Supramolecular and self-assembled metal-containing materials / / edited by Alaa S. Abd-El-Aziz ... [et al.]

• Record Nr.: UNINA9911019551503321
• Pubbl/distr/stampa: Hoboken ; ; [Chichester], : Wiley-Interscience, 2009
• ISBN: 9786612455377; 9781282455375; 1282455370; 9780470527085; 0470527080; 9780470527047; 0470527048
• Descrizione fisica: 1 online resource (552 p.)
• Collana: Macromolecules containing metal and metal-like elements ; ; v. 9
• Altri autori (Persone): Abd-El-AzizAlaa S
• Disciplina: 547.7
• Soggetti: Macromolecules; Organometallic compounds; Metal complexes
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and indexes.
• Nota di contenuto: Macromolecules Containing Metal and Metal-Like Elements Volume 9; Contents; Preface; Series Preface; 1. Supramolecular Structures and Functions with Inorganic Building Blocks; I. Introduction; II. Hybrid Lipid Thin Films; III. Layer-by-Layer Assemblies; IV. Structure Transcription; V. Functional Mesoporous Hybrids; VI. Future Perspectives; VII. Acknowledgments; VIII. References; 2. Self-Assembly of Hydrophilic Polyoxometalate Macroanions in Dilute Solutions; I. Introduction; II. Solution Behavior of POM Macroions: Soluble but Still Aggregate; III. Characterization of the Supramolecular StructuresIV. Controlling the Blackberry Formation and Blackberry Size by Changing Solvent Quality; V. Counterion Association around Discrete POM Macroions; VI. Counterion Condensation around Blackberries; VII. Identification of the Driving Forces Responsible for the Blackberry Formation; VIII. Soft Nature of the Blackberries-Effect of Additional Hydrogen Bonding; IX. Weak Electrolyte Type POMs; X. Effect of Additional Electrolytes; XI. ; Kinetic Process of Blackberry Formation; XII. Cation Transport over the Anionic Blackberry Membrane; XIII. Macroions in Solution: An important Linkage among Simple Ions, Polymers, Colloids, and BiosystemsXIV. Conclusions; XV. Acknowledgments; XVI. References; 3. Supramolecular Structures and Polyoxometalates; I. Introduction; II. Supramolecular Features of Polyoxometalate-Supported Transition-Metal Complexes; III. Polyoxometalate Crown Ether Complexes with Supramolecular cations; IV. Supramolecular Water Clusters Associated with Polyoxometalates; V. Concluding Remarks; VI. Acknowledgements; VII. References; 4. Supramolecular Coordination Networks Employing Sulfonate and Phosphonate Linkers: From Layers to Open StructuresI. Introduction; II. The Sulfonate Group as a Ligand; III. Layered Metal Sulfonates; IV. Nonlayered Metal Sulfonates; A. Dynamic and Crystalline Metal Sulfonate Frameworks; B. Hydrogen Bonded Second Sphere Coordination Networks; V. Metal phosphonates; VI. Conclusion; VII. References; 5. Transition-Metal-Based Linear Chain Compounds; I. Introduction; II. Ligand-Supported Metal Chains; A. Linear Chains of Chromium; B. Linear Metal Chains of Cobalt; C. Linear Chains of Copper; D. Linear Chains of NickelE. Linear Chains of Palladium; III. Unsupported Metal Chains; A. Linear Chain Compounds of Rhodium; B. Linear Chain of Iridium; C. The Platinum Blues; IV. Concluding Remarks; V. References; 6. Boronate-Linked Materials: Ranging from Amorphous Assemblies to Highly Structured Networks; I. Introduction and Scope; II. Supramolecular Boronate Assemblies; A. ""Traditional"" Hydrogen Bonded Supramolecular Assemblies; B. ""Novel"" Phenyl-Boron-Phenyl Sandwich Supramolecular Assembly; C. Coordination-Based Macrocyclic Assemblies; D. Coordination-Based Linear Assemblies; III. Covalently Linked Boronate Assemblies
• Sommario/riassunto: This book series Macromolecules Containing Metal and Metal-like Elements brings new concepts and developments in the titled area of research. Volume 9 focuses attention on the area of supramolecular chemistry, supramolecular architecture and supramolecular self-assemblies that involve materials containing metals and metal-like elements and the potential applications of these interesting hybrid materials.