1.

Record Nr.

UNINA9910145388903321

Titolo

2008 IEEE International Conference on Computer Design

Pubbl/distr/stampa

[Place of publication not identified], : I E E E, 2008

ISBN

9781509078516

1509078517

9781424426584

1424426588

Descrizione fisica

1 online resource (xvi, 706 pages)

Disciplina

621.38195

Soggetti

Electronic digital computers - Circuits

Computer engineering

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Bibliographic Level Mode of Issuance: Monograph



2.

Record Nr.

UNINA9911019993503321

Titolo

Modern arylation methods / / edited by Lutz Ackermann

Pubbl/distr/stampa

Weinheim, : Wiley-VCH, c2009

ISBN

9786612118500

9781282118508

1282118501

9783527627332

3527627332

Descrizione fisica

1 online resource (563 p.)

Altri autori (Persone)

AckermannLutz

Disciplina

541.39

Soggetti

Arylation

Organic compounds - Synthesis

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Modern Arylation Methods; Contents; Preface; List of Contributors; 1 Arylation Reactions: A Historical Perspective; 1.1 Structure and Bonding of Benzene; 1.2 Syntheses of Substituted (Hetero)Arenes, and the Contents of this Book; Abbreviations; References; 2 Metal-Catalyzed Coupling Reactions with Aryl Chlorides, Tosylates and Fluorides; 2.1 Introduction; 2.2 Coupling Reactions of Aryl Chlorides; 2.2.1 Nickel-Catalyzed Cross-Couplings of Aryl Chlorides; 2.2.2 Palladium-Catalyzed Cross-Coupling Reactions; 2.2.2.1 Suzuki Reaction; 2.2.2.2 Stille Reaction; 2.2.2.3 Hiyama Coupling

2.2.2.4 Negishi Coupling2.2.2.5 Kumada Coupling; 2.3 Coupling Reactions of Aryl Fluorides; 2.4 Coupling Reactions of Aryl Tosylates; 2.5 Conclusions; Abbreviations; References; 3 Palladium-Catalyzed Arylations of Amines and α-C-H Acidic Compounds; 3.1 Introduction; 3.2 Palladium-Catalyzed Arylations of Amines; 3.2.1 Historical Development; 3.2.2 Catalytic Systems; 3.2.2.1 Palladium Sources; 3.2.2.2 Ligands; 3.2.2.3 Bases; 3.2.2.4 Solvents; 3.2.3 Aryl Halides; 3.2.4 Arylsulfonic Acid Esters; 3.2.5 Heteroaromatic Electrophiles; 3.2.6 Amines as Nucleophiles

3.2.7 Amine Derivatives as Nucleophiles3.2.8 Applications; 3.2.9



Mechanistic Aspects; 3.2.10 Chirality; 3.3 Palladium-Catalyzed Arylations of α-C-H Acidic Compounds; 3.3.1 Historical Development; 3.3.2 Catalytic Systems; 3.3.3 α-Arylations of Esters; 3.3.4 α-Arylations of Malonates and α-Cyano Esters; 3.3.5 α-Arylations of Ketones; 3.3.6 α-Arylations of Amides; 3.3.7 α-Arylations of Nitriles; 3.4 Summary and Conclusions; Abbreviations; References; 4 Copper-Catalyzed Arylations of Amines and Alcohols with Boron-Based Arylating Reagents; 4.1 Introduction

4.2 Discovery and Development of a New O-H Bond Arylation Reaction: From Stoichiometric to Catalytic in Copper4.3 Mechanistic Considerations; 4.4 Miscellaneous Applications; 4.4.1 Additional Applications with ArB(OH)(2); 4.4.2 Alternatives to ArB(OH)(2); 4.4.3 Alternatives to Phenols; 4.5 Development of a New N-H Bond Arylation Reaction; 4.5.1 Stoichiometric in Copper; 4.5.2 Alternatives to Boronic Acids; 4.6 Development of a New N-H Bond Arylation Reaction: Catalytic in Copper; 4.6.1 Proposed Mechanism; 4.6.2 Additional Important Non-N-H Arylation Examples; 4.7 Summary and Conclusions

