1.

Record Nr.

UNINA9911006806103321

Autore

Hewitt Norman

Titolo

Compounding precipitated silica in elastomers / / Norman Hewittt

Pubbl/distr/stampa

Norwich, NY, : William Andrew Pub., c2007

ISBN

0-08-094728-X

1-282-76962-6

9786612769627

1-282-01358-0

9786612013584

0-8155-1653-3

1-60119-517-6

Descrizione fisica

1 online resource (603 p.)

Collana

Plastics design library

Disciplina

678

Soggetti

Elastomers

Rubber

Silica

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Front Cover; Compounding Precipitated Silica in Elastomers; Copyright Page; Table of Contents; Acknowledgements; Preface; Chapter 1. SILICA AS A REINFORCING FILLER; 1.1 Introduction; 1.2 Manufacture of Precipitated Silica; 1.3 Silica and Carbon Black; 1.4 Silica Surface Area; 1.5 Silica Free Water; 1.6 Silica Free Water, Affect on Visible Dispersion; 1.7 Silica Surface Silanol Groups; 1.8 Silica pH; 1.9 Soluble Salts in Silica; 1.10 Physical Form and Sensity of Silica; 1.11 Other Silica Properties; 1.12 Silane Treated Silicas; Chapter 2. COMPOUNDING PRECIPITATED SILICA IN NATURAL RUBBER

2.1 Introduction2.2 Silica and Carbon Black; 2.3 Activation: Zinc Oxide; 2.4 Cure Activation: Glycols; 2.5 Acceleration with Secondary Accelerators in Normal Sulfur Systems; 2.6 Acceleration: Single Accelerators in Normal Sulfur Systems; 2.7 Acceleration: Single Accelerators;  Vulcanizate Properties; 2.8 Acceleration: Low Sulfur/Sulfur Donor Systems; 2.9 Reversion; 2.10 Antioxidant Systems:



Non-staining; 2.11 Plasticization; 2.12 Tear Resistance; 2.13 Tear Resistance: Contour Curve Studies of Silica Content Effects; 2.14 Tear Resistance: Silica Primary Particle Size; 2.15 Tear Resistance

Non-Marking Solid tires2.16 Shelf Aged Stiffness and Green Strength; 2.17 Peroxide Cure; 2.18 Peroxide Curing: Silica Reinforcement and Structure; 2.19 Peroxide Curing: Silica Surface Area; 2.20 Peroxide Cure: Silane Coupling; 2.21 Silane Coupling: Sulfur Cure Systems; 2.22 Zinc-Free Cure Systems; 2.23 Zinc-Free Cure Systems: Polyisoprene (IR); 2.24 Brass Adhesion; 2.25 Brass Adhesion Mechanism; 2.26 Adhesion to Textile Fabrics;  the HRH System; 2.27 Fabric Adhesion: Dynamic Testing; 2.28 Heat Resistance; Natural Rubber Formulary; Chapter 3. COMPOUNDING PRECIPITATED SILICA IN EMULSION SBR

3.1 Introduction3.2 Silica and Carbon Black; 3.3 Cure Systems: Activation with Glycols; 3.4 Cure System: Zinc Oxide Activation; 3.5 Cure System: Magnesium Oxide Activation; 3.6 Cure System: Lead oxide (Litharge) Activation; 3.7 Cure System: Stearic Acid; 3.8 Cure Systems: Primary, Secondary Accelerators; 3.9 Cure Systems: Single Accelerators; 3.10 Cure Systems: Sulfur Concentration; 3.11 Plasticization; 3.12 Antioxidants; 3.13 Tear Resistance: Silica Primary Particle Size; 3.14 Tear Resistance: Silica Content; 3.15 Fabric Adhesion; 3.16 Heat Resistance; 3.17 Silane Coupling

3.18 Silane Coupling: CompetitionEmulsion SBR Formulary; Chapter 4. COMPOUNDING PRECIPITATED SILICA IN SOLUTION SBR AND BR; 4.1 Introduction; 4.2 Silica and Carbon Black; 4.3 Zinc-Free Cure Systems; 4.4 Zinc-Free Cure Systems: Accelerators & Sulfur; 4.5 Zinc-Free Cure Systems: Polymer Effects; 4.6 Zinc-Free Cure Systems: Zinc Oxide and HMT; 4.7 Zinc-Free Cure Systems: Effects of Additives; 4.8 Zinc-Free Cure Systems: Sulfur Content; 4.9 Zinc-Free Cure System: Antioxidants; 4.10 Zinc-Free Cure Systems: Processing; 4.11 Zinc-Free Systems: Plasticizers

4.12 Zinc-Free Systems: Additive Plasticizers

Sommario/riassunto

This valuable guide to compounding elastomers with precipitated silica covers principles, properties, mixing, testing and formulations from a practical perspective. This handbook and reference manual will serve those who work on part design, elastomer formulation, manufacturing and applications of elastomers. Ample discussion of compound specifications adds to the usefulness of this book to practitioners. Comparisons of carbon black and silica compounds throughout the book allow readers to select the most suitable formulation for applications ranging from tires to electrical insulation to shoe