Donor-Acceptor Cyclopropanes in Organic Synthesis

• Record Nr.: UNINA9911020239403321
• Autore: Banerjee Prabal
• Pubbl/distr/stampa: Newark : , : John Wiley & Sons, Incorporated, , 2024; ©2024
• ISBN: 9783527835652; 3527835652; 9783527835638; 3527835636
• Edizione: [1st ed.]
• Descrizione fisica: 1 online resource (467 pages)
• Altri autori (Persone): BijuAkkattu T
• Disciplina: 572.65
• Soggetti: Cyclopropane; Chemical reactions
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Nota di contenuto: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- 1 Introduction to the Chemistry of Donor–Acceptor Cyclopropanes: A Historical and Personal Perspective -- 1.1 Introduction -- 1.2 My Personal Entry to Donor–Acceptor Cyclopropanes -- 1.3 A Few Principles of the Chemistry of Donor–Acceptor Cyclopropanes -- 1.4 Remarks Regarding the Terminology Applied to the Use of Donor–Acceptor Cyclopropanes -- 1.5 Conclusions -- Abbreviations -- References -- 2 Understanding the Reactivity of Donor–Acceptor Cyclopropanes: Structural and Electronic Analysis -- 2.1 Introduction -- 2.2 Activated Cyclopropanes -- 2.3 Donor–Acceptor Cyclopropanes (DACs) -- 2.4 Computational and Kinetic Investigations -- 2.5 Concluding Remarks -- References -- 3 Cycloaddition and Annulation Reactions of Donor–Acceptor Cyclopropanes -- 3.1 Introduction -- 3.2 Formal [3+2]-Cycloaddition with Carbon–Carbon Multiple Bonds -- 3.2.1 General Aspects -- 3.2.2 Formal [3+2]-Cycloaddition with C=C Double Bond -- 3.2.3 Formal [3+2]-Cycloaddition with Triple C≡C Bond -- 3.2.4 [3+2]-Annulation with Aromatic C=C Bond -- 3.2.5 [3+2]-Annulation of D–A Cyclopropanes Involving Aryl/Heteroaryl Donor ; Substituent -- 3.3 Formal [3+2]-Cycloaddition with C=O and C=N Double Bond -- 3.3.1 Formal [3+2]-Cycloaddition with C=O Double Bond
• Sommario/riassunto: This book provides a comprehensive exploration of the use of cyclopropanes in organic synthesis. Edited by Prabal Banerjee and Akkattu T. Biju, it delves into the historical development, structural analysis, and reactivity of cyclopropanes. The book covers a wide array of topics including cycloaddition and annulation reactions, ring-opening processes, and catalytic activation methods. It aims to serve as an in-depth resource for researchers and professionals in the field of organic chemistry, providing detailed procedural information and theoretical insights into the versatile applications of cyclopropanes in synthetic chemistry.