1.

Record Nr.

UNINA9911019784903321

Titolo

Polymer brushes : synthesis, characterization, applications / / edited by Rigoberto C. Advincula ... [et al.]

Pubbl/distr/stampa

Weinheim, : Wiley-VCH, c2004

ISBN

9786610520145

9781280520143

1280520140

9783527603824

3527603824

9783527604999

3527604995

Descrizione fisica

1 online resource (509 p.)

Altri autori (Persone)

AdvinculaRigoberto C

Disciplina

668.9

Soggetti

Polymerization

Polymers - Surfaces

Thin films

Polymeres - Surfaces

Polymerisation

Couches minces

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Polymer Brushes; Contents; Preface; List of Contributors; Polymer Brushes: On the Way to Tailor-Made Surfaces; 1 Growth of Polymer Molecules at Surfaces: Introductory Remarks; 2 Coatings: From First Principles to High-Tech Applications; 3 Surface-Coating Techniques; 4 Surface-Attached Polymers; 5 Polymer Brushes: General Features; 6 Theory of Polymer Brushes; 7 Synthesis of Polymer Brushes; 8 Polymer Brushes as Functional Materials; 9 Microstructured Polymer Brushes; 10 Surface-Initiated Polymerization: The Overall Picture; Part I Synthesis; 1 Recent Advances in Polymer Brush Synthesis

1.1 Introduction1.2 "Grafting To" Synthesis Technique; 1.3 "Grafting From" Synthesis Technique; 2 Polymer Brushes by Atom Transfer



Radical Polymerization; 2.1 Introduction; 2.2 Polymer Brushes on Flat Surfaces; 2.2.1 Controlled ATRP from Flat Surfaces; 2.2.2 Block Copolymer Brushes on Flat Surfaces; 2.2.3 Stimuli-Responsive Ultrathin Films from "Grafting To" Approach; 2.3 Polymer Brushes from Particles; 2.3.1 Spherical Brushes from Inorganic Colloids; 2.3.2 Multilayered Core-Shell Colloids; 2.3.3 Imaging of Individual Spherical Brushes; 2.3.4 Modification of Carbon Black Fillers

2.4 Molecular Brushes2.4.1 Synthesis of Molecular Brushes from Linear Polymeric Macroinitiators; 2.4.2 Molecular Brushes from Dendritic Macroinitiators; 3 Polymer Brushes by Atom Transfer Radical Polymerization Initiated from Macroinitiator Synthesized on the Surface; 3.1 Introduction; 3.2 Experimental; 3.3 Results and Discussion; 3.3.1 Synthesis of Macroinitiator for ATRP; 3.3.2 ATRP from Macroinitiator; 4 Synthesis of Polypeptide Brushes; 4.1 Introduction; 4.2 Preparation of Peptide Brushes by "Grafting To"; 4.3 Preparation of Peptide Brushes by Grafting From Polymerization

4.3.1 Mechanisms of NCA Polymerization4.3.2 Amine-Initiated Grafting From Polymerizations in Solution; 4.3.3 Other Techniques for Amine-Initiated Grafting From Polymerizations; 4.4 Preparation of Peptide Brushes by Living Grafting From Polymerization; 4.4.1 Copolymerization Approach; 4.4.2 Alloc-Amide Approach; 5 Bottle Brush Brushes: Ring-Opening Polymerization of Lactide from Poly(hydroxyethyl methacrylate) Surfaces; 5.1 Introduction; 5.2 Synthesis of PHEMA-g-PLA; 5.3 Conclusions and Implications for Future Studies; 5.4 Experimental Section; 5.4.1 Materials

5.4.2 Preparation of Monomer Solution and Substrates5.4.3 Ring-Opening Polymerization from PHEMA Surface; 5.4.4 Analytical Methods; 6 Preparation of Well-Defined Organic-Inorganic Hybrid Nanostructures using Living Cationic Surface-Initiated Polymerization from Silica Nanoparticles; 6.1 Introduction; 6.2 Experimental Section; 6.2.1 Materials; 6.2.2 Characterization; 6.2.3 Synthesis of Immobilized Macroinitiators; 6.3 Results and Discussion; 6.3.1 Living Cationic Surface-Initiated Polymerization of IB from Silica Nanoparticles in the Presence of Sacrificial Free Initiator

6.3.2 Living Cationic Surface-Initiated Polymerization of IB from Silica Macroinitiators

Sommario/riassunto

Materials scientists, polymer chemists, surface physicists and materials engineers will find this book a complete and detailed treatise on the field of polymer brushes, their synthesis, characterization and manifold applications. In a first section, the various synthetic pathways and different surface materials are introduced and explained, followed by a second section covering important aspects of characterization and analysis in both flat surfaces and particles. These specific surface initiated polymerization (SIP) systems such as linear polymers, homopolymers, block copolymers, and hyperbra



2.

Record Nr.

UNINA9910957864103321

Autore

Meierhofer Christian

Titolo

Formen der Evidenz : Populäre Wissenschaftsprosa zwischen Liebig und Haeckel / Christian Meierhofer

Pubbl/distr/stampa

Paderborn, : Brill | Fink, 2019

ISBN

3-8467-6479-5

Edizione

[1st ed.]

Descrizione fisica

1 online resource

Disciplina

830.945

Soggetti

Moderne

Naturwissenschaft

Rhetorik

Popularität

Wissenschaft

Bölsche

Büchner

Zeitschrift

Brief

Weltanschauung

modernity

sciences

rhetorics

popularity

humanities

journal

letter

Lingua di pubblicazione

Tedesco

Formato

Materiale a stampa

Livello bibliografico

Monografia

Nota di bibliografia

Includes bibliographical references (pages [513]-602) and index.

Nota di contenuto

Front Matter -- Copyright page -- Hinweise zur Textgestaltung -- Dank -- Popularität und Modernität der Wissenschaftskommunikation -- Befreiungen -- Zuspitzungen -- Rhythmisierungen -- Summierungen -- Überwindungen -- Wissenschafts- und begriffskritische Ausgänge -- Back Matter -- Literaturverzeichnis --



Siglenverzeichnis -- Abbildungsverzeichnis -- Personenregister.

Sommario/riassunto

Die Studie untersucht das Spektrum populärwissenschaftlicher Darstellungsformen in der zweiten Hälfte des 19. Jahrhunderts und unternimmt erstmals den Versuch einer Systematisierung des Textfeldes zwischen Justus von Liebig und Ernst Haeckel.Die populäre Wissenschaftsprosa wird über ihre textuellen Verfahren, ihre gattungs- und medienspezifischen Darbietungsansprüche erschlossen. Leitend ist dabei die These, dass Popularität als eigenständiges Textmerkmal zu verstehen ist und maßgeblich vom rhetorischen Konzept der Evidenz und von Techniken der Veranschaulichung, des Sichtbarmachens und Vor-Augen-Stellens abhängt. Die Arbeit untersucht unter anderem populäre Briefe, Zeitschriften, Lexika, Hand- und Lehrbücher ebenso wie weltanschauliche Streitschriften. An all diesen Quellen lässt sich zeigen, wie sich die Entstehung und Professionalisierung und die Verbreitung und Popularisierung moderner Wissenschaftsdisziplinen wechselseitig bedingen.