Fluid phase behavior of systems involving high molecular weight compounds and supercritical fluids / / Pedro F. Arce and Martín Aznar

• Record Nr.: UNINA9910955716203321
• Autore: Arce Pedro F
• Pubbl/distr/stampa: New York, : Nova Science Publishers, c2010
• ISBN: 1-61324-617-X
• Edizione: [1st ed.]
• Descrizione fisica: 1 online resource (139 p.)
• Collana: Chemical engineering methods and technology
• Altri autori (Persone): AznarMartín
• Disciplina: 541/.363
• Soggetti: Phase rule and equilibrium; Supercritical fluids; Molecular weights; High pressure (Technology); Fluid dynamics
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references (p. [113]-121) and index.
• Nota di contenuto: Intro -- FLUID PHASE BEHAVIOR OF SYSTEMS INVOLVING HIGH MOLECULAR WEIGHT COMPOUNDS AND SUPERCRITICAL FLUIDS -- FLUID PHASE BEHAVIOR OF SYSTEMS INVOLVING HIGH MOLECULAR WEIGHT COMPOUNDS AND SUPERCRITICAL FLUIDS -- CONTENTS -- PREFACE -- Chapter 1 ABSTRACT -- Chapter 2 INTRODUCTION -- Chapter 3 THERMODYNAMIC MODELS -- 3.1. PERTURBED CHAIN - STATISTICAL ASSOCIATING FLUID THEORY, PC-SAFT -- 3.2. SANCHEZ-LACOMBE, SL. -- 3.3. PENG-ROBINSON, PR -- Chapter 4 PHASE EQUILIBRIUM AT HIGH-PRESSURES -- Chapter 5 RESULTS AND DISCUSSIONS -- 5.1. EOS PURE-COMPONENT PARAMETERS -- 5.1.1. Low Molecular Weight Pure-Component Parameters -- 5.1.2. High Molecular Weight Pure-Component Parameters -- 5.2. PS + SUPERCRITICAL FLUID SYSTEMS -- 5.2.1. Pure-Component Parameters -- 5.2.2. Binary Interaction Parameters. -- 5.2.3. Modeling Solubility Pressures of Binary Systems -- 5.2.3.1. PS + Supercritical Fluid Systems -- 5.2.3.2. PS + Chlorofluorocarbon Fluid Systems -- 5.2.3.3. PS + Hydrochlorofluorocarbon and PS + Hydrofluorocarbon Fluid Systems -- 5.3. MOLTEN POLYMER + CO2 SYSTEMS -- 5.3.1. Evaluation of EoS Pure-Component Parameters -- 5.3.2. Correlation of GLE Data -- ; 5.3.3. HDPE + CO2 and LDPE + CO2 Systems -- 5.3.4. i-PP + CO2 Systems -- 5.3.5. P(Vac) + CO2 Systems -- 5.3.6. PS + CO2 Systems -- 5.3.7. p(MMA) + CO2 Systems -- 5.3.8. p(BMA) + CO2 Systems -- 5.3.9. p(DMS) + CO2 Systems -- 5.3.10. PC + CO2 Systems -- 5.4. MODELING OF BINARY AND TERNARY SYSTEMS INVOLVING A BIODEGRADABLE POLYMER, ACOPOLYMER AND A SUPERCRITICAL FLUID -- 5.4.1. Polymer + Fluid and Copolymer + Fluid Equilibrium -- 5.4.1.1. PLA + DME System -- 5.4.1.2. PLA + CO2 System -- 5.4.1.3. PLA + CDFM System -- 5.4.1.4. PLA + DFM System -- 5.4.1.5. PLA + TFM System -- 5.4.1.6. PLA + TFE System -- 5.4.1.7. PBS + CO2 System -- 5.4.1.8. PBSA + CO2 System.; 5.4.2. Polymer + Fluid 1 + Fluid 2 Equilibrium -- 5.4.2.1. PLA + CO2 + DME System -- 5.5. BIODEGRADABLE COPOLYMER + SUPERCRITICAL FLUID SYSTEMS -- 5.5.1. PLAG + DME System -- 5.5.2. PLAG + CO2 System. -- 5.5.3. PLAG + CDFM System -- 5.5.4. PLAG + TFM System -- 5.6. BLOCK COPOLYMER + SUPERCRITICAL CO2 SYSTEMS -- 5.6.1. p(EO-b-BO) + CO2 System -- 5.6.2. p(EO-b-PO) + CO2 System -- 5.6.3. P(Vac-B-AHO) + CO2 System -- 5.7. POLYMER BLENDS AND POLYMER BLEND + CO2 SYSTEMS -- 5.7.1. Cloud Points Temperature of Blends -- 5.7.1.1. PBD/PS Blends -- 5.7.1.2. PVME/PS Blends -- 5.7.1.3. PPG/PEGE Blends -- 5.7.1.4. PEO/PES Blends -- 5.7.2. Fluid Phase Behavior of PS/PVME Blend + CO2 Systems -- Chapter 6 CONCLUSIONS -- ACKNOWLEDGMENTS -- REFERENCES -- INDEX -- Blank Page.
• Sommario/riassunto: Although supercritical fluids (SCF) and their unique solvent characteristics have been a matter of continuing scientific interest since the past century, their potential benefit to chemical processing have not been fully realised; it is only in the past a few years that SCF solvents have been the focus of active research and development programs.