1.

Record Nr.

UNINA9910493239203321

Autore

Raden Audrey <1961->

Titolo

When I Came to Die : Process and Prophecy in Thoreau's Vision of Dying / / Audrey Raden

Pubbl/distr/stampa

Amherst : , : University of Massachusetts Press, , [2017]

Baltimore, Md. : , : Project MUSE, , 2017

©[2017]

ISBN

1-61376-475-8

Descrizione fisica

1 online resource (xii, 156 pages )

Disciplina

818/.309

Soggetti

Death in literature

Electronic books.

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Nota di bibliografia

Includes bibliographical references and index.



2.

Record Nr.

UNINA9911019795103321

Autore

Tidwell Thomas T. <1939->

Titolo

Ketenes II / / Thomas T. Tidwell

Pubbl/distr/stampa

Hoboken, N.J., : Wiley-Interscience, c2006

ISBN

9786610288212

9781280288210

1280288213

9780470361771

0470361778

9780471767671

0471767670

9780471767664

0471767662

Edizione

[2nd ed.]

Descrizione fisica

1 online resource (672 p.)

Disciplina

547/.436

Soggetti

Ketenes

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

KETENES II; Contents; Preface; Introduction; References; 1 Structure, Bonding, and Thermochemistry of Ketenes; 1.1 Theoretical and Computational Studies of Ketenes; 1.1.1 Molecular and Electronic Structure and Energy; References; 1.1.2 Theoretical and Computational Studies of Ketene Reactions; References; 1.1.3 Substituent Effects on Ketenes; References; 1.2 Molecular Structure Determinations; References; 1.3 Thermochemistry of Ketenes; References; 2 Spectroscopy and Physical Properties of Ketenes; 2.1 Nuclear Magnetic Resonance Spectroscopy; References

2.2 Ultraviolet Spectra, Photoelectron Spectra, and Chiroptical PropertiesReferences; 2.3 Infrared Spectra and Raman Spectra; References; 2.4 Dipole Moments; References; 2.5 Mass Spectrometry and Gas Phase Ion Chemistry; References; 3 Preparation of Ketenes; 3.1 Ketenes from Ketene Dimers; References; 3.2 Ketenes from Carboxylic Acids and their Derivatives; 3.2.1 Ketenes from Carboxylic Acids and



Anhydrides; 3.2.1.1 Ketenes from Carboxylic Acids; References; 3.2.1.2 Ketenes from Acid Anhydrides; References; 3.2.2 Ketenes from Acyl Halides and Activated Acids; References

3.2.3 Ketenes from Esters3.2.3.1 Ketenes from Ester Enolates; 3.2.3.2 Ketenes by Ester Pyrolysis; References; 3.2.4 Ketenes by Dehalogenation of a-Halo Carboxylic Acid Derivatives; References; 3.3 Ketenes from Diazo Ketones (Wolff Rearrangements); 3.3.1 Thermal Wolff Rearrangement; 3.3.2 Catalyzed Wolff Rearrangement; 3.3.3 Photochemical Wolff Rearrangement; 3.3.4 Other Routes to Ketocarbene Rearrangements; References; 3.4 Ketenes by Photochemical and Thermolytic Methods; 3.4.1 Ketenes from Cyclobutanones and Cyclobutenones; References

3.4.2 Ketenes from Photolysis of Cycloalkanones and EnonesReferences; 3.4.3 Ketenes from Cyclohexadienones and other Cycloalkenones; References; 3.4.4 Ketenes from Dioxinones; References; 3.4.5 Ketenes by Thermolysis of Alkynyl Ethers; References; 3.4.6 Ketenes from other Thermolytic and Photochemical Routes; References; 3.5 Ketenes from Metal Carbene Complexes; References; 3.6 Ketene Formation from Cations and Free Radicals; References; 3.7 Ketenes from Oxidation of Alkynes; References; 3.8 Other Routes to Ketenes; References; 4 Types of Ketenes; 4.1 Carbon-Substituted Ketenes

4.1.1 AlkylketenesReferences; 4.1.2 Alkenylketenes; References; 4.1.3 Alkynyl- and Cyanoketenes; References; 4.1.4 Aryl- and Heteroarylketenes; References; 4.1.5 Cyclopropyl-, Cyclopropenyl-, and Oxiranylketenes; References; 4.1.6 Acylketenes; References; 4.1.7 Imidoylketenes; References; 4.1.8 Cumulene-Substituted Ketenes; References; 4.1.9 Ketenes with Charged, Radical, or Carbenic Side Chains; References; 4.1.10 Fulvenones and Cumulenones; 4.1.10.1 Triafulvenones; 4.1.10.2 Pentafulvenones; References; 4.1.11 Oxoquinone Methides, Oxoxylylenes, and Related Species; References

4.2 Nitrogen-Substituted Ketenes

Sommario/riassunto

The most up-to-date single reference on ketene chemistry for the practicing researcherKetenes are valued by both practicing organic synthetic chemists and pharmaceutical researchers for their ease of preparation, high reactivity, and versatility of use.Ketenes, Second Edition is an updated version of the premier resource on this important class of compounds, and features a comprehensive, self-contained guide to all aspects of ketene chemistry, including:* Types of ketenes* Theoretical studies* Thermochemistry* Ketene preparation* Reactions, including mechani