Novel concepts in catalysis and chemical reactors : improving the efficiency for the future / / edited by Andrzej Cybulski, Jacob A. Moulijn, Andrzej Stankiewicz

• Record Nr.: UNINA9911019806403321
• Pubbl/distr/stampa: Weinheim, : Wiley-VCH, c2010
• ISBN: 9783527641536; 352764153X; 9783527630899; 3527630899; 9783527630882; 3527630880
• Descrizione fisica: 1 online resource (824 p.)
• Altri autori (Persone): CybulskiAndrzej <1938->; MoulijnJacob A; StankiewiczAndrzej I
• Disciplina: 660.2995
• Soggetti: Catalysts; Chemical reactors
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Cover; Title; Copyright; Preface; List of Contributors; 1: Molecular Catalytic Kinetics Concepts; 1.1 Key Principles of Heterogeneous Catalysis; 1.2 Elementary Rate Constants and Catalytic Cycle; 1.3 Linear Activation Energy-Reaction Energy Relationships; 1.4 Microkinetic Expressions; Derivation of Volcano Curve; 1.5 Compensation Effect; 1.6 Hydrocarbon Conversion Catalyzed by Zeolites; 1.7 Structure Sensitive and Insensitive Reactions; 1.8 The Nonmetal Atom Sharing Rule of Low-Barrier Transition States; 1.9 Summary; 2: Hierarchical Porous Zeolites by Demetallation; 2.1 Zeolites and Catalyst Effectiveness2.2 Hierarchical Zeolites; 2.3 Mesoporous Zeolites by Demetallation; 2.4 Desilication; 2.5 Conclusions and Outlook; 3: Preparation of Nanosized Gold Catalysts and Oxidation at Room Temperature; 3.1 Introduction; 3.2 Preparation of Nanosized Gold Catalysts; 3.3 Gas-Phase Oxidation Around Room ; Temperature; 3.4 Conclusions; 4: The Fascinating Structure and the Potential of Metal-Organic Frameworks; 4.1 Introduction; 4.2 Preparation and Structure; 4.3 Applications; 4.4 Conclusion; 5: Enzymatic Catalysis Today and Tomorrow; 5.1 Introduction; 5.2 Enzymatic Catalysis Today5.3 Enzymatic Catalysts of Tomorrow; 5.4 Concluding Remarks; 6: Oxidation Tools in the Synthesis of Catalysts and Related Functional Materials; 6.1 Introduction; 6.2 Preparation Strategies Involving Chemical Oxidative Approaches; 6.3 A Catalytic Oxidation Tool. Fenton Chemistry in Solid Catalyst Synthesis; 6.4 First Concept in Catalyst Design. Shifting Complexation Equilibria for Ion-Exchange by Oxidation of the Organic Chelates; 6.5 Second Concept in Catalyst Design. One-Pot Synthesis of Fe Zeolite Catalysts; 6.6 Third Concept in Catalyst Design. Fenton Detemplation. Mild Organic Template Removal in Micro- and Mesoporous Molecular Sieves6.7 Concluding Remarks; 7: Challenges in Catalysis for Sustainability; 7.1 Introduction; 7.2 Population and Human Resources; 7.3 Food Security; 7.4 Species and Ecosystem; 7.5 Energy; 7.6 Industry; 7.7 The Urban Challenge; 7.8 Future Advances in Catalysis for Sustainability; 7.9 Conclusions; 8: Catalytic Engineering in the Processing of Biomass into Chemicals; 8.1 Introduction; 8.2 Chemicals and Fuels from Biomass; 8.3 Chemical Reaction Engineering in Biomass Transformation8.4 Conclusions and Future Perspectives; 9: Structured Reactors, a Wealth of Opportunities; 9.1 Introduction; 9.2 Monoliths; 9.3 Other Structured Catalysts; 9.4 Foams; 9.5 Why are Industrial Applications of Structured Reactors so Scarce?; 9.6 Concluding Remarks; 10: Zeolite Membranes in Catalysis: What Is New and How Bright Is the Future?; 10.1 Introduction; 10.2 Zeolites: a Versatile, Well-Defined Class of Materials; 10.3 Application Options; 10.4 Potential Applications; 10.5 Current Hurdles; 10.6 Concluding Remarks and Future Outlook
• Sommario/riassunto: The chemical process industry faces a tremendous challenge of supplying a growing and ever more demanding global population with the products we need. The average efficiency at which resources are converted into the final products is however still dramatically low. The most obvious solution is to carry out chemical conversions at much higher yields and selectivity and this is where active and selective catalysts and efficient chemical reactors play a crucial role. Written by an international team of highly experienced editors and authors from academia and industry, this ready reference focuses