AbbreviationsReferences; 5 Metal-Catalyzed Arylations of Nonactivated Alkyl (Pseudo)Halides via Cross-Coupling Reactions; 5.1 Introduction; 5.2 Palladium-Catalyzed Arylations of Alkyl (Pseudo)Halides; 5.3 Nickel-Catalyzed Arylations of Alkyl (Pseudo)Halides; 5.4 Iron-Catalyzed Arylations of Alkyl (Pseudo)Halides; 5.5 Copper- and Cobalt-Catalyzed Arylations of Alkyl (Pseudo)Halides; Abbreviations; References; 6 Arylation Reactions of Alkynes: The Sonogashira Reaction; 6.1 Introduction; 6.2 Palladium-Catalyzed Reactions: Ligands and Reaction Protocols; 6.2.1 Phosphine-Based Ligands

6.2.1.1 Copper-Free Catalytic Systems

Sommario/riassunto

Today, arylation methods are belonging to the most important reaction types in organic synthesis. Lutz Ackermann, a young and ambitious professor has gathered a number of top international authors to present the first comprehensive book on the topic. Starting from a historical review, the book covers hot topics like Palladium-catalyzed arylation of N-H and alpha-C-H-acidic Bonds, Copper-catalyzed arylation of N-H and O-H Bonds, direct arylation reactions, carbanion aromatic synthesis, arylation reactions of alkenes, alkynes and much more. This compact source of high quality information



3.

Record Nr.

UNINA9910972854303321

Titolo

Attachment theory in clinical work with children : bridging the gap between research and practice / / edited by David Oppenheim, Douglas F. Goldsmith

Pubbl/distr/stampa

New York, : Guilford Press, c2007

ISBN

1-281-12370-6

9786611123703

1-59385-657-1

Edizione

[1st ed.]

Descrizione fisica

1 online resource (272 p.)

Altri autori (Persone)

OppenheimDavid <1958->

GoldsmithDouglas F

Disciplina

618.92/8588

Soggetti

Attachment behavior in children

Attachment disorder in children

Child psychotherapy

Parent and child

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Constructing a relationship formulation for mother and child : clinical application of the working model of the child interview / Charles H. Zeanah -- Keeping the inner world of the child in mind : using the Insightfulness assessment with mothers in a therapeutic preschool / Nina Koren-Karie, David Oppenheim, and Douglas F. Goldsmith -- Intervening with maltreated children and their adoptive parents : identifying attachment-facilitating behavior / Miriam Steele ... [et al.] -- The role of caregiver commitment in foster care : insights from the "This is my baby" interview / Mary Dozier ... [et al.] -- Parental resolution of the child's diagnosis and the parent-child relationship : insights from the Reaction to diagnosis interview / David Oppenheim ... [et al.] -- Attachment and trauma : an integrated approach to treating young children exposed to family violence / Amy L. Busch and Alicia F. Lieberman -- The circle of security project : a case study--"It hurts to give that which you did not receive" / Bert Powell ... [et al.] -- Challenging children's negative internal working models : utilizing



attachment-based treatment strategies in a therapeutic preschool / Douglas F. Goldsmith -- Disorganized mother, disorganized child : the mentalization of affective dysregulation and therapeutic change / Arietta Slade.

Sommario/riassunto

Attachment research has tremendous potential for helping clinicians understand what happens when parent-child bonds are disrupted, and what can be done to help. Yet there remains a large gap between theory and practice in this area. This book reviews what is known about attachment and translates it into practical guidelines for therapeutic work. Leading scientist-practitioners present innovative strategies for assessing and intervening in parent-child relationship problems; helping young children recover from maltreatment or trauma; and promoting healthy development in adoptive and fos