Catalytic kinetics : chemistry and engineering / / Dmitry Yu. Murzin and Tapio Salmi

• Record Nr.: UNINA9911034968803321
• Autore: Murzin Dmitry <1963->
• Pubbl/distr/stampa: Amsterdam, : Elsevier, 2016
• ISBN: 0-444-63753-2
• Edizione: [Second edition.]
• Descrizione fisica: 1 online resource
• Disciplina: 541/.395
• Soggetti: Catalysis; Chemical kinetics
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Machine generated contents note: ; 1.1. History -- ; 1.2. Catalysis -- ; 1.3. Formal Kinetics -- ; 1.4. Acquisition of Kinetic Data -- ; 1.5. Kinetics and Thermodynamics -- ; 1.6. Examples and Exercises -- Reference -- ; 2.1. Homogeneous Catalysis -- ; 2.2. Heterogeneous Catalysis -- ; 2.3. Organocatalysis -- ; 2.4. Examples and Exercises -- Reference -- ; 3.1. Reaction Rate Theory -- ; 3.2. Elementary Reactions in Solutions -- ; 3.3. Reaction Mechanism -- ; 3.4. Quasi-equilibrium Approximation -- ; 3.5. Relationship Between Thermodynamics and Kinetics -- ; 3.6. Transition State Theory of Surface Reactions -- ; 3.7. Rates of Reactions on Nonideal Surfaces -- ; 3.8. Deterministic and Stochastic Models -- ; 3.9. Microkinetic Modeling -- ; 3.10. Compensation Effect -- ; 3.11. Isotope Effects -- ; 3.12. Examples and Exercises -- References -- ; 4.1. Steady State Kinetics of Complex Reactions -- ; 4.2. Basic Routes of Complex Reactions -- ; 4.3. Single-Route Steady-State Reaction -- ; 4.4. Topological Analysis of Complex Reactions -- ; 4.5. Electrical Analogy of Reaction Networks -- ; 4.6. Thermodynamic Consistency of Rate Constants for Complex Networks -- ; 4.7. Kinetic Aspects of Selectivity -- ; 4.8. Parallel Reactions: Kinetic Coupling -- ; 4.9. Reduction of Complexity -- ; 4.10. Polynomial Kinetics -- ; 4.11. Examples and Exercises -- References -- ; 5.1. Homogeneous Acid-Base Catalysis -- ; 5.2. Nucleophilic Catalysis -- ; 5.3. Catalysis by Metal Ions -- ; 5.4. Catalysis by Organometallic Complexes -- ; 5.5. Organocatalysis -- ; 5.6. Polymerization Catalysis ; -- ; 5.7. Examples and Exercises -- References -- ; 6.1. Enzymatic Catalysis -- ; 6.2. Cooperative Kinetics -- ; 6.3. Inhibition -- ; 6.4. Effects of pH -- ; 6.5. Single Molecule Enzymology -- ; 6.6. Enantioselectivity in Enzyme Catalyzed Reactions -- ; 6.7. Generalized Rate Laws for Enzymatic Reactions -- ; 6.8. Heterogeneous Systems/Immobilized Enzymes -- ; 6.9. Examples and Exercises -- References -- ; 7.1. Reactions on Ideal Surfaces -- ; 7.2. Reactions on Nonideal Surfaces -- ; 7.3. Selectivity -- ; 7.4. Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode -- ; 7.5. Solvent Effects -- ; 7.6. Ionic Species -- ; 7.7. Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions -- ; 7.8. Electrocatalytic Kinetics -- ; 7.9. Photocatalytic Kinetics -- ; 7.10. Nanokinetics -- ; 7.11. Examples and Exercises -- References -- ; 8.1. General -- ; 8.2. Combined Catalytic and Noncatalytic Reactions -- ; 8.3. Multiple Catalysts of the Same Type -- ; 8.4. Multiple Catalysts of Different Types -- ; 8.5. Examples and Exercises -- References -- ; 9.1. Transient Kinetics -- ; 9.2. Relaxation Methods -- ; 9.3. Temperature-Programmed Desorption -- ; 9.4. Oscillations -- ; 9.5. Dynamic Catalyst Changes -- ; 9.6. Examples and Exercises -- References -- ; 10.1. Catalytic Multi-Phase Systems -- ; 10.2. Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials -- ; 10.3. Liquid-Liquid Diffusion, Phase-Transfer Catalysis -- ; 10.4. Catalytic Two-Phase Systems -- ; 10.5. Mass Transfer and Enzymatic Kinetics -- ; 10.6. External Mass Transfer -- ; 10.7. Internal Diffusion and Selectivity -- ; 10.8. Internal Diffusion and Deactivation -- ; 10.9. Elucidation of the Impact of Mass Transfer -- ; 10.10. Three-Phase Systems -- ; 10.11. Examples and Exercises -- References -- ; 11.1. Basic Principles -- ; 11.2. Heuristic Design of Experiments -- ; 11.3. Parameter Estimation: Classical Methods -- ; 11.4. Parameter Estimation: Regression -- ; 11.5. Numerical Strategies -- ; 11.6. Analysis of Parameters -- ; 11.7. Model Discrimination -- ; 11.8. Software -- ; 11.9. Case Studies -- References.