1.

Record Nr.

UNINA9911019428603321

Autore

Tietze Lutz-Friedjan

Titolo

Domino reactions in organic synthesis / / Lutz F. Tietze, Gordon Brasche, and Kersten M. Gericke

Pubbl/distr/stampa

Weinheim, : Wiley-VCH, c2006

ISBN

9786610722679

9781280722677

1280722673

9783527609925

352760992X

9783527608683

3527608680

Descrizione fisica

1 online resource (633 p.)

Altri autori (Persone)

BrascheGordon <1976->

GerickeKersten M. <1976->

Disciplina

547.1393

Soggetti

Organic compounds - Synthesis

Chemical reactions

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Domino Reactions in Organic Synthesis; Table of Contents; Preface; Abbreviations; Introduction; Classification; 1 Cationic Domino Reactions; 1.1 Cationic/Cationic Processes; 1.1.1 Cationic/Cationic/Cationic Processes; 1.2 Cationic/Pericyclic Processes; 1.3 Cationic/Reductive Processes; 2 Anionic Domino Reactions; 2.1 Anionic/Anionic Processes; 2.1.1 Anionic/Anionic/Anionic Processes; 2.1.2 Fourfold and Higher Anionic Processes; 2.1.3 Two- and Threefold Anionic Processes Followed by a Nonanionic Process; 2.2 Anionic/Radical Processes; 2.3 Anionic/Pericyclic Processes

2.3.1 Anionic/Pericyclic Processes Followed by Further Transformations2.4 Anionic/Transition Metal-Catalyzed Processes; 2.5 Anionic/Oxidative or Reductive Processes; 3 Radical Domino Reactions; 3.1 Radical/Cationic Domino Processes; 3.2 Radical/Anionic Domino Processes; 3.3 Radical/Radical Domino Processes; 3.3.1 Radical/Radical/Anionic Domino Processes; 3.3.2



Radical/Radical/Radical Domino Processes; 3.3.3 Radical/Radical/Pericyclic Domino Processes; 3.3.4 Radical/Radical/Oxidation Domino Processes; 3.4 Radical/Pericyclic Domino Processes; 4 Pericyclic Domino Reactions

4.1 Diels-Alder Reactions4.1.1 Diels-Alder/Diels-Alder Reactions; 4.1.2 Diels-Alder Reactions/Sigmatropic Rearrangements; 4.1.3 Diels-Alder/Retro-Diels-Alder Reactions; 4.1.4 Diels-Alder Reactions/Mixed Transformations; 4.1.5 Hetero-Diels-Alder Reactions; 4.2 1,3-Dipolar Cycloadditions; 4.3 [2+2] and Higher Cycloadditions; 4.4 Sigmatropic Rearrangements; 4.5 Electrocyclic Reactions; 4.6 Ene Reactions; 4.7 Retro-Pericyclic Reactions; 5 Photochemically Induced Domino Processes; 5.1 Photochemical/Cationic Domino Processes; 5.2 Photochemical/Anionic Domino Processes

5.3 Photochemical/Radical Domino Processes5.4 Photochemical/Pericyclic Domino Processes; 5.5 Photochemical/Photochemical Domino Processes; 5.6 Photochemical/Transition Metal-Catalyzed Domino Processes; 6 Transition Metal-Catalyzed Domino Reactions; 6.1 Palladium-Catalyzed Transformations; 6.1.1 The Heck Reaction; 6.1.1.1 Domino Heck Reactions; 6.1.1.2 Heck/Cross-Coupling Reactions; 6.1.1.3 Heck/Tsuji-Trost Reactions; 6.1.1.4 Heck Reactions/CO-Insertions; 6.1.1.5 Heck Reactions/C-H-Activations; 6.1.1.6 Heck Reactions: Pericyclic Transformations; 6.1.1.7 Heck Reactions/Mixed Transformations

6.1.2 Cross-Coupling Reactions6.1.2.1 Suzuki Reactions; 6.1.2.2 Stille Reactions; 6.1.2.3 Sonogashira Reactions; 6.1.2.4 Other Cross-Coupling Reactions; 6.1.3 Nucleophilic Substitution (Tsuji-Trost Reaction); 6.1.4 Reactions of Alkynes and Allenes; 6.1.5 Other Pd(0)-Catalyzed Transformations; 6.1.6 Pd(II)-Catalyzed Transformations; 6.2 Rhodium-Catalyzed Transformations; 6.2.1 Formation of Carbenes; 6.2.2 Hydroformylations; 6.2.3 Other Rhodium-Catalyzed Transformations; 6.3 Ruthenium-Catalyzed Transformations; 6.3.1 Metathesis Reactions; 6.3.1.1 Metathesis-Metathesis Processes

6.3.1.2 Metathesis/Heck Reaction/Pericyclic Reaction/Hydrogenation

Sommario/riassunto

Domino reactions enable you to build complex structures in one-pot reactions without the need to isolate intermediates- a dream comes true. In this book, the well-respected expert, Professor Lutz Tietze, summarizes the possibilities of this reaction type - an approach for an efficiant, economically benificial and ecologicalbenign synthesis.A definite must for every organic chemist.



2.

Record Nr.

UNINA9910968175203321

Autore

Mak Geertje

Titolo

Doubting sex : inscriptions, bodies and selves in nineteenth-century hermaphrodite case histories / / Geertje Mak

Pubbl/distr/stampa

Manchester : , : Manchester University Press, , 2012

Manchester, UK : , : Manchester University Press, , [2013]

©2012

ISBN

9781847794697

1847794696

9781781702628

1781702624

9781847794291

1847794297

Edizione

[1st ed.]

Descrizione fisica

1 online resource (297 pages) : digital file(s)

Disciplina

616.694009034

Soggetti

Intersexuality - History - 19th century

Gender identity - History

Sex role - History

History

Social & Cultural History

SOCIAL SCIENCE - Gender Studies

Gender studies, gender groups

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Introduction -- Inscription. Secrecy and disclosure: politics of containment -- Early sex reassignments and the absence of a sex of self -- Herculine Barbin -- Body. How to get the semen to the neck of the womb -- Justine Jumas: conflicting body politics -- The dislodgement of the person -- Self. Sex assignment around 1900: from a legal to a clinical issue -- The turn inwards -- Scripting the self: N. O. Body's autobiography -- Conclusion.

Sommario/riassunto

"An adolescent girl is mocked when she takes a bath with her peers, because her genitals look like those of a boy. A couple visits a doctor



asking to 'create more space' in the woman for intercourse. A doctor finds testicular tissue in a woman with appendicitis, and decides to keep his findings quiet. These are just a few of the three hundred European case histories of people whose sex was doubted during the long nineteenth century that Geertje Mak draws upon in her remarkable new book. How did people deal with such situations? How did they decide to which sex a person should belong? This groundbreaking analysis of clinical case histories shows how sex changed from an outward appearance inscribed in a social body to something to be found deep inside body and self. A fascinating, easy to follow, yet sophisticated argument addressing major issues of the history of body, sex, and self, this volume will fit advanced undergraduate courses, while challenging specialists."--Publisher's website.