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1. |
Record Nr. |
UNINA9911019723903321 |
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Autore |
Laurence Christian |
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Titolo |
Lewis basicity and affinity scales : data and measurement / / Christian Laurence, Jean-Franc ois Gal |
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Pubbl/distr/stampa |
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Chichester, : Wiley, 2010 |
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ISBN |
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9786612687242 |
9781282687240 |
1282687247 |
9780470681909 |
047068190X |
9780470681893 |
0470681896 |
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Descrizione fisica |
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1 online resource (490 p.) |
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Altri autori (Persone) |
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Disciplina |
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Soggetti |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di contenuto |
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Lewis Basicity and Affinity Scales; Contents; Preface; 1 Lewis Basicity and Affinity Measurement: Definitions and Context; 1.1 The Br ̀ˆonsted Definition of Acids and Bases; 1.2 Scales of Br ̀ˆonsted Basicity and Affinity in Solution; 1.3 Scales of Br ̀ˆonsted Basicity and Affinity in the Gas Phase; 1.4 The Lewis Definition of Acids and Bases; 1.5 Quantum Chemical Descriptions of Lewis Acid/Base Complexes; 1.5.1 Valence-Bond Model; 1.5.2 Perturbation Molecular Orbital Theory; 1.5.3 Variational Supermolecular Method and Energy Decomposition Schemes; 1.5.4 Natural Bond Orbital Theory |
1.5.5 Quantum Theory of Atoms in Molecules1.6 Measurement of Lewis Basicity; 1.6.1 Gas-phase Reactions; 1.6.2 Solution Reactions; 1.6.3 Standard State Transformations; 1.6.4 Choice of Solvent; 1.7 Measurement of Lewis Affinity; 1.8 The Role of the Solvent; 1.9 Spectroscopic Scales of Basicity (Affinity); 1.10 Polybasic Compounds; |
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1.11 Attempts at a Quantitative Formulation of the Lewis Definition of Acids and Bases; 1.11.1 Hard and Soft Acids and Bases; 1.11.2 The ECW and ECT Models; 1.11.3 The Beta and Xi Equation; 1.11.4 A Chemometric Approach |
1.11.5 Quantum Chemical Descriptors for Basicity Scales1.12 Concluding Remarks and Content of Chapters 2-7; References; 2 The Donor Number or SbCl5 Affinity Scale; 2.1 Structure of SbCl5 Complexes; 2.2 Definition of the Donor Number Scale; 2.3 Experimental Determination of the Donor Number; 2.4 The Donor Number Scale: Data; 2.5 Critical Discussion; References; 3 The BF3 Affinity Scale; 3.1 Structure of BF3 Complexes; 3.2 Definition of the BF3 Affinity Scale; 3.3 Experimental Determination of the BF3 Affinity Scale; 3.4 The BF3 Affinity Scale: Data; 3.5 Discussion; 3.5.1 Medium Effects |
3.5.2 Hardness of BF33.5.3 Comparison of the BF3 and SbCl5 Affinity Scales; 3.5.4 Computation of the BF3 Affinity; 3.6 Conclusion; References; 4 Thermodynamic and Spectroscopic Scales of Hydrogen-Bond Basicity and Affinity; 4.1 Structure of Hydrogen-Bonded Complexes; 4.2 Hydrogen-Bond Basicity Scales: Early Works; 4.3 The 4-Fluorophenol Hydrogen-Bond Basicity Scale; 4.3.1 Definition; 4.3.2 Method of Determination; 4.3.3 Polyfunctional Hydrogen-Bond Acceptors; 4.3.4 Data; 4.3.5 Range of Validity of the Scale; 4.4 Hydrogen-Bond Affinity Scales: Early Studies |
4.5 The 4-Fluorophenol Affinity Scale4.6 Comparison of 4-Fluorophenol Affinity and Basicity Scales; 4.7 Spectroscopic Scales; 4.7.1 Infrared Shift of Methanol; 4.7.2 Solvatochromic Shifts of 4-Nitrophenol and 4-Nitroaniline; 4.8 Conclusion; References; 5 Thermodynamic and Spectroscopic Scales of Halogen-Bond Basicity and Affinity; 5.1 Structure of Halogen-Bonded Complexes; 5.2 The Diiodine Basicity Scale; 5.2.1 Definition of the Scale; 5.2.2 Methods for the Determination of Diiodine Complexation Constants; 5.2.3 Temperature Correction; 5.2.4 Solvent Effects; 5.2.5 Data |
5.3 Is the Diiodine Basicity Scale a General Halogen-Bond Basicity Scale? |
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Sommario/riassunto |
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The Lewis concept of acids and bases is discussed in every general, organic and inorganic chemistry textbook. This is usually just a descriptive treatment, as it is not possible to devise a single numerical scale suitable for all occasions. However quantitative Lewis acid-base chemistry can be developed by compiling reaction-specific basicity scales which can be used in specific branches of chemistry and biochemistry. Lewis Basicity and Affinity Scales: Data and Measurementbrings together for the first time a comprehensive range of Lewis basicity/affinity data in one volume. More t |
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2. |
Record Nr. |
UNINA9910962881703321 |
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Titolo |
Therapeutic uses of rap and hip hop / / edited by Susan Hadley and George Yancy |
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Pubbl/distr/stampa |
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New York, : Routledge, c2012 |
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New York : , : Routledge, , 2012 |
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ISBN |
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1-136-65232-9 |
1-136-65233-7 |
0-203-80601-8 |
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Edizione |
[1st ed.] |
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Descrizione fisica |
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1 online resource (429 p.) |
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Altri autori (Persone) |
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HadleySusan <1967-> (Susan Joan) |
YancyGeorge |
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Disciplina |
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Soggetti |
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Music therapy |
Rap (Music) - Psychological aspects |
Hip-hop - Psychological aspects |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Cover; Therapeutic uses of rap and hip-hop; Copyright; Contents; Acknowledgments; Contributors; Introduction: Give 'em Just One Mic: The TherapeuticAgency of Rap and Hip-Hop; Part 1: Historical and Theoretical Perspectives; 1. RA P (Requisite, Ally, Protector) and the Desperate Contemporary Adolescent; 2. Contextualizing Rap Music as a Means of Incorporating into Psychotherapy; 3. The Importance of Hip-Hop for Music Therapists; 4. The Hero's Journey in Hip-Hop and Its Applications in Music Therapy |
5. I t's Bigger Than Hip-Hop: A Hip-Hop Feminist Approach to Music Therapy with Adolescent Females6. Therapeutically and Socially Relevant Themes in Hip-Hop Music: A Comprehensive Analysis of a Selected Sample of Songs; Part 2: Rap and Hip -Hop With At-Risk Youth; 7. Beats, Rhymes, and Life: Rap Therapy in an Urban Setting; 8. Therapeutic Outreach through Bboying (Break Dancing) in Canada's Arctic and First Nations Communities: Social Work through Hip-Hop; 9. Hear Our Voices: A Music Therapy Songwriting Program and the |
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Message of the Little Saints through the Medium of Rap |
10. "Just So You Know, I Miss You So Bad": The Expression of Life and Loss in the Raps of Two Adolescents in Music Therapy11. Naming My Story and Claiming My Self; 12. Yo, Can Ya Flow! Research Findings on Hip-Hop Aesthetics and Rap Therapy in an Urban Youth Shelter; 13. Rap Composition and Improvisation in a Short- Term Juvenile Detention Facility; 14. Song Communication Using Rap Music in a Group Setting with At-Risk Youth; Part 3: Rap With Clients in Specific Clinical Settings; 16. Beat It: The Effects of Rap Music on Adol escents in the Pediatric Medical Setting |
17. "Must Be the Ganja": Using Rap Music in Music Therapy for Substance Use Disorders18. "Morphine Mamma": Creating Original Songs Using Rap with Women with Cancer; 19. Rapping Round the System: A Young Black Man's Journey through a High-Security Hospital; Index |
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Sommario/riassunto |
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In perceiving all rap and hip-hop music as violent, misogynistic, and sexually charged, are we denying the way in which it is attentive to the lived experiences, both positive and negative, of many therapy clients? This question is explored in great depth in this anthology, the first to examine the use of this musical genre in the therapeutic context. The contributors are all experienced therapists who examine the multiple ways that rap and hip-hop can be used in therapy by listening and discussing, performing, creating, or improvising.The text is divided into three sections that explor |
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