4.1 Substrate Selectivity; 1.4.1.1 Substrate Diastereoselectivity (Diastereomer Selectivity); 1.4.1.2 Substrate Enantioselectivity (Enantiomer Selectivity). Kinetic Resolution; 1.4.2 Product Selectivity; 1.4.2.1 Formation of Stereoisomers |
1.4.2.2 Conditions Necessary for Stereoselectivity1.4.2.3 Concept of Stereodifferentiation; 1.4.2.4 Methods for Inducing Stereoselectivity; 1.4.3 Stereoselective Synthetic Strategies; 1.4.3.1 Enantioconvergent Synthesis; 1.4.3.2 Selective Preparation of Both Enantiomers from a Single Substrate; 1.5 Kinetics and Thermodynamics of Stereoselective Reactions; 2 Stereoselective Catalytic Reductions; 2.1 Stereoselective Homogeneous Hydrogenations with Rhodium-, Ruthenium- and Iridium-Phosphine Catalysts; 2.1.1 Hydrogenation of Olefinic Bonds; |
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