1.

Record Nr.

UNINA9911102359503321

Autore

Costisor Otilia

Titolo

Metal mediated template synthesis of ligands / / Otilia Costisor, Wolfgang Linert

Pubbl/distr/stampa

Singapore ; ; River Edge, NJ, : World Scientific Pub. Co., c2004

ISBN

9786611934705

9781281934703

1281934704

9789812794819

9812794816

Edizione

[1st ed.]

Descrizione fisica

1 online resource (307 p.)

Altri autori (Persone)

LinertW

Disciplina

541.2242

547.05

547/.05

Soggetti

Organometallic compounds - Synthesis

Organic compounds - Synthesis

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record

Nota di bibliografia

Includes bibliographical references (p. 257-294) and index.

Nota di contenuto

Contents               ; Preface              ; The Template Effect                          ; 1.1. Types of Template Effects                                     ; 1.2. The Template Effect as a Molecular Organizer Effect                                                               ; 1.3. Factors Affecting the Product of a Template Reaction                                                                ; 1.3.1. Coordination of ligands                                     ; 1.3.2. The chelate effect                                ; 1.3.3. Macrocyclic effect

1.4. The Negative Template Effect                                        1.5. Advantages of Metal Template Reaction                                                 ; Alkylation Reactions                           ; 2.1. Alkylation of the Nitrogen Atom                                           ; 2.2. Alkylation of the Sulfur Atom                                         ; 2.2.1. Open chain systems                                ; 2.2.2. Macrocyclic ligands                                 ; Schiff Condensation                          ; 3.1. Mechanistic Aspects

3.2. Open-chain Ligands                              3.3. Macrocyclic Ligands                               ; 3.3.1 Diimine macrocycles                                ; 3.3.2. Tetraimine macrocycles                                    ; 3.4. Cage Ligands                        ;



3.5 Compartmental Ligands                                ; 3.5.1. Closed-chain ligands                                  ; 3.5.2. Open chain ligands                                ; Mannich Condensation                           ; 4.1. Mechanistic Aspects

4.2 Acyclic Ligands                          4.2.1. Polyamine ligands                               ; 4.2.2. NO donor ligands                              ; 4.2.3. SN donor ligands                              ; 4.3. Monocyclic Ligands                              ; 4.3.1. Tetraaza macrocycles                                  ; 4.3.2. Pentaaza macrocycles                                  ; 4.3.3. Hexaaza macrocycles                                 ; 4.3.4. Octaaza macrocycles                                 ; 4.3.5. Azaether macrocycle

4.3.6. Azathioether macrocycle                                     4.3.7. Reinforced macrocycles                                    ; 4.3.8. Macromonocyclic dicompartmental ligands                                                     ; 4.4. Isolated Dimacrocycles                                  ; 4.5.Condensed Polymacrocyclic Ligands                                            ; 4.5.1. Carbon and nitrogen caped amine ligands                                                     ; 4.5.2. P- As amine cage ligands

4.5.3. Thioamine cage ligands

Sommario/riassunto

This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role



2.

Record Nr.

UNINA9911117051903321

Titolo

Indigeneity and nation / / edited by G.N. Devy and Geoffrey V. Davis

Pubbl/distr/stampa

New York : , : Routledge, , 2021

ISBN

1-000-19213-X

0-429-29183-3

1-000-19207-5

9780429291838

Edizione

[1st ed.]

Descrizione fisica

1 online resource (179 pages)

Collana

Key concepts in indigenous studies

Disciplina

306.08

305.8

Soggetti

Indigenous peoples

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Cover -- Half Title -- Series -- Title -- Copyright -- Contents -- Notes on contributors -- Preface -- Acknowledgements -- Introduction -- 1 Indigeneity in Southern Africa -- 2 Oceanic Identities: trans/national formations in New Zealand and the Pacific Islands region -- 3 Storied nationhood: literature, constitutionalism, and citizenship in Indigenous North America -- 4 Finding nation: the nation and the state in F. Sionil Jose's Mass and Edwin Thumboo's A Third Map -- 5 Indigenous peoples and nation interface in India -- 6 African indigeneity: the Southern African challenge -- 7 Two poets of the Pacific: Hone Tuwhare and Haunani-Kay Trask -- Index.

Sommario/riassunto

Part of the series Key Concepts in Indigenous Studies, this book focuses on the concepts that recur in any discussion of nature, culture and society among the indigenous. The book, the third in a five-volume series, deals with the two key concepts of indigeneity and nation of indigenous people from all the continents of the world. With contributions from renowned scholars, activists and experts across the globe, it looks at issues and ideas of indigeneity, nationhood, nationality, State, identity, selfhood, constitutionalism, and citizenship in Africa, North America, New Zealand, Pacific Islands and Oceania, India, and Southeast Asia from philosophical, cultural, historical and



literary points of view. Bringing together academic insights and experiences from the ground, this unique book with its wide coverage will serve as a comprehensive guide for students, teachers and scholars of indigenous studies. It will be essential reading for those in social and cultural anthropology, tribal studies, sociology and social exclusion studies, politics, religion and theology, cultural studies, literary and postcolonial studies, Third World and Global South studies, as well as activists working with indigenous communities.

3.

Record Nr.

UNINA9911139822503321

Titolo

Hydrocolloids . Part 2 Fundamentals and applications in food, biology, and medicine / / edited by Katsuyoshi Nishinari

Pubbl/distr/stampa

Amsterdam ; ; New York, : Elsevier, 2000

ISBN

1-281-04827-5

0-08-053429-5

Edizione

[1st ed.]

Descrizione fisica

1 online resource (982 p.)

Altri autori (Persone)

NishinariKatsuyoshi

Disciplina

541.3/4513 21

660.2945

541.34513

Soggetti

Hydrocolloids

Colloids

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Papers presented at Osaka City University International Symposium 98, joint meeting with the 4th International Conference on Hydrocolloids, held Oct. 4-10, 1998.

Nota di bibliografia

Includes bibliographical references and indexes.

Nota di contenuto

Cover; Part One; Volume I Cover; Hydrocolloids: Physical Chemistry and Industrial Application of Gels, Polysaccharides, and Proteins; Copyright Page; Preface to Part 1; Contents; PART 1: Introductory Lecture; Chapter 1. Short -range and long-range forces between hydrophilic surfaces and biopolymers in aqueoussolutions; PART 2: Structure Of Gels And Gelation; Chapter 2. Thermoreversible  gelation with multiple junctions in associating polymers; Chapter 3. Effect  of electric charges on the volume phase transition of thermosensitive gels.; Chapter 4. Structure  



and dynamics of ovalbumin gels

Chapter 5. Thermoreversible  gelation strongly coupled to polymer conformational transition Chapter 6. Hydrogels  from N-isopropylacrylamide oligomer; Chapter 7. Kinetic  effects of the gel size on the thermal behavior of poly- (N-isopropylacrylamide) gels : a calorimetric study; Chapter 8. Characterizations  of dehydrated polyacrylamide gel and its formation process; Chapter 9. Viscoelastic  behavior of tungstic acid gel during the gelation process; Chapter 10. The  volume phase transition of DNA and RNA gels

Chapter 11. Rheological  properties and microstructure of monodispersed O/W emulsion agar gelPART 3: Polysaccharides; Chapter 12. Viewing  biopolymer networks, their formation and breakdown by AFM; Chapter 13. Thermally  induced gels obtained with some amphiphilic polysaccharide derivatives: synthesis, mechanism and properties; Chapter 14. Industrial  production of new emulsifying polysaccharide by plant cell culture; Chapter 15. Production  and applications of novel plant cell culture polysaccharides; Chapter 16. Structural  features of polysaccharide of Hericium erinaceum

Chapter 17. Structural  and physical features of polysaccharide of Tremella aurantiaChapter 18. Dynamic  light scattering of dilute and semi-dilute xanthan solutions and comparison with rheological characteristics; Chapter 19. Relationships  between structural features, molecular weight and rheologicd properties ofcereal b -D-glucans; Chapter 20. New  biopolymers produced by nitrogen fixing microorganisms for use in foods; Chapter 21. Studies  on production and rheology of a polysaccharide synthesized by Beijerinckia sp strain 7070

Chapter 22. Heteropolysaccharides  produced by Xanthomonas campestris pv pruni C24Chapter 23. Rheological  properties of guar galactomannan solutions filled with PARTiculate inclusions; Chapter 24. Characterization  of chitosan film and structure in solution; Chapter 25. Elsinan , a potential food hydrocolloid produced by elsinoe species: properties and enzymatic degradation; Chapter 26. Effects  of alkali metal salts on the viscoelasticity of hnoran and y -carrageenan; Chapter 27. Texture  and structure of high-pressure -frozen konjac

Chapter 28. Extraction  of highly gelling pectins from sugar beet pulp

Sommario/riassunto

Hydrocolloids