1.

Record Nr.

UNINA9911006679603321

Autore

Kuptsov A. H

Titolo

Handbook of fourier transform Raman and infrared spectra of polymers / / A.H. Kuptsov, G.N. Zhizhin

Pubbl/distr/stampa

Amsterdam ; ; New York, : Elsevier, 1998

ISBN

1-282-16719-7

9786612167195

0-08-053194-6

Descrizione fisica

1 online resource (571 p.)

Collana

Physical sciences data ; ; 45

Altri autori (Persone)

ZhizhinG. N (German Nikolaevich)

Disciplina

547.7/046

Soggetti

Polymers - Spectra

Fourier transform spectroscopy

Raman spectroscopy

Fourier transform infrared spectroscopy

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references (p. xxx-xxxiii) and indexes.

Nota di contenuto

Front Cover; Handbook of Fourier Transform Raman and Infrared Spectra of Polymers; Copyright Page; Contents; Historical introduction; The essential principles of infrared absorption and Raman scattering; Important advantages of Raman spectroscopy; Main stages in the development of Fourier transform infrared spectroscopy; FTIR spectrometer - optical correlometer; Fourier transform Raman spectroscopy; Characterization of samples; Polymer classification; Polymer classification guide; Experimental conditions; Comments on data presentation; References; Appendix; Spectral interpretation literature

Spectral collectionsAcknowledgements; Spectra; Alphabetical compound name index; Alphabetical synonym or TM index; Alphabetical general formula index; Chemical Abstracts Service registry number index

Sommario/riassunto

A collection of infrared and Raman spectra of 500 natural and synthetic polymers of industrial importance is presented  in this book. A large variety of compounds are included, starting with linear polyolefins and finishing with complex biopolymers and related compounds. The



spectra were registered using Infrared Fourier Transform Spectrometers in the laboratory of the All-Russia Institute of Forensic Sciences. The IR and Raman spectra are presented together on the same sheet. The accompanying data include general and structure formulae, CAS register numbers, and sample preparation conditions.

2.

Record Nr.

UNINA9911018976103321

Titolo

Main group metals in organic synthesis / / edited by Hisahi Yamamoto and Koichiro Oshima

Pubbl/distr/stampa

Weinheim, Germany, : Wiley-VCH, 2004

ISBN

9786610520442

9781280520440

1280520442

9783527605354

3527605355

9783527602605

3527602607

Descrizione fisica

1 online resource (907 p.)

Altri autori (Persone)

YamamotoHisashi

OshimaKoichiro <1947->

Disciplina

547.05

Soggetti

Organometallic compounds - Synthesis

Organic compounds

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Main Group Metals in Organic Synthesis; Contents; Preface; List of Contributors; Volume 1; 1 Lithium in Organic Synthesis; 1.1 Introduction; 1.2 Nature of Organolithium Compounds; 1.2.1 Overview; 1.2.2 Structural Features; 1.2.3 Configurational Stability; 1.2.4 Titration of Organolithium Compounds; 1.3 Methods for the Preparation of Organolithium Compounds; 1.3.1 Overview; 1.3.2 Reductive Lithiation using Lithium Metal; 1.3.3 Preparation of Organolithium Compounds from Another Organolithium Compounds; 1.3.3.1 Deprotonation;



1.3.3.2 Halogen-Lithium Exchange; 1.3.3.3 Transmetallation

1.3.3.4 Carbolithiation1.3.3.5 Miscellaneous; 1.4 Methods for Construction of Carbon Frameworks by Use of Organolithium Compounds; 1.4.1 Overview; 1.4.2 Stereospecificity; 1.4.3 Synthetic Application; 1.4.3.1 C-C Bond Formation: Conversion of C-Li to Halogen-Li; 1.4.3.2 C-C Bond Formation: Conversion of C-Li to O-Li; 1.4.3.3 C-C Bond Formation: Conversion of C-Li to N-Li; 1.5 References; 2 Rubidium and Cesium in Organic Synthesis; 2.1 Introduction; 2.2 Organo-, Silyl-, Germyl-, and Stannylmetal; 2.3 Fluoride Ion Source; 2.3.1 Nucleophilic Fluorination; 2.3.2 Desilylation Reactions

2.3.2.1 Carbanion Equivalent Formation2.3.2.2 Desilylation-Elimination; 2.4 Electrophilic Fluorination - Cesium Fluorosulfate; 2.5 Cesium Salts as Bases; 2.6 Cesium Enolate; 2.7 Catalytic Use; 2.8 Conclusion; 2.9 References; 3 Magnesium in Organic Synthesis; 3.1 Introduction; 3.2 Preparation of Organomagnesium Compounds; 3.2.1 Preparation from Alkyl Halides and Mg Metal; 3.2.2 Preparation with Rieke Magnesium; 3.2.3 Transmetalation; 3.2.4 Sulfoxide-Magnesium Exchange (Ligand Exchange Reaction of Sulfoxides with Grignard Reagent); 3.2.5 Hydromagnesation

3.2.6 Metalation (Deprotonation from Strong Carbon Acids)3.2.7 Other Preparative Methods; 3.3 Reaction of Organomagnesium Compounds; 3.3.1 Reaction with Organomagnesium Amides; 3.3.1.1 Preparation of Magnesium Monoamides and Bisamides; 3.3.1.2 Reaction with Organomagnesium Amide; 3.3.2 Cp(2)TiCl(2)- or Cp(2)ZrCl(2)-catalyzed Reaction with Grignard Reagents; 3.3.3 Substitution at Carbon by Organomagnesium Compounds; 3.3.4 Addition to Carbon-Carbon Multiple Bonds; 3.3.5 Addition of Organomagnesium Compounds to Carbonyl Groups; 3.4 Halogen-Magnesium Exchange Reactions

3.4.1 Practical Examples of Halogen-Magnesium Exchange Reactions3.4.1.1 Perfluoro Organomagnesium Reagents; 3.4.1.2 Polyhalogenated Arylmagnesium Reagents; 3.4.1.3 Exchange of Polyhalomethane Derivatives; 3.4.1.4 Preparation of Magnesiated Nitrogen-Heterocycles; 3.4.1.5 Formation of Enolates by Halogen-Magnesium Exchange; 3.4.1.6 Miscellaneous Reactions; 3.4.2 iPrMgBr-induced Halogen-Magnesium Exchange for the Preparation of Polyfunctional Organomagnesium Reagents; 3.4.2.1 Exchange Reaction of Aryl Halides; 3.4.2.2 Exchange Reaction of Heterocyclic Halides

3.4.2.3 Exchange Reaction of Alkenyl Halides

Sommario/riassunto

This is the first handbook to cover in detail all aspects of this fascinating field of chemistry. In this handy two-volume set, readers will instantly find the information they need, clearly structured according to the individual metals in the main groups, hitherto only accessible after much time-consuming research. The result is in indispensable aid for everyday work in the lab.Alongside all the classical organic reactions, this book focuses on the modern variations as well as novel, current reactions in organic synthesis that are closely linked to main group elements - both stoechiometri



3.

Record Nr.

UNINA9910954871103321

Autore

Hübner Hans <1930->

Titolo

Law in Paul's thought / / by Hans Hübner ; translated by James C.G. Greig ; edited by John Riches

Pubbl/distr/stampa

Edinburgh : , : T. & T. Clark, , 1984

ISBN

9780567335975

0567335976

9780567660923

0567660923

Descrizione fisica

1 online resource (199 p.)

Collana

Studies of the New Testament and its world

Disciplina

241/.2

Soggetti

Law (Theology)

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Includes indexes.

Translation of: Das Gesetz bei Paulus.

Nota di bibliografia

Bibliography: pages 167-177.

Sommario/riassunto

"Until now Paul's theology has been treated in exegetical literature almost exclusively as a systematic ntil now Paul's theology has been treated in exegetical literature   almost exclusively as a systematic whole. Here, by contrast, the attempt is made to show how Paul's theology can be adequately understood only when it is seen in relation to its development. There is a decisive process of theological development between Galatians and Romans which in turn must be related to Paul's biography. Law in Paul's Thought  examines the relation between Paul's teaching in Galatians and Romans, arguing that there is a major shift in emphasis between the two. An intriguing and concisely argued monograph, it points to a striking discord within Paul's view of the Law and asks whether these differences should not be explained in terms of development in Paul's theology. H bner skillfully traces the arguments and interconnections between arguments in the different passages, illuminating Paul's theology from law."--Bloomsbury Publishing.