Variational principles and methods in theoretical physics and chemistry / / Robert K. Nesbet

• Record Nr.: UNINA9910961260003321
• Autore: Nesbet R. K.
• Pubbl/distr/stampa: Cambridge : , : Cambridge University Press, , 2003
• ISBN: 1-107-13095-6; 1-280-43335-3; 9786610433353; 0-511-17828-X; 0-511-04162-4; 0-511-14877-1; 0-511-30551-6; 0-511-53516-3; 0-511-04386-4
• Edizione: [1st ed.]
• Descrizione fisica: 1 online resource (xiv, 229 pages) : digital, PDF file(s)
• Disciplina: 530.15/564
• Soggetti: Calculus of variations; Mathematical physics; Chemistry, Physical and theoretical - Mathematics
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Title from publisher's bibliographic system (viewed on 05 Oct 2015).
• Nota di bibliografia: Includes bibliographical references (p. 205-223) and index.
• Nota di contenuto: I. Classical mathematics and physics -- ; 1. History of variational theory -- ; 2. Classical mechanics -- ; 3. Applied mathematics -- ; II. Bound states in quantum mechanics -- ; 4. Time-independent quantum mechanics -- ; 5. Independent-electron models -- ; 6. Time-dependent theory and linear response -- ; III. Continuum states and scattering theory -- ; 7. Multiple scattering theory for molecules and solids -- ; 8. Variational methods for continuum states -- ; 9. Electron-impact rovibrational excitation of molecules -- ; IV. Field theories -- ; 10. Relativistic Lagrangian theories.
• Sommario/riassunto: This book brings together the essential ideas and methods behind applications of variational theory in theoretical physics and chemistry. The emphasis is on understanding physical and computational ; applications of variational methodology rather than on rigorous mathematical formalism. The text begins with an historical survey of familiar variational principles in classical mechanics and optimization theory, then proceeds to develop the variational principles and formalism behind current computational methodology for bound and continuum quantum states of interacting electrons in atoms, molecules, and condensed matter. It covers multiple-scattering theory, including a detailed presentation of contemporary methodology for electron-impact rotational and vibrational excitation of molecules. The book ends with an introduction to the variational theory of relativistic fields. Ideal for graduate students and researchers in any field that uses variational methodology, this book is particularly suitable as a backup reference for lecture courses in mathematical methods in physics and theoretical chemistry.