Organic synthesis highlights III / / edited by Johann Mulzer and Herbert Waldmann

• Record Nr.: UNINA9911020196103321
• Pubbl/distr/stampa: Weinheim ; ; New York, : Wiley-VCH, c1998
• ISBN: 9786611764647; 9781281764645; 1281764647; 9783527619962; 3527619968; 9783527620517; 3527620516
• Descrizione fisica: 1 online resource (477 p.)
• Altri autori (Persone): MulzerJ <1944-> (Johann); WaldmannH (Herbert)
• Disciplina: 547.2
• Soggetti: Organic compounds - Synthesis; Chemistry, Organic
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Organic Synthesis Highlights III; Contents; Catalytic Asymmetric Synthesis Using New Enolato-, Amido-, and Organolithium Chemistry; Steric and Stereoelectronic Effects in the Palladium Catalyzed Allylation; Asymmetric Alkylation of Amide Enolates with Pseudoephedrine as Chiral Auxiliary - Unexpected Influence of Additives?; Catalytic Asymmetric Carbonyl-Ene Reactions; Chiral 2-Amino-1,3-butadienes: New Reagents for Asymmetric Cycloadditions; Recent Developments in the Enantioselective Syntheses of Cyclopropanes; Enantioselective Rhodium(II) Catalysts; Oxazaborolidines and Dioxaborolidines in Enantioselective CatalysisEnantioselective Catalytic Hydrogenation; The Sharpless Asymmetric Aminohydroxylation of Olefins; Epoxides in Asymmetric Synthesis: Enantioselective Opening by Nucleophiles Promoted by Chiral Transition Metal Complexes; Asymmetric Deprotonation as an Efficient Enantioselective Preparation of Functionalized Secondary ; Alcohols and Amino-Alcohols; Planar-Chiral Ferrocenes: Synthetic Methods and Applications; Asymmetric Autocatalysis with Amplification of Chirality; Resolution of Racemates by Distillation with Inclusion Compounds; Absolute Asymmetric Synthesis by Irradiation of Chiral CrystalsCyclopentadienyl Ruthenium Complexes: Valuable Assistents in the Construction of Carbon-Carbon Bonds; Transition Metal Catalyzed Synthesis of Seven-Membered Carbocyclic Rings; [4+4]-Cycloaddition Reactions in the Total Synthesis of Naturally Occurring Eight-Membered Ring Compounds; "New" Reagents for the "Old' Pinacol Coupling Reaction; Exciting Results from the Field of Homogeneous Two-Phase Catalysis; Palladium-Catalyzed Amination of Aryl Halides; The Metal-mediated Oxidation of Organic Substrates via Organometallic Intermediates:Recent Developments and Questions of DisputeThe Oxofunctionalization of Alkanes; Cooperativity in Rh2 Complexes: High Catalytic Activity and Selectivity in the Hydroformylation of Olefins; Synthesis of Optically Active Macromolecules Using Metallocene Catalysts; Discovering Biosynthetic Pathways - A Never Ending Story; Peptide Ligases - Tools for Peptide Synthesis; Synthetic Ribozymes and Deoxyribozymes; Enzyme Mimics; Metal-Assisted Peptide Organization: From Coordination Chemistry to De Novo Metalloproteins; Artificial Replication SystemsLiCI04 and Organic Solvents - Unusual Reaction Media; Reactions in Supercritical Carbon Dioxide; The Selective Blocking of trans-Diequatorial, Vicinal Diols; Applications in the Synthesis of Chiral Building Blocks and Complex Sugars; Oxidative Polycyclization Versus the "Polyepoxide cascade": New Pathways in Polyether (Bio)synthesis?; Radical Reactions as Key Steps in Natural Product Synthesis; Light-Directed Parallel Synthesis of Up to 250 000 Different Oligopeptides and Oligonucleotides; Opportunities for New Chemical Libraries: Unnatural Biopolymers and Diversomers
• Sommario/riassunto: A collection of articles on various topics of organic synthesis -- short, precise and topical, written by leading experts in their fields. Organic synthesis is a core subject in organic chemistry, and volumes I and II have been very successful.The topics reflect modern and up-to-date problems and research areas in organic synthesis. Readers will learn about the key synthetic strategies that are important in their daily work. A large number of references is included for each article, making the primary literature easily accessible.This is a 'must-have' book for any organic chemi