1.

Record Nr.

UNINA9911019885603321

Titolo

Metal-coordination polymers / / edited by Alaa S. Abd-El-Aziz ... [et al.]

Pubbl/distr/stampa

Hoboken, N.J., : John Wiley & Sons, c2005

ISBN

9786610277155

9781280277153

1280277157

9780470294390

0470294396

9780471727651

0471727652

9780471727644

0471727644

Descrizione fisica

1 online resource (434 p.)

Collana

Macromolecules containing metal and metal-like elements ; ; v. 5

Altri autori (Persone)

Abd-El-AzizAlaa S

Disciplina

547/.7

Soggetti

Polymers

Metal complexes

Macromolecules

Polymerization

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Caption title.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Macromolecules Containing Metal and Metal-Like Elements Volume 5; Contributors; Contents; Preface; Series Preface; 1. Introduction to Metal-Coordination Polymers; I. Introduction; II. Polymer Solubility; III. Polymer Formation; IV. Complex Structures; V. Schiff Base Polymers; VI. Porphyrin Systems; VII. Phthalocyanine Systems; VIII. Pyridine and Related Systems; IX. Miscellaneous Ring and Multisite Systems; X. Coordination Networks Constructed from Organometallic Ligand Spacers; XI. References; 2. Synthetic Strategies for Inert Metal-Skeletal Polymers; I. Overview Of Metal-Skeletal Polymers

II. Step-Growth SynthesisA. Step-Condensation Synthetic Generalities; B. Synthesis via Functionalized Metal Species; C. Synthesis via Bridging



Ligand Coordination; D. Synthesis via Bridging Ligand Formation; E. Step-Addition Syntheses; III. Chain Polymerization; A. Radical Polymerization; B. Cationic Polymerization; C. Anionic Polymerization; IV. Ring-Opening Polymerization; A. Coordination Ring-Opening Polymerization; B. Organometallic Ring-Opening Polymerization; V. Redox Polymerization; A. Reductive Coupling Synthesis; B. Oxidative Coupling Synthesis; C. Miscellaneous Redox Synthesis

VI. ConclusionsVII. Acknowledgments; VIII. References; 3. Metallo-Supramolecular Polymers: Synthesis, Material Properties, and Potential Future Applications; I. Introduction; II. Metallo-Supramolecular Polymers; A. Linear Coordination Polymers; 1. Synthetic Strategies; 2. "Switching" (Reversing) the Metal-Ligand Bonding; 3. Thin-Film Morphology; B. Terpyridine-Containing Poly(methyl methacrylate)s; 1. Copolymers; 2. Terpolymers; III. Summary; IV. Acknowledgments; V. References; 4. Coordination/Organometallic Oligomers and Polymers of Palladium and Platinum: Focus on Metal-Containing Backbone

I. IntroductionII. Mono-Palladium and Platinum Fragment-Containing Polymers; A. Organometallic and Coordination Polymers (M-C); B. Coordination Polymers via the M-N Bond; C. Coordination/Organometallic Polymers with Cyanide, Isocyanide, and Nitrile Bridges; D. Coordination Polymers via the M-O, M-S, and M-P Bonds; E. Organometallic Polymers with Bi-, Tri-, and Tetranuclear Clusters; F. Polymers Built Upon Weak Homonuclear M···M Interactions; III. Conclusion; IV. Acknowledgments; V. References; 5. Metal-Containing Polymers for Optoelectronic Applications; I. Introduction; II. Background

A. Metal Complexes UsedB. Metal Complexes as Electroluminescence Materials; C. Metal Complexes as Photosensitizing Materials; III. Metal Complexes in Conjugated Main Chain; A. Poly(p-Phenylenevinylene) Incorporated with [Ru(tpy)(2)](2+) Complexes; B. Conjugated Polymers with Ruthenium Dipyridophenazine Complexes; C. Conjugated Polymers with Aromatic Oxadiazole and Phenanthroline Moieties; D. Metal Complex on Other Types of Polymer Main Chain; IV. Conjugated Polymers with Pendant Metal Complexes; V. Metal-Containing Polymers for Ultrathin Film Formation; VI. Summary; VII. Acknowledgments

VIII. References

Sommario/riassunto

This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. The fifth volume in this series provides useful descriptions of the transition metals and their applications. Transition Metals are covered in 2 volumes, the second part is covered in Volume 6.