1.

Record Nr.

UNINA9910959258903321

Autore

Abdulagatov Aziz I

Titolo

Binary aqueous and CO[subscript 2] containing mixtures and the Krichevskii parameter / / Aziz I. Abdulagatov, Ilmutdin M. Abdulagatov, Gennadii V. Stepanov

Pubbl/distr/stampa

Hauppauge, N.Y., : Nova Science Publishers, c2010

ISBN

1-61761-451-3

Edizione

[1st ed.]

Descrizione fisica

1 online resource (237 p.)

Collana

Chemistry research and applications series

Altri autori (Persone)

AbdulagatovIlmutdin M

StepanovGennadiĭ Vladimirovich

Disciplina

660/.042

Soggetti

Supercritical fluids

Liquid carbon dioxide

Thermochemistry - Mathematical models

Solvents

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Intro -- Library of Congress Cataloging-in-Publication Data -- Contents -- Preface -- Introduction -- 1.1. Technological Applications of the  Supercritical Fluid Mixtures Containing CO2 -- 1.2. Technological Applications of the  Supercritical Fluid Mixtures Containing H2O -- 1.3. Scientific Applications of the  Supercritical Fluid Mixtures -- The Critical Properties of Binary Mixtures and Related Thermodynamic Properties -- 2.1. The Critical Properties of Binary  Mixtures and the Krichevskii Parameter -- 2.2. Partial Molar Volume, Henry's Constant, Distribution Coefficient, Solubility, and Structurtal Properties of Dilute Mixtures and Krichevskii Parameter -- 2.3. The Critical Curves Shape Behavior and Asymptotic Scaling Properties of Binary Mixtures Near the Critical Points of Pure Solvent -- Experimental Methods -- 3.1. Method-1. Observation of the Appearance and Disappearance of Meniscus at The Vapor-Liquid Interface. "Sealed Tube" Method -- 3.2. Method 2: Law of Rectilinear Diameter -- 3.3. Method 3: PVT Relations, ((P/(V)T = (( 2P/(V2)T =0 -- 3.4. Method 4: Pulse Heating Method -- 3.5. Method  5: Flow Apparatus -- 3.6. Method 6: Acoustic Method of  Determination of the Critical Points --



3.7. Method 7: Method of Quasi-Static Thermograms -- The Critical Properties of Binary CO2+Solute Mixtures -- 4.1. The Critical Properties of Binary CO2+Alcohol Mixtures -- 4.2. The Critical Properties of  Binary CO2+N-Alkane Mixtures -- 4.3. The Critical Properties of Binary CO2+Aromatic Hydrocarbon Mixtures -- 4.4. The Critical Properties of Binary CO2+H2O Mixtures -- 4.5. The Critical Properties of Binary CO2+Monatomic Gas (He, Ar, Kr, And Xe) Mixtures -- 4.6. The Critical Properties of Binary CO2+Twoatomic Gases (O2, N2, H2 ) -- 4.7. The Critical Properties of CO2+ Poly-Atomic Fluid (H2S, SO2, N2O, SF6, NH3) Mixtures.

4.8. The Critical Properties of CO2+Refrigerant (CHF3, CH2F2, R134a) Mixtures -- 4.9. The Critical Properties of Binary CO2+(Ethylene, Acetylene, Cyclohexane, and Isomers) -- 4.10. The Critical Properties of Binary CO2+ (Pyridine, Ethanoic Acid, Acetone, Chloroform, Acetonitrile, And Tetrahydrofuran) Mixtures -- The Critical Properties of  Binary Aqueous Solutions -- 5.1. The Critical Properties of  Binary Aqueous Salt Solutions -- 5.2. The Critical Properties of Binary  Aqueous Alcohol Solutions -- 5.3. The Critical Properties of  Binary Aqueous Gas Solutions -- 5.4. The Critical Properties of Binary Aqueous Hydrocarbon Solutions -- 5.5. The Critical Properties of H2O+D2O -- Conclusion -- Acknowledgments -- References -- Compilation of the Critical Properties of Binary Mixtures Containing Carbon Dioxide -- Compilation of the Critical Properties  of Binary Aqueous Solutions -- Index.

Sommario/riassunto

All available sources of the critical curves data of binary aqueous solutions and binary carbon dioxide containing mixtures have been collected, evaluated, and compared with various data sources and with prediction and correlation methods in this work.