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Record Nr. |
UNINA9911004764103321 |
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Autore |
Procter David J |
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Titolo |
Organic synthesis using samarium diiodide : a practical guide / / David J. Procter, Robert A. Flowers, Troels Skrydstrup |
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Pubbl/distr/stampa |
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Cambridge, : Royal Society of Chemistry, 2010 |
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ISBN |
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9781628708752 |
1628708751 |
9781849730754 |
184973075X |
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Edizione |
[1st ed.] |
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Descrizione fisica |
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1 online resource (221 p.) |
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Altri autori (Persone) |
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FlowersRobert A |
SkrydstrupTroels |
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Disciplina |
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Soggetti |
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Samarium |
Samarium - Reactivity |
Organic compounds - Synthesis |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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9781847551108; i_iv; v_vi; vii; viii; ix_xiii; xiv_xvi; 001_004; 005_019; 020_035; 036_068; 069_144; 145_156; 157_197; 198_204 |
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Sommario/riassunto |
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Samarium diiodide is one of the most important reducing agents available to synthetic organic chemists. The lanthanide(II) reagent acts by single-electron transfer to organic substrates leading to the formation of both radical and/or anionic intermediates. The power of the reagent arises from its versatility - samarium diiodide can be used in processes ranging from functional group conversions to elaborate carbon-carbon bond-forming cyclization sequences that result in a dramatic increase in molecular complexity. In addition, reactions involving samarium diiodide often show high stereoselectiv |
